scholarly journals Dynamics of herbicide degradation in cauliflower

2018 ◽  
Vol 64 (No. 11) ◽  
pp. 551-556
Author(s):  
Jaroslav Šuk ◽  
Miroslav Jursík ◽  
Marie Suchanová ◽  
Dana Schusterová ◽  
Kateřina Hamouzová
Keyword(s):  
Active Ingredient ◽  
Field Experiments ◽  
Residue Level ◽  
Herbicide Residues ◽  
Herbicide Degradation ◽  
Maximum Residue Level ◽  
Brassica Vegetables

The aim of this work was to compare the dynamics of the degradation of herbicides commonly used in brassica vegetables. Series of plot field experiments were carried out in planting cauliflower in 2012–2014. The amount of herbicide residues with the maximum residue level (MRL) determined by the Regulation (EC) No. 396/2005 and with requirements of non-residue production (up to 10 µg/kg of active ingredient in harvested product) was compared. Napropamide, clomazone and dimethachlor were applied before planting and pendimethalin, S-metolachlor, pyridate, ethametsulfuron, dimethenamid, metazachlor, quinmerac, picloram, clopyralid, cycloxydim, fluazifop, propaquizafop and quizalofop were applied after planting the cauliflower. Besides fluazifop and quizalofop, all tested herbicides showed a fast degradation and can be recommended for non-residue production. The amount of fluazifop residues did not fall below the MRL even 6 weeks after application. Residues of post-emergently applied quizalofop were detected in cauliflower 10–44 days after application in most of the samples at concentration 9–73 µg/kg(below the MRL).

scholarly journals Dynamics of herbicides degradation in carrot (Daucus carota L.) roots and leaves  

2021 ◽  
Author(s):  
Jaroslav Šuk ◽  
Kateřina Hamouzová ◽  
Jana Hajšlová ◽  
Miroslav Jursík
Keyword(s):  
Daucus Carota ◽  
Field Experiments ◽  
Residue Level ◽  
Withdrawal Period ◽  
Daucus Carota L ◽  
Herbicide Residues ◽  
Maximum Residue Level ◽  
Low Concentrations

This research had two main aims. First, to analyse the degradation dynamics of herbicides commonly used in carrot (aclonifen, clomazone, flufenacet, linuron, metribuzin, pendimethalin, S-metolachlor). Second, to compare the amount of herbicide residues with the maximum residue level and with requirements of non-residual production. The field experiments were conducted in 2012–2016. All tested herbicides resulted in relatively low concentrations of residues in carrot roots (up to 10 µg/kg) when the recommended withdrawal period was followed between application and harvest. The concentration of S-metolachlor in carrot roots exceeded the maximal residual limit (MRL) if the application was carried out four days before harvest. The measured values of other tested herbicide residues in carrot roots did not exceed the MRL in any of the tested samples. Pre-emergent use of clomazone, linuron and flufenacet could be recommended for non-residue carrot production. Post-emergent use of metribuzin can be used for non-residue carrot production if the interval between application and harvest is at least 80 days. Concentrations of herbicide residues in carrot leaves were many times higher than in roots. All tested herbicides can be applied for safe carrot production if applicators adhere to the requirements for use.  

scholarly journals Residues of carbosulfan and its carbofuran metabolites and 3-hydroxy-carbofuran in oranges

2004 ◽  
Vol 26 (2) ◽  
pp. 230-233 ◽  
Author(s):  
Marcos José Trevisan ◽  
Gilberto Casadei de Baptista ◽  
Luiz Roberto Pimentel Trevizan ◽  
Geraldo Papa
Keyword(s):  
Gas Chromatography ◽  
Field Experiments ◽  
Residue Level ◽  
Fruit Consumption ◽  
Low Intensity ◽  
Brazilian Legislation ◽  
Maximum Residue Level ◽  
Nitrogen Phosphorus Detector ◽  
Nitrogen Phosphorus ◽  
Unique Application

