The effect of instrument resolution on diffusion coefficients measured using NMR spectroscopy

10.1617/13676 ◽  
2001 ◽  
Vol 34 (241) ◽  
pp. 389-395
Author(s):  
G. H. Galbraith
Keyword(s):  
Nmr Spectroscopy ◽  
Diffusion Coefficients ◽  
Instrument Resolution

The effect of instrument resolution on diffusion coefficients measured using NMR spectroscopy

2001 ◽  
Vol 34 (7) ◽  
pp. 389-395
Author(s):  
G. H. Galbraith ◽  
J. Guo ◽  
R. C. McLean ◽  
A. S. M. Y. Munsi ◽  
C. H. Sanders
Keyword(s):  
Nmr Spectroscopy ◽  
Diffusion Coefficients ◽  
Instrument Resolution

scholarly journals Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1723 ◽  
Author(s):  
Martin Pulst ◽  
Yury Golitsyn ◽  
Detlef Reichert ◽  
Jörg Kressler
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Nmr Spectroscopy ◽  
Diffusion Coefficients ◽  
Important Class ◽  
Spectroscopy Data ◽  
Ion Conductivities ◽  
Electrochemical Devices ◽  
Pfg Nmr ◽  
Conductive Properties ◽  
Triazolium Salts

1,2,3-Triazolium salts are an important class of materials with a plethora of sophisticated applications. A series of three novel 1,3-dimethyl-1,2,3-triazolium salts with fluorine, containing anions of various size, is synthesized by methylation of 1,2,3-triazole. Their ion conductivity is measured by impedance spectroscopy, and the corresponding ionicities are determined by diffusion coefficients obtained from 1H and 19F pulsed field gradient nuclear magnetic resonance (PFG NMR) spectroscopy data, revealing that the anion strongly influences their ion conductive properties. Since the molar ion conductivities and ionicities of the 1,3-dimethyl-1,2,3-triazolium salts are enhanced in comparison to other 1,2,3-triazolium salts with longer alkyl substituents, they are promising candidates for applications as electrolytes in electrochemical devices.

scholarly journals Diffusional Properties of Methanogenic Granular Sludge: 1H NMR Characterization

2003 ◽  
Vol 69 (11) ◽  
pp. 6644-6649 ◽  
Author(s):  
Piet N. L. Lens ◽  
Rakel Gastesi ◽  
Frank Vergeldt ◽  
Adriaan C. van Aelst ◽  
Antonio G. Pisabarro ◽  
...  
Keyword(s):  
Diffusion Coefficient ◽  
Relaxation Time ◽  
Nmr Spectroscopy ◽  
Diffusion Coefficients ◽  
Metal Sulfide ◽  
Free Water ◽  
Granular Sludge ◽  
Self Diffusion ◽  
Nmr Characterization ◽  
Self Diffusion Coefficient

ABSTRACT The diffusive properties of anaerobic methanogenic and sulfidogenic aggregates present in wastewater treatment bioreactors were studied using diffusion analysis by relaxation time-separated pulsed-field gradient nuclear magnetic resonance (NMR) spectroscopy and NMR imaging. NMR spectroscopy measurements were performed at 22°C with 10 ml of granular sludge at a magnetic field strength of 0.5 T (20 MHz resonance frequency for protons). Self-diffusion coefficients of H2O in the investigated series of mesophilic aggregates were found to be 51 to 78% lower than the self-diffusion coefficient of free water. Interestingly, self-diffusion coefficients of H2O were independent of the aggregate size for the size fractions investigated. Diffusional transport occurred faster in aggregates growing under nutrient-rich conditions (e.g., the bottom of a reactor) or at high (55°C) temperatures than in aggregates cultivated in nutrient-poor conditions or at low (10°C) temperatures. Exposure of aggregates to 2.5% glutaraldehyde or heat (70 or 90°C for 30 min) modified the diffusional transport up to 20%. In contrast, deactivation of aggregates by HgCl2 did not affect the H2O self-diffusion coefficient in aggregates. Analysis of NMR images of a single aggregate shows that methanogenic aggregates possess a spin-spin relaxation time and self-diffusion coefficient distribution, which are due to both physical (porosity) and chemical (metal sulfide precipitates) factors.

Diffusion of molecular probes and the effects of their interactions with polymer matrices as studied by pulsed-field gradient NMR spectroscopy

2008 ◽  
Vol 86 (6) ◽  
pp. 579-585 ◽  
Author(s):  
Héloise Thérien-Aubin ◽  
Wilms E Baille ◽  
X X Zhu
Keyword(s):  
Nmr Spectroscopy ◽  
Carboxylic Acid ◽  
Field Gradient ◽  
Diffusion Coefficients ◽  
Molecular Probes ◽  
Poly Vinyl Alcohol ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Self Diffusion ◽  
Carboxylic Acid Groups

Pulsed-field gradient NMR spectroscopy was used to study the interactions between small molecular probes and polymers bearing interacting groups. The self-diffusion coefficients of ethylene glycol and its oligomers and their methyl ester derivatives in poly(vinyl alcohol) gels were measured to study the effect of hydrogen bonding. The self-diffusion coefficients of small molecular probes containing hydroxyl, amine, and carboxylic acid groups were determined in several polymer matrices including poly(vinyl alcohol), poly(allylamine), and poly(acrylic acid) bearing lateral hydroxyl, amine, and carboxylic acid groups, respectively. The ionic interactions between the functional groups of the diffusants and of the polymers exhibited a marked effect on the diffusion of the molecular probes. For example, the reduced self-diffusion coefficients measured for a diffusant with a carboxylic acid group in a poly(allylamine) matrix were shown to be lower even though the molecular masses of the diffusants are similar.Key words: pulsed-field gradient NMR spectroscopy, self-diffusion, intermolecular interactions.

Diffusion Coefficients of Xenon in Polystyrene Determined by Xenon-129 NMR Spectroscopy

1996 ◽  
Vol 29 (6) ◽  
pp. 2138-2142 ◽  
Author(s):  
Jeffrey H. Simpson ◽  
Wen ◽  
Alan A. Jones ◽  
Paul T. Inglefield ◽  
John T. Bendler
Keyword(s):  
Nmr Spectroscopy ◽  
Diffusion Coefficients

What use for polysilsesquioxane lithium salts in lithium batteries?

2016 ◽  
Vol 40 (9) ◽  
pp. 7657-7662
Author(s):  
Mathieu Meyer ◽  
Lydie Viau ◽  
Ahmad Mehdi ◽  
Sophie Monge ◽  
Patrick Judeinstein ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Nmr Spectroscopy ◽  
High Molecular Weight ◽  
Lithium Batteries ◽  
Diffusion Coefficients ◽  
Transference Numbers ◽  
Lithium Salts ◽  
Self Diffusion ◽  
Acetonitrile Solutions ◽  
Pfg Nmr

High molecular weight polysilsesquioxane lithium salts were prepared. Ion self-diffusion coefficients and transference numbers in acetonitrile solutions were quantified by PFG NMR spectroscopy.

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