Self-assembled InP Quantum Dot -TiO2 Solid Grätzel Solar Cell

2003 ◽  
Vol 764 ◽  
Author(s):  
Tingying Zeng ◽  
Elizabeth Gladwin ◽  
Richard O. Claus
Keyword(s):  
Short Circuit ◽  
Cost Effective ◽  
Short Circuit Current ◽  
Average Diameter ◽  
Open Circuit ◽  
Hole Transport ◽  
Solar Simulator ◽  
Light Power ◽  
P Type ◽  
Conversion Efficiencies

AbstractThe processing of Solid Grätzel Solar Cells (SGSCs) offers advantages of cost effective fabrication, possible flexible products, and high incident photon-to-electron conversion efficiencies (IPCE). In this paper, InP quantum dots (QDs) were synthesized and used as the photosensitizer to design new generation SGSCs. An organic p-type charge transport material (spiro-OMeTAD) was used as the hole-transport material (HTM). The InP QD has an average diameter of approximately 3nm. Preliminary research indicates that InP QD is a promising photosensitizer, which allows the sensitized SGSC TiO2 nanocrystalline cell to achieve over 400mV open circuit photovoltage, and a short-circuit current greater than 0.035mA/cm2 under the illumination of a solar simulator with an integrated light power of 58mW/cm2.

scholarly journals GaInP/GaAs/poly-Si Multi-Junction Solar Cells by in Metal Balls Bonding

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 726
Author(s):  
Ray-Hua Horng ◽  
Yu-Cheng Kao ◽  
Apoorva Sood ◽  
Po-Liang Liu ◽  
Wei-Cheng Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Low Temperature ◽  
Triple Junction ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Metal Line ◽  
Solar Simulator ◽  
Junction Solar Cell

In this study, a mechanical stacking technique has been used to bond together the GaInP/GaAs and poly-silicon (Si) solar wafers. A GaInP/GaAs/poly-Si triple-junction solar cell has mechanically stacked using a low-temperature bonding process which involves micro metal In balls on a metal line using a high-optical-transmission spin-coated glue material. Current–voltage measurements of the GaInP/GaAs/poly-Si triple-junction solar cells have carried out at room temperature both in the dark and under 1 sun with 100 mW/cm2 power density using a solar simulator. The GaInP/GaAs/poly-Si triple-junction solar cell has reached an efficiency of 24.5% with an open-circuit voltage of 2.68 V, a short-circuit current density of 12.39 mA/cm2, and a fill-factor of 73.8%. This study demonstrates a great potential for the low-temperature micro-metal-ball mechanical stacking technique to achieve high conversion efficiency for solar cells with three or more junctions.

Solar Cell Contacts Using Nano-Sized Dispersions

1999 ◽  
Vol 581 ◽  
Author(s):  
Doug Schulz ◽  
R. Ribelin ◽  
X. Wu ◽  
K.M. Jones ◽  
R.J. Matson ◽  
...  
Keyword(s):  
Solar Cells ◽  
Spray Deposition ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Cdte Layer ◽  
Open Circuit ◽  
Alloy Formation ◽  
Current Densities ◽  
P Type ◽  
Open Circuit Voltages

ABSTRACTNano-sized dispersions have been employed as precursor inks for the spray deposition of contacts to both Si and CdTe materials. In the case of Si, nano-sized Al particles (nano-Al) were dispersed and spray deposited onto p-type Si. Annealing above the eutectic temperature causes alloy formation yielding a p+ layer with p ∼ 10−4 Ω•cm. For CdTe, nano-sized Te particles (nano-Te) were dispersed and sprayed onto CdTe/CdS/SnO2/glass heterostructures. Contact to the CdTe layer occurred during a 30 min anneal in He (T = 215 to 255 °C). These solar cells were finished by spin-coating the Te layer with Ag paint and subsequently annealing in air (100 °C / 1 h). This approach produces solar cells with open circuit voltages (Voc) from 720 to 800 mV, short circuit current densities (Jsc) from 18 to 20 mA/cm2 and efficiencies up to 10.3%. The performance of these cells was similar to those produced using the standard NREL contact.

Optical Simulation and Investigation of the Effect of Hysteresis on the Perovskite Solar Cells

NANO ◽  
2019 ◽  
Vol 14 (10) ◽  
pp. 1950127 ◽  
Author(s):  
Farhad Jahantigh ◽  
S. M. Bagher Ghorashi
Keyword(s):  
Grain Size ◽  
Solar Cells ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