The objectives of this study were to evaluate the residues of the insecticide carbosulfan and its carbofuran metabolites and 3-hydroxy-carbofuran in orange compartments (whole fruit, bagasse and juice) and comparison between the residual levels found in fruits with the maximum residue level and the safety interval established by the Brazilian legislation. Two field experiments were carried out, both with the following treatments: a-check; b-one application of 10 g of carbosulfan . 100 L-1 of water; c-one application with twice the rate applied in treatment b; d-four applications with the same rate applied in treatment b. Samples were taken at (-1), zero, 1, 3, 7, 14, 21 and 28 days after the last or unique application. The quantitative determinations were done by gas chromatography technique, using a nitrogen-phosphorus detector. The carbosulfan metabolism to its carbofuran metabolite was rapid (3 days), being both analytes concentrated in the bagasse (peel + flavedo + albedo). However, the metabolism of carbofuran to 3-hydroxy-carbofuran was of low intensity or this metabolite was quickly dissipated. Carbosulfan residues and its metabolites did not penetrate into the fruit, thus not contaminating the juice. The use of the pesticide was adequate, with respect to fruit consumption, in relation to the Brazilian legislation.

scholarly journals Selectivity and efficacy of herbicides dimethachlor and pethoxamid in rocket crop

2020 ◽  
Vol 56 (No. 4) ◽  
pp. 305-316
Author(s):  
Ivana Doležalová ◽  
Irena Petrželová ◽  
Martin Duchoslav
Keyword(s):  
Field Experiments ◽  
Chenopodium Album ◽  
Application Rate ◽  
Amaranthus Retroflexus ◽  
Residue Level ◽  
Portulaca Oleracea ◽  
Negative Effects ◽  
Weed Density ◽  
Application Rates ◽  
Maximum Residue Level

Field experiments were conducted to evaluate the efficacy, selectivity and health harmlessness of four application rates of two pre-emergent herbicides (pethoxamid and dimethachlor) in the rocket [Eruca vesicaria (L.) Cavanilles)]. Pethoxamid was found to be less efficient on the total weed density (efficacy 86.0–93.3%) in comparison with the effect of dimethachlor (94.9–95.8%). Dimethachlor expressed an excellent efficacy on Echinochloa crus-galli (L.) P. Beauvois, Portulaca oleracea Linnaeus, Amaranthus retroflexus Linnaeus, Lamium purpureum Linnaeus, and Veronica persica Poiret from the lowest tested application rate (800 g/ha). Pethoxamid showed an excellent efficacy on E. crus-galli, Lamium purpureum, Lamium amplexicaule Linnaeus, V. persica, and P. oleracea. In higher application rates, pethoxamid controlled Chenopodium polyspermum Linnaeus and Chenopodium album Linnaeus. In contrast to mostly negative effects of dimethachlor, pethoxamid showed either no effects or positive ones on the rocket yield. Residues of both herbicides in the harvested product were always below a 'default limit', which is the baseline maximum residue level for food. The selectivity of pethoxamid at an application rate of 960 g/ha was good, herbicide residues in the rocket were not detected and the yield of the rocket increased.

PENENTUAN KADAR RESIDU TETRASIKLIN HCl PADA IKAN AIR TAWAR YANG BEREDAR DI PASAR SEGIRI MENGGUNAKAN METODE SPEKTROFOTOMETRI ULTRA VIOLET

2017 ◽  
Vol 2 (2) ◽  
pp. 173
Author(s):  
Henny Nurhasnawati ◽  
Siti Jubaidah ◽  
Novita Elfia
Keyword(s):  
Freshwater Fish ◽  
Ultra Violet ◽  
Standard Addition ◽  
Fish Farming ◽  
Residue Level ◽  
Ultraviolet Spectrophotometry ◽  
Maximum Residue Level ◽  
Traditional Market ◽  
Antibiotic Residue ◽  
Tetracycline Hcl

Tetracycline HCl is one of the most commonly used antibiotics in fish farming that aims to control diseases caused by bacteria. The purpose of this study was to determine the presence and the level of tetracycline HCl antibiotic residue in freshwater fishes sold at the Segiri traditional market. The method used in this research was a standard addition ultraviolet spectrophotometry. The results showed that residue level of tetracycline HCl in freshwater fish is 192,067 μg/g – 257,409 μg/g. These result was far exceeded the maximum residue level of tetracycline class antibiotics in meat and dairy based on SNI 01-6366-2000 that limit the residue not higher than 0.1 μg/g

scholarly journals Modification of the existing maximum residue level for ethephon in kaki/Japanese persimmons

EFSA Journal ◽  
2017 ◽  
Vol 15 (3) ◽  
Author(s):  
◽  
Alba Brancato ◽  
Daniela Brocca ◽  
Chloé De Lentdecker ◽  
Zoltan Erdos ◽  
...  
Keyword(s):  
Residue Level ◽  
Maximum Residue Level

scholarly journals Deltamethrin residues applied in different formulations in staked cucumber and the actions of insecticides on the pickleworm control

