scholarly journals Value Of The Index Of Chemical Oxygen Demand As Measure Of The Methanol Content In Return Underground Local-Water Of Oil And Gas Condensate Fields

2019 ◽  
Vol 14 (2) ◽  
pp. 73-78
Author(s):  
E.A. Reshetnyak ◽  
N.N. Nemets ◽  
O.S. Chernyshova ◽  
V.M. Ostrovskaya

The method of the methanol content control in samples of return underground local-water of oil and gas condensate fields is described. The determination is based on a preliminary estimation of the chemical oxygen demand index, using an accelerated technique with potentiometric redox titration of potassium dichromate excess. On water-methanol solutions of known composition using the “added-found” method, it was proved that under the conditions of the chosen procedure, the methanol is completely oxidized; the value of the relative standard deviation of the determination results does not exceed 3 %. The interfering influence of the components of highly mineralized water samples on the integral assessment of chemical oxygen demand was studied. The accuracy of the determination of methanol in real water samples is proved by the method of standard additives.

2011 ◽  
Vol 264-265 ◽  
pp. 1690-1695
Author(s):  
M.M. Rahman ◽  
Alias Mohd Yusof

Mercury concentrations and speciation were determined in surface water samples taken from rivers in the vicinity of industrial area, in Johore Malaysia. Samples were collected from the same sites before and immediately after rainfall. The aim of this study is to assess the influence of seasonal change in river water on the concentration of mercury (Hg) species. Trace concentrations of mercury in water samples were determined by a method involving a simple and rapid procedure involving the flow-injection inductively coupled plasma mass spectrometry (FI-ICP-MS) and graphite furnace atomic absorption spectrometry (GFAAS) techniques. Mercury vapor, generated by sodium borohydride as the reductant, was stabilized by potassium dichromate (K2Cr2O7), then released by controlled heating and detected by FI-ICP-MS. Methyl mercury (II) was preconcentrated using the ammonium pyrolidindithiocarbamate (APDTC)-chloroform extraction procedure and the chloroform extract was introduced into the graphite tube. The absolute detection limits were found to be 0.204 μg L-1 and 0.273 μg L-1 for total mercury and methyl mercury respectively, with thevariability being lower than 5% relative standard deviation (RSD) at the 5 μg L-1 level. Because of the high stability of MeHg (II)-APDTC complexes, it is possible to evaporate the extract in order to obtain a crystalline powder to be dissolved with a few micro liters of chloroform enacting MeHg (II) and Hg (II) can be detected at sub-nanogram levels.


2019 ◽  
Vol 32 ◽  
pp. 153-162
Author(s):  
Nada M. Al-Baghdadi ◽  
Abdulaziz M. Abdullah ◽  
Entisar N. Sultan

The current study has evaluated Shatt Al-Arab water using organic pollution index. The study included three stations, the first Al-Sharash, the second Al-Salhiya and the third area Al-Dweab. Water samples were monthly collected from December 2017 to November 2018. Five environmental parameters were used to calculate the organic pollution index (OPI) including Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Active nitrate (NO3), Ammonium ion (NH4) and Total Phosphate (TP). The highest biological oxygen demand was 9 mg.l-1 at Al-Sharash station in July and the lowest values 1mg.l-1 in the Al- Dweab station during December, January, February and April. The highest chemical oxygen demand (250 mg.l-1 was recorded at Al-Sharash station in September and the lowest value was 6.2 mg.l-1 in Al-Dweab station during December. Nitrates was recorded the highest value 41.51 mg nitrogen-nitrate.l-1 at Al-Salhiya station in May and lowest value 1.49 mg nitrogen- nitrate.l-1 at Al-Sharash station during December. The ammonium ion was recorded in highest value 7.7 mg.l-1 at Al- Salhiya station in December and the lowest value 0.5 mg. l-1 at Al-Sharash station during June, while phosphate value was 0.23 and 1.99 mg.l-1 were recorded at Al-Sharash station in August and July respectively. The highest value of organic pollution index was 2.56 at Al-Salihiya station in August and lowest value 0.69 in the Al-Dweab station in April, while the annual rate of organic pollution index for the first, second and third stations were 1.55, 1.81 and 1.47 respectively, and 1.61 for Shatt Al-Arab water.


