scholarly journals New anti-fluorite solid-solution phases in Li-Ti-N ternary system

2009 ◽  
Vol 117 (1361) ◽  
pp. 52-55 ◽  
Author(s):  
Atsuo YAMADA ◽  
Shunsuke MORI ◽  
Hiromasa IYAMA ◽  
Ryoji KANNO ◽  
Masatoshi SHIBATA
Keyword(s):  
Solid Solution ◽  
Ternary System ◽  
Fluorite Solid Solution

scholarly journals Silicon Nitride Solid Solution in the Ternary System, Si3N4-AlN-SiO2

1975 ◽  
Vol 83 (963) ◽  
pp. 553-557 ◽  
Author(s):  
Nobuo KAMIYA ◽  
Yoichi OYAMA ◽  
Osami KAMIGAITO
Keyword(s):  
Solid Solution ◽  
Silicon Nitride ◽  
Ternary System

scholarly journals Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series

RSC Advances ◽  
2020 ◽  
Vol 10 (57) ◽  
pp. 34632-34650
Author(s):  
Devon L. Drey ◽  
Eric C. O'Quinn ◽  
Tamilarasan Subramani ◽  
Kristina Lilova ◽  
Gianguido Baldinozzi ◽  
...  
Keyword(s):  
Solid Solution ◽  
Solid Solution Series ◽  
Length Scales ◽  
Total Scattering ◽  
Disorder Transition ◽  
X Ray ◽  
Chemical Substitution ◽  
Solution Series ◽  
Calorimetric Measurements ◽  
Fluorite Solid Solution

Combined neutron and X-ray total scattering with calorimetric measurements of the solid solution series Ho2Ti2−xZrxO7 reveals a complex order–disorder transition across short, intermediate, and long length scales induced by chemical substitution.

Growth of Fluorite Solid Solution Crystals in the Ternary SrF2–BaF2–LaF3 System and Investigation of Their Properties

2018 ◽  
Vol 63 (6) ◽  
pp. 1015-1021
Author(s):  
D. N. Karimov ◽  
I. I. Buchinskaya ◽  
A. G. Ivanova ◽  
O. N. Il’ina ◽  
N. A. Ivanovskaya ◽  
...  
Keyword(s):  
Solid Solution ◽  
Fluorite Solid Solution

Subsolidus phase equilibria in the RuO2–Bi2O3–CeO2 system

2003 ◽  
Vol 18 (6) ◽  
pp. 1297-1300 ◽  
Author(s):  
Marko Hrovat ◽  
Andreja Benčan ◽  
Janez Holc ◽  
Tadej Rojac ◽  
Marija Kosec
Keyword(s):  
Solid Solution ◽  
Phase Equilibria ◽  
Solid Oxide Fuel Cells ◽  
Solid Electrolyte ◽  
Solid Solubility ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Subsolidus Phase ◽  
Fluorite Solid Solution ◽  
Tie Line

Subsolidus equilibria in air in the RuO2–Bi2O3–CeO2 systems were studied with the aim of obtaining information on possible interactions between a Bi2Ru2O7-based cathode and a CeO2-based solid electrolyte in solid-oxide fuel cells. Bi2O3 is soluble in CeO2, and forms a cubic fluorite solid solution Bi1-xCexO2-x/2 up to Bi1/3Ce2/3O1.83, while no solid solubility of the CeO2 in Bi2O3 was detected. No ternary compound was found in the system. The tie line is between Bi2Ru2O7 and the CeO2 solid solution.

scholarly journals Experimental Investigation of the Phase Equilibria in the Al-Mn-Zn System at 400°C

2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
Tian Wang ◽  
Dmytro Kevorkov ◽  
Ahmad Mostafa ◽  
Mamoun Medraj
Keyword(s):  
Solid Solution ◽  
Ternary System ◽  
Terminal Solid Solution ◽  
Stoichiometric Compound ◽  
Diffusion Couples ◽  
Ternary Compounds ◽  
Ternary Solubility ◽  
Limited Solid Solubility ◽  
Binary Compounds ◽  
Phase Relationships

Al-Mn-Zn ternary system is experimentally investigated at 400°C using diffusion couples and key alloys. Phase relationships and homogeneity ranges are determined for binary and ternary compounds using EPMA, SEM/EDS, and XRD. Reported ternary compound T3 (Al11Mn3Zn2) is confirmed in this study and is denoted as τ2 in this paper. Two new ternary compounds (τ1 and τ3) are observed in this system at 400°C. τ1 is determined as a stoichiometric compound with the composition of Al31Mn8Zn11. τ3 has been found to have homogeneity range of AlxMnyZnz (x=9–13 at%; y=11–15 at%; z=75–77 at%). The binary compounds Al4Mn and Al11Mn4 exhibit limited solid solubility of around 6 at% and 4 at% Zn, respectively. Terminal solid solution Al8Mn5 is found to have maximum ternary solubility of about 10 at% Zn. In addition, ternary solubility of Al-rich β-Mn′ at 400°C is determined as 4 at% Zn. Zn-rich β-Mn′′ has a ternary solubility of 3 at% Al. The solubility of Al in Mn5Zn21 is measured as 5 at%. Based on the current experimental results, the isothermal section of Al-Mn-Zn ternary system at 400°C has been constructed.