2008 ◽  
Vol 26 (3) ◽  
pp. 321-324 ◽  
Author(s):  
Gilberto C de Baptista ◽  
Luiz Roberto P Trevizan ◽  
André A Franco ◽  
Renato A da Silva
Keyword(s):  
Gas Chromatography ◽  
Pesticide Residues ◽  
Residue Level ◽  
Concentrate Suspension ◽  
Evaluation Period ◽  
Emulsifiable Concentrate ◽  
Maximum Residue Level ◽  
Low Levels ◽  
Vegetables And Fruits ◽  
Sampling Times

Pesticide residues, especially in vegetables and fruits, are a reason for concern with respect to the health of consumers and workers that need to return to areas that have been treated with these agrochemicals. The objectives of this experiment were to (a) study the behavior of deltamethrin residues from different formulations on cucumber fruits; and (b) correlate insecticide contents in the fruits with pickleworm control. Treatments were as follows: (a) control; (b) three 30 mL applications of deltamethrin 25 EC 100 L-1 water (emulsifiable concentrate formulation); (c) three 7.5 mL applications of deltamethrin 100 EC 100 L-1 water (emulsifiable concentrate); and (d) three 3.75 mL applications of deltamethrin 200 CS 100 L-1 water (concentrate suspension). Samples were taken at (-1), zero, 1; 3; 5; 7, and 14 days after the last application. Residues were determined by the gas chromatography technique, using an electron capture detector. In order to evaluate insecticide effectiveness, six infestation surveys were conducted during the same sampling times. Although at low levels, the deltamethrin residues in the fruits were above the maximum residue level (MRL = 0.03 mg kg-1), even one day after the end of the safety interval (2 days), and were higher for the CS formulation. The insecticide was effective to control the pest during the entire evaluation period.

Rate of decrease of the residual concentration of diazinon in cabbage

1980 ◽  
Vol 20 (105) ◽  
pp. 504
Author(s):  
JR Hargreaves ◽  
KJ Melksham
Keyword(s):  
Initial Period ◽  
Residue Level ◽  
Spray Application ◽  
Rapid Decay ◽  
Residual Concentration ◽  
First Order ◽  
First Order Kinetics ◽  
Maximum Residue Level

Analysis of diazinon residues in cabbages up to 14 days after the final spray application, showed an initial period of rapid decay followed by a period of slower decay, which approximates to first order kinetics. The Australian maximum residue level of 0.7 mg kg-1 diazinon for the whole cabbage was reached in 2-3 days in summer and 7-8 days in winter. The recommended Australia 14-day withholding period, combined with marketing of hearts alone, conformed to Japanese marketing requirements of 0.1 mg kg-1.

scholarly journals The Political Economy of Standards: Does MRLs Matter in Cottonseed and its Trade?

2017 ◽  
Vol II (I) ◽  
pp. 177-196
Keyword(s):  
Cottonseed Oil ◽  
Ordinary Least Squares ◽  
Residue Level ◽  
International Standards ◽  
The Political ◽  
Maximum Residue Limit ◽  
Maximum Residue Level ◽  
Maximum Residue Limits ◽  
Regression Estimators ◽  
Crude Cottonseed Oil

In this paper, we introduce three indices of trade which are consequently applied to the case maximum residue level, MRLs of pesticide. The aggregation indices of NTM i.e Li and Beghin index of trade, Heterogeneous index of trade (HIT) and actual heterogeneous index of trade (AHIT) regulations to compute their protectionism relative to international standards. The application of indices to Maximum Residue Limit (MRL) affecting cottonseed and its by-product i.e crude cottonseed oil and refined cottonseed oil, using a science-based standards Codex Alimentarius. In this analysis, the main aim of the article is to show the response of the maximum residue limits (MRLs) adopted by 50 importing countries on exports of the cottonseed commodities for the year 2005 to 2014. In this study, we estimate the augmented gravity model using the ordinary least squares (OLS) and Poisson regression estimators. The results show that maximum residue limits (MRLs) have a trade increasing effect on exports of the cottonseed commodities.

scholarly journals Modification of the existing maximum residue level for tebuconazole in beans with pods

EFSA Journal ◽  
2017 ◽  
Vol 15 (6) ◽  
Author(s):  
◽  
Alba Brancato ◽  
Daniela Brocca ◽  
Chloé De Lentdecker ◽  
Zoltan Erdos ◽  
...  
Keyword(s):  
Residue Level ◽  
Maximum Residue Level
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