2008 ◽  
Vol 5 (3) ◽  
pp. 487-492 ◽  
Author(s):  
Arunabh Mishra ◽  
Vasishta Bhatt

A report of physico-chemical and microbial study of the water samples taken from the region nearby Anand district of central Gujarat is presented here. Six water samples are subjected to physico- chemical analysis like pH, TDS, hardness, conductivity, dissolved oxygen and chemical oxygen demand. The MPN count resulted from the bacteriological study of these samples has given the information regarding the suitability of the water for drinking and other domestic applications. The results are analyzed comparatively and conclusions regarding the suitability of the use of such waters are made.


2020 ◽  
Vol 19 (2) ◽  
pp. 144-151
Author(s):  
Arif Sumantri ◽  
Rifqi Zakiya Rahmani

Latar Belakang: Limbah industri tekstil menghasilkan limbah logam berat kromium (VI)) untuk digunakan dalam proses produksi. Kromium (VI) yang masuk ke dalam air bisa menjadi masalah kesehatan baik jangka pendek maupun panjang. Salah satu wilayah industri yang banyak berkembang terdapat di sektor hulu Sungai Citarum terdapat di Kecamatan Majalaya, Kabupaten Bandung sebagai kawasan zona industri.Terdapat sekitar 1500 industri dengan potensi jumlah limbah yang dibuang mencapai 2.800 ton per hari  yang sekaligus sebagai sumber pencemaran paling dominan.Metode: Instrumen penelitian ini adalah observasi dan pengujian sampel di laboratorium.Sampel diambil selama 3 hari berturut-turut di 7 stasiun di setiap lokasi. Variabel yang diuji yaitu, kromium (VI), COD, DO, dan pH. Metode pengambilan yang digunakan adalah grab sampel dengan teknik purposive sampling. Waktu untuk mengambil sampel air dilakukan pada malam hari. Sampel air diawetkan dengan cara pengasaman dan pendinginan sesuai dengan SNI 6989.57: 2008. Hasil penelitian ini dianalisis dengan membandingkan dengan Peraturan Pemerintah No.82 Tahun 2001.Hasil: Hasil penelitian menunjukan konsentrasi kromium (VI)di stasiun A1 adalah 0,042 mg/l, stasiun A2 0,44 mg/l, di stasiun A3 adalah 0,075 mg/l dan stasiun A4 adalah 0,093 mg/l. Selain itu, di stasiun B1, B2, dan B3 konsentrasi di bawah 0,04 mg/l (batas alat minimum). Kadar kromium (VI) A3 dan A4 tidak memenuhi persyaratan menurut PP No.82 tahun 2001 standar kualitas kromium (VI)di badan air kelas II adalah 0,05 mg/l.Simpulan: Air Sungai Citarum di Kabupaten Majalaya telah tercemar oleh kromium (VI). Dari hasil, kromium (VI)telah melebihi perairan sungai dari stasiun A3 dan A4 dengan kadar 0,075 mg/l dan 0,093 mg/l. ABSTRACTTitle: Analysis of Chromium IV pollution based on Chemical Oxygen Demand at Citarum River, Majalaya District, Bandung Regency, West JavaBackground: Textile industrial waste produces heavy metal waste chromium (VI) for use in the production process. Chromium (VI) that gets into water can be a health problem both in the short and long term. One of the most developed industrial areas is in the upstream sector of the Citarum River in Majalaya District, Bandung Regency as an industrial zone. There are around 1500 industries with the potential for the amount of waste disposed of up to 2,800 tons per day which is also the most dominant source of pollution.Methods: The research instrument was observation and sample testing in the laboratory. Samples were taken for 3 consecutive days at 7 stations in each location. The variables tested were chromium (VI), COD, DO, and pH. The method used is grab sampling with purposive sampling technique. Time to take water samples is done at night. The water samples were preserved by means of acidification (HNO3 and H2SO4) and cooling according to SNI 6989.57: 2008. The results of this study were analyzed by comparing with PP No.82 of 2001.Results: The results showed that the chromium (VI) concentration at station A1 was 0.042 mg / l, station A2 was 0.44 mg / l, at station A3 was 0.075 mg / l and station A4 was 0.093 mg / l. In addition, at stations B1, B2, and B3 the concentration was below 0.04 mg / l (minimum equipment limit). Chromium (VI) A3 and A4 levels do not meet the requirements according to PP No. 82 of 2001 the quality standard for chromium (VI) in class II water bodies is 0.05 mg / l.Conclusion: Citarum River water in Majalaya Regency has been polluted by chromium (VI). From the results, chromium (VI) has exceeded the river waters of stations A3 and A4 with levels of 0.075 mg / l and 0.093 mg / l. 