Phase relationships in the Ce–Nd–B system at 773 K

2020 ◽  
Vol 111 (6) ◽  
pp. 526-532
Author(s):  
Xuehong Cui ◽  
Jinming Zhu ◽  
Ketong Luo ◽  
Jianlie Liang
Keyword(s):  
Solid Solution ◽  
Ternary System ◽  
Continuous Solid Solution ◽  
Solution Phase ◽  
Solid Solution Phase ◽  
X Ray Diffraction ◽  
Two Phase ◽  
X Ray ◽  
Three Phase ◽  
Phase Relationships

Abstract Phase relationships in the Ce-Nd-B ternary system at 773 K were investigated by means of X-ray diffraction and scanning electron microscopy with energy dispersive X-ray spectroscopy techniques. Six borides, i. e. CeB4, CeB6, NdB4, NdB6, NdB66 and Nd2B5 are confirmed in this work. No ternary compound was observed. CeB4 and NdB4 were discovered to form the continuous solid solution phase (Ce,Nd)B4, CeB6 and NdB6 also form the solid solution phase (Ce,Nd)B6. The maximum solid solubility of Ce in (Ce,Nd)2B5 phase is 46.5 at.%. The isothermal section of the Ce-Nd-B ternary system at 773 K consists of 3 three-phase regions, 7 two-phase regions and 7 single- phase regions.

A Review of the XRD Data of the Phases Present in the CaO-SrO-CuO System

1992 ◽  
Vol 7 (3) ◽  
pp. 142-148 ◽  
Author(s):  
Brian J. Reardon ◽  
Camden R. Hubbard
Keyword(s):  
Solid Solution ◽  
Ternary System ◽  
Crystal Structures ◽  
Powder Diffraction ◽  
Solid Solution Series ◽  
Powder Diffraction File ◽  
Reference Pattern ◽  
X Ray ◽  
Solution Series ◽  
Xrd Patterns

AbstractX-ray powder patterns for the phases in the CaO-SrO-CuO ternary system, along with the corresponding crystal structures, were obtained from the literature and from the Powder Diffraction File. Available XRD patterns were compared with each other and with a calculated pattern for each phase, yielding a recommended reference pattern. The simulated powder patterns presented here deal with the phases found within the (Ca,Sr)O, (Ca,Sr)2CuO3, (Ca,Sr)14Cu24O41, (Ca,Sr)CuO2, (Ca,Sr)Cu2O3, and (Ca,Sr)Cu2O2 solid solution series and are recommended for the Powder Diffraction File (PDF).

Lignes monovariantes de l'isotherme 75 °C du système quaternaire réciproque: H3PO4–K2SO4–H2SO4–K3PO4–H2O

1993 ◽  
Vol 71 (11) ◽  
pp. 1816-1820 ◽  
Author(s):  
Néji Bourguiba ◽  
Tahar Jouini
Keyword(s):  
Solid Solution ◽  
Chemical Analysis ◽  
Ternary System ◽  
Reciprocal System ◽  
Substitution Type ◽  
Invariant Points ◽  
Boundary Curves

The boundary curves and quaternary invariant points of the reciprocal system H3PO4–K2SO4–H2SO4–K3PO4–H2O were investigated at 75 °C and 1 atm by chemical analysis of solutions in equilibria, respectively, with two or three salts. Eleven compounds occur in this system. Only eight of them have crystallization areas inside Janecke's prism; these are K2SO4, K2SO4•KHSO4, K2SO4•7KHSO4•H2O, KHSO4, KH2PO4•KHSO4, KH5(PO4)2, KH2PO4, and a solid solution K8(H2PO4)1+x(HSO4)7−x, 0 ≤ x ≤ 1, of substitution type continuous between the two limiting compositions KH2PO4•7KHSO4 and KH2PO4•3KHSO4. The crystallization fields of 3K2HPO4•KH2PO4•2H2O, K2HPO4, and K3PO4•3H2O are very close to the solubility curves of the ternary system K3PO4–H3PO4–H2O. Results are explained and discussed.

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