Rheological Characterization of Novel Delayed-Transition Metal Crosslinked Fracturing Fluids: Correlation With First Field Applications

2009 ◽  
Author(s):  
Carlos Abad ◽  
Andrey L. Mirakyan ◽  
Mike D. Parris ◽  
Yiyan Chen ◽  
Fred A. Mueller
Keyword(s):  
Transition Metal ◽  
Rheological Characterization ◽  
Fracturing Fluids ◽  
Delayed Transition

Rheological characterization of tack and viscoelasticity of compositions of crepe coating used in the Yankee dryer

TAPPI Journal ◽  
2019 ◽  
Vol 18 (11) ◽  
pp. 641-649
Author(s):  
JOSHUA OMAMBALA ◽  
CARL MCINTYRE
Keyword(s):  
Normal Force ◽  
Weight Ratio ◽  
Good Combination ◽  
Rheological Characterization ◽  
Nonlinear Viscoelastic ◽  
Coating Composition ◽  
Linear And Nonlinear ◽  
Work Done ◽  
Tissue Production

The vast majority of tissue production uses creping to achieve the required set of properties on the base sheet. The Yankee coating helps to develop the desired crepe that in turn determines properties such as bulk and softness. The adhesion of the sheet to the Yankee surface is a very important characteristic to consider in achieving the desired crepe. The coating mix usually consists of the adhesive, modifier, and release. A good combination of these components is essential to achieving the desired properties of the tissue or towel, which often are determined by trials on the machine that can be time consuming and lead to costly rejects. In this paper, five compositions of an industrial Yankee coating adhesive, modifier, and release were examined rheologically. The weight ratio of the adhesive was kept constant at 30% in all five compositions and the modifier and release ratios were varied. The normal force and work done by the different compositions have been shown at various temperatures simulating that of the Yankee surface, and the oscillatory test was carried out to explain the linear and nonlinear viscoelastic characteristic of the optimal coating composition.

Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform

2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Element ◽  
Oxidation States ◽  
Boron Compounds ◽  
Main Text ◽  
Main Group Element ◽  
Rational Ligand Design ◽  
Supplementary Material

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>

CHEMICAL AND RHEOLOGICAL CHARACTERIZATION OF A VEGETABLE-BASED EMULSION

2019 ◽  
Author(s):  
Luiz Eduardo Rodrigues Vieira ◽  
Leonardo Rosa Ribeiro da Silva ◽  
Felipe Chagas Rodrigues de Souza ◽  
Wisley Sales ◽  
Álisson Rocha Machado
Keyword(s):  
Rheological Characterization

RHEOLOGICAL CHARACTERIZATION OF PERUVIAN COPPER ORE SLURRIES

2020 ◽  
Author(s):  
Joel López Bonilla ◽  
Cesar Celis ◽  
Danmer Maza
Keyword(s):  
Rheological Characterization ◽  
Copper Ore
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