Perovskite solar cells have recently been considered to be an auspicious candidate for the advancement of future photovoltaic research. A power conversion efficiency (PCE) as high as 22% has been reported to be reached, which can be obtained through an inexpensive and high-throughput solution process. Modeling and simulation of these cells can provide deep insights into their fundamental mechanism of performance. In this paper, two different perovskite solar cells are designed by using COMSOL Multiphysics to optimize the thickness of each layer and the overall thickness of the cell. Electric potential, electron and hole concentrations, generation rate, open-circuit voltage, short-circuit current and the output power were calculated. Finally, PCEs of 20.7% and 26.1% were predicted. Afterwards, according to the simulation results, the role of the hole transport layer (HTL) was investigated and the optimum thickness of the perovskite was measured to be 200[Formula: see text]nm for both cells. Therefore, the spin coating settings are selected so that a coating with this thickness for cell 1 is deposited. In order to compare the performance of HTM layer, solar cells with a Spiro-OMeTAD HTM and without the HTM layer in their structure were fabricated. According to the obtained photovoltaic properties, the solar cell made with Spiro-OMeTAD has a more favorable open-circuit voltage ([Formula: see text]), short-circuit current density ([Formula: see text]), fill factor (FF) and PCE compared to the cell without the HTM layer. Also, hysteresis depends strongly on the perovskite grain size, because large average grain size will lead to an increase in the grain’s contact surface area and a decrease in the density of grain boundaries. Finally, according to the results, it was concluded that, in the presence of a hole transport layer, ion transfer was better and ion accumulation was less intense, and therefore, the hysteresis decreases.

Design and modeling of an SJ infrared solar cell approaching upper limit of theoretical efficiency

2018 ◽  
Vol 32 (02) ◽  
pp. 1850014 ◽  
Author(s):  
G. S. Sahoo ◽  
G. P. Mishra
Keyword(s):  
Solar Cell ◽  
Quantum Efficiency ◽  
Conversion Efficiency ◽  
Internal Quantum Efficiency ◽  
Spectral Response ◽  
Short Circuit ◽  
Cost Effective ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit

Recent trends of photovoltaics account for the conversion efficiency limit making them more cost effective. To achieve this we have to leave the golden era of silicon cell and make a path towards III–V compound semiconductor groups to take advantages like bandgap engineering by alloying these compounds. In this work we have used a low bandgap GaSb material and designed a single junction (SJ) cell with a conversion efficiency of 32.98%. SILVACO ATLAS TCAD simulator has been used to simulate the proposed model using both Ray Tracing and Transfer Matrix Method (under 1 sun and 1000 sun of AM1.5G spectrum). A detailed analyses of photogeneration rate, spectral response, potential developed, external quantum efficiency (EQE), internal quantum efficiency (IQE), short-circuit current density (J[Formula: see text]), open-circuit voltage (V[Formula: see text]), fill factor (FF) and conversion efficiency ([Formula: see text]) are discussed. The obtained results are compared with previously reported SJ solar cell reports.

Photoelectrical and Photovoltaic Peroperties of n-ZnO/p-Si Heterojunction

2011 ◽  
Vol 399-401 ◽  
pp. 1477-1480
Author(s):  
Yan Li Xu ◽  
Jin Hua Li
Keyword(s):  
Solar Cell ◽  
Silicon Solar Cell ◽  
Ion Beam ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Textured Surface ◽  
Si Solar Cell ◽  
The One ◽  
P Type

n-ZnO thin films doped In with 2 atm.% were deposited on p-type silicon wafer with textured surface by Ion Beam Enhanced Deposition method, after annealing and prepared front and back electrodes, the n-ZnO/p-Si heterojunction samples were fabricated. The photoelectric property of the sample were measured and compared with silicon solar cell. The result indicated the saturated photocurrent of n-ZnO/p-Si heterojunction was 20% greater than one of the Si solar cell. It means the ZnO/Si heterojunction has a higher ability of produce photoelectron then one of silicon solarcell. The result of the photovoltaic test of n-ZnO/p-Si heterojunction show The open circuit voltage and short-circuit current of the n-ZnO/p-Si heterojunction was 400mV and 5.5mA/cm2 respectively. It was much smaller than the one of silicon solar cells. The reason was discussed

PHOTOELECTRICAL PROPERTIES OF p-TYPE AND n-TYPE ELECTRICAL CONDUCTIVITY AMORPHOUS CARBON THIN FILMS FOR APPLICATION IN ECONOMICAL CARBON-BASED SOLAR CELLS

2005 ◽  
Vol 12 (03) ◽  
pp. 343-350 ◽  
Author(s):  
M. RUSOP ◽  
T. SOGA ◽  
T. JIMBO
Keyword(s):  
Energy Conversion ◽  
Conversion Efficiency ◽  
Fill Factor ◽  
Short Circuit ◽  
Wavelength Region ◽  
Short Circuit Current ◽  
Energy Conversion Efficiency ◽  
Open Circuit ◽  
Photon Absorption ◽  
P Type