2020 ◽  
Vol 36 (7) ◽  
pp. 841-846
Author(s):  
Xiaomin CHEN ◽  
Lian PENG ◽  
Jingcheng WANG ◽  
Debing ZHANG ◽  
Yong ZHAO ◽  
...  

2018 ◽  
Vol 13 (1) ◽  
pp. 85-89
Author(s):  
E.A. Reshetnyak ◽  
◽  
N.N. Nemets ◽  
E.A. Shugaj ◽  
O.S. Chernyshova ◽  
...  

2015 ◽  
Vol 73 (3) ◽  
pp. 697-706 ◽  
Author(s):  
Yingke Xie ◽  
Zhiyu Wen ◽  
Zhihong Mo ◽  
Zhiqiang Yu ◽  
Kanglin Wei

An automatic, miniature and multi-parameter on-line water quality monitoring system based on a micro-spectrometer is designed and implemented. The system is integrated with the flow-batch analysis and spectrophotometric detection method. The effectiveness of the system is tested by measuring chemical oxygen demand (COD) and ammonia-nitrogen in water. The results show that the modified system provides a cost-effective, sensitive, reproducible and reliable way to measure COD and ammonia-nitrogen in water samples with automatic operation and low toxic chemical consumption. In addition, the experiment results show that the relative error of the system is less than 10%, the limit of detection is 2 mg/L COD and 0.032 mg/L ammonia-nitrogen, respectively, and the relative standard deviation was 6.6% at 15.0 mg/L COD (n = 7) and 5.0% at 0.300 mg/L ammonia-nitrogen (n = 7). Results from the newly designed system are consistent with the data collected through the Chinese national standard analysis methods.


2020 ◽  
Vol 17 (4) ◽  
pp. 1160
Author(s):  
Ghadir El-Chaghaby ◽  
Sayed Rashad ◽  
Muhammad Abdul Moneem

Fresh water resources in terms of water quality is a crucial issue worldwide. In Egypt, the Nile River is the main source of fresh water in the country and monitoring its water quality is a major task on governments and research levels. In the present case study, the physical, chemical and algal distribution in Nile River was monitored over two seasons (winter and summer) in 2019. The aims of the study were to check the seasonal variation among the different water parameters and also to check the correlations between those parameters. Water samples were collected from the Nile in Cairo governorate in EGYPT. The different physiochemical and microbiological properties in water samples were assessed. The studied parameters were included: temperature, turbidity, dissolved oxygen, chemical oxygen demand, pH, electric conductivity, total dissolved solids, total hardness, anions and cations. Also, the total algae count, blue-green algae, green algae, diatoms, unicellular and filamentous algae were monitored. The results revealed that during winter season the values recorded for (turbidity, total dissolved solids, pH, total alkalinity, total hardness, dissolved oxygen, chemical oxygen demand as well as nitrate, sulfate, chloride, fluoride ions, calcium and magnesium) were higher than during summer. While other parameters including ammonia, nitrite, silicate, carbon dioxide, phosphate, manganese, iron and residual aluminium were higher in summer compared to winter. The data showed a variation total algal count of 4600 to 6500 unit/ml in winter and varied from 3100 to 4500 unit/ml during summer season with predominance of diatoms. The recorded Pearson’s correlations indicated several significant correlations between tested parameters. In conclusion, although there were several variations in tested water quality parameters though all results were within the permissible limits set by the World Health Organization for drinking water.


2017 ◽  
Vol 9 (39) ◽  
pp. 5797-5805 ◽  
Author(s):  
Do Thi Kim Hue ◽  
Takumi Shiba ◽  
Yasuaki Maeda ◽  
Norimichi Takenaka

In this study, the use of potassium dichromate as an oxidizing reagent in the 3-step chemiluminescence (CL) chemical oxygen demand (COD) method, based on the principle of the permanganate COD (CODMn) method (JIS K0102), was developed (3-step CL CODCr method).


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