ChemInform Abstract: Studies of BaO-In2O3-CuO Ternary System. Part 1. Phase Equilibria in the Isothermal Cross-Section of 930 °C. Part 2. Crystallochemical Characterization of the (β)-Solid Solution.

ChemInform ◽  
2010 ◽  
Vol 31 (32) ◽  
pp. no-no
Author(s):  
R. Horyn ◽  
E. Bukowska ◽  
A. Sikora
2005 ◽  
Vol 20 (3) ◽  
pp. 254-258 ◽  
Author(s):  
S. N. Achary ◽  
A. K. Tyagi

A series of mixed fluoride compositions with PbF2 and ScF3 were prepared by heating the intimate mixtures of component fluorides at 600 °C for 10 h followed by slowly cooling to room temperature. The products obtained were analyzed by powder XRD to reveal the phases present in them and hence the low-temperature phase equilibria in the PbF2-ScF3 system. The phase equilibria show the fluorite-type solid solution up to the composition of about 15 mol% of ScF3 in the PbF2 lattice. The unit cell volume decreases with increasing ScF3 contents in the fluorite-type solid solutions. Beyond the solubility limit, the biphasic mixture of the cubic fluorite-type solid solution and leftover ScF3 is found to exist.


2015 ◽  
Vol 757 ◽  
pp. 1-5
Author(s):  
Chang Jiang Liu ◽  
Qiu Juan Lv ◽  
Zhi Qing Guo ◽  
Yan Jiao Li ◽  
Jian Feng Guo

The phase equilibria in the Fe-Nb-V ternary system were investigated by means of optical microscopy, electron probe microanalysis. One isothermal section in the Fe-Nb-V ternary system at 1050 °C was firstly experimentally established. Present experimental results indicate that: (1) there is a large (Nb, V) continuous bcc solid solution; (2) there are the larger solubilities of V in the FeNb and Fe2Nb phases. The newly determined phase equilibria in this system will provide important support for the development of microalloyed steels.


2013 ◽  
Vol 546 ◽  
pp. 107-111
Author(s):  
Chang Jiang Liu ◽  
Yan Jiao Li ◽  
Zhi Qing Guo ◽  
Qiu Juan Lv ◽  
Fang Xie ◽  
...  

The phase equilibria in the Fe-Nb-V ternary system were investigated by means of optical microscopy, electron probe microanalysis. One isothermal section in the Fe-Nb-V ternary system at 900 °C was firstly experimentally established. Present experimental results indicate that: (1) there is a large (Nb, V) continuous bcc solid solution; (2) there are the larger solubilities of V in the FeNb and Fe2Nb phases. The newly determined phase equilibria in this system will provide important support for the development of microalloyed steels.


2012 ◽  
Vol 67 (6) ◽  
pp. 265-269 ◽  
Author(s):  
Yu. V. Balykova ◽  
S. V. Nikolaev ◽  
E. Yu. Kerimov ◽  
E. M. Slyusarenko

1995 ◽  
Vol 39 ◽  
pp. 731-738
Author(s):  
Winnie Wong-Ng ◽  
Lawrence P. Cook ◽  
F. Jiang

Phase equilibria of two superconductor phases, namely the 20K Raveau phase (Bi2.2-xSr1.8+xCuOz, currently referred to as the 11905 phase) and the 80K 2212 phase of the Bi-Sr-Ca-Cu-0 system were investigated. The amount of Ca-substitution of the Raveau solid solution was determined and the solid solution region can be approximately described as Bi2.2+xSr1.8-X-Y CayCu1±x/2Ow (referred to as the Ca-Raveau phase or the 119x5, ‘ with 0<x<0.15, 0<y<0.5. To determine the melting equilibria of the 2212 phase, a procedure involving the use of a wicking technique to capture the melt was applied. X-ray powder diffraction (XPD) and quantitative energy dispersive x-ray spectroscopy (EDS) were used to analyse the phases present in the residual and melt, respectively. The approximate primary crystallization field of the incongruently melting 2212 phase was illustrated.


Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 958 ◽  
Author(s):  
Cuiping Wang ◽  
Xianjie Zhang ◽  
Lingling Li ◽  
Yunwei Pan ◽  
Yuechao Chen ◽  
...  

The phase equilibria of the Co-Ti-Ta ternary system at 1000 °C, 1100 °C, and 1200 °C were experimentally investigated using an electron probe microanalyzer and X-ray diffraction. Experimental results show that: (1) No ternary compound exists in the studied isothermal sections; (2) the β(Ti) and β(Ta) phases form the continuous solid solution β(Ti,Ta) in the Ti-Ta side; (3) the solubility of Ta in the (αCo) is less than 5%; (4) the phases of Co2Ti(h) and γ-Co2Ta, Co2Ti(c) and β-Co2Ta form the continuous solid solutions Co2(Ta,Ti)(h) and Co2(Ta,Ti)(c), respectively.


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