The successful deposition of boron ( B )-doped p-type ( p-C:B ) and phosphorous ( P )-doped n-type ( n-C:P ) carbon ( C ) films, and fabrication of p-C:B on silicon ( Si ) substrate ( p-C:B/n-Si ) and n-C:P/p-Si cells by the technique of pulsed laser deposition (PLD) using graphite target is reported. The cells' performances are represented in the dark I–V rectifying curve and I–V working curve under illumination when exposed to AM 1.5 illumination condition (100 mW/cm2, 25°C). The open circuit voltage (V oc ) and short circuit current density (J sc ) for p-C:B/n-Si are observed to vary from 230–250 mV and 1.5–2.2 mA/cm2, respectively, and to vary from 215–265 mV and 7.5–10.5 mA/cm2, respectively, for n-C:P/p-Si cells. The p-C:B/n-Si cell fabricated using the target with the amount of B by 3 Bwt% shows highest energy conversion efficiency, η = 0.20%, and fill factor, FF = 45%, while, the n-C:P/p-Si cell with the amount of P by 7 Pwt% shows highest energy conversion efficiency, η = 1.14%, and fill factor, FF = 41%. The quantum efficiencies (QE) of the p-C:B/n-Si and n-C:P/p-Si cells are observed to improve with Bwt% and Pwt%, respectively. The contributions of QE are suggested to be due to photon absorption by carbon layer in the lower wavelength region (below 750 nm) and Si substrates in the higher wavelength region. The dependence of B and P content on the electrical and optical properties of the deposited films, and the photovoltaic characteristics of the respective p-C:B/n-Si and n-C:P/p-Si heterojunction photovoltaic cells, are discussed.

scholarly journals Chalcogenide glass-ceramic with self-organized heterojunctions: application to photovoltaic solar cells

2018 ◽  
Vol 9 ◽  
pp. 3 ◽  
Author(s):  
Xianghua Zhang ◽  
Ilia Korolkov ◽  
Bo Fan ◽  
Michel Cathelinaud ◽  
Hongli Ma ◽  
...  
Keyword(s):  
Thin Films ◽  
Solar Cells ◽  
Chalcogenide Glass ◽  
Glass Ceramic ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Iodine Doping ◽  
P Type ◽  
Photovoltaic Solar Cells

In this work, we present for the first time the concept of chalcogenide glass-ceramic for photovoltaic applications with the GeSe2–Sb2Se3–CuI system. It has been demonstrated that thin films, deposited with the sputtering technique, are amorphous and can be crystallized with appropriate heat treatment. The thin film glass-ceramic behaves as a p-type semiconductor, even if it contains p-type Cu2GeSe3and n-type Sb2Se3. The conductivity of Sb2Se3has been greatly improved by appropriate iodine doping. The first photovoltaic solar cells based on the association of iodine-doped Sb2Se3and the glass-ceramic thin films give a short-circuit current density JSCof 10 mA/cm2and an open-circuit voltage VOCof 255 mV, with a power conversion efficiency of about 0.9%.

scholarly journals Performance of Natural Dye Extracted from Annatto, Black Plum, Turmeric, Red Spinach, and Cactus as Photosensitizers in TiO2NP/TiNT Composites for Solar Cell Applications

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Shibu Joseph ◽  
Albin John P. Paul Winston ◽  
S. Muthupandi ◽  
P. Shobha ◽  
S. Mary Margaret ◽  
...  
Keyword(s):  
Solar Cell ◽  
Low Cost ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Photovoltaic Properties ◽  
Ft Ir ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

This paper is aimed at how to select, extract, and characterize natural dyes and to use them as sensitizers in dye-sensitized solar cells (DSSCs). Dyes obtained from fresh sources of annatto fruits, black plums, cactus fruits, turmeric roots, and red spinach leaves were used as sensitizers. The dye pigments were analyzed using UV-Vis spectrophotometer and FT-IR for the characterization of their spectral properties. The combination from Titanium dioxide paste with the powdered nanotubes was used as photoanodes for DSSCs. The photovoltaic properties of the DSSCs such as efficiency, fill factor, open-circuit voltage, and short circuit current were studied using a standard illumination of air-mass 1.5 global (AM 1.5 G) having an irradiance of 100 mW/cm2. The highest power conversion efficiencies (η) of 0.7% was achieved for the DSSCs fabricated using dye extracted from annatto fruits and 0.4% each for dyes extracted from black plum fruits and cactus fruits, respectively. The widespread accessibility of these fruits, roots, and leaves and ease of extraction of dyes from these ordinarily available natural resources render them unique and low-cost candidates for solar cell fabrication.

Nanoscale Phase Separation in Ternary Organic Solar Cells Based on PTB7:PC70BM:IC70BA

2021 ◽  
Vol 21 (11) ◽  
pp. 5749-5755
Author(s):  
Chang Li ◽  
Wei Li ◽  
Xiaoxiang Sun ◽  
Jifei Wang ◽  
Jiayou Tao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Phase Separation ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Short Circuit ◽  
Weight Ratio ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Hole Transport ◽  
Fullerene Derivative

As a fullerene derivative, IC70BA is widely used in the ternary organic solar cells (TOSCs) to increase the open circuit voltage (Voc) of the devices. Unfortunately, most of the literature shows that IC70BA will lead to a reduction in the short-circuit current density (Jsc) and fill factor (FF). In this work, IC70BA is added to the PTB7:PC70BM binary system to form the ternary system, which is composed of one donor and two fullerene acceptors. Surprisingly, the addition of IC70BA does not immediately lead to a decrease in Jsc and FF. In fact, the appropriate weight ratio of IC70BA in fullerenes can simultaneously increase the Voc, Jsc, and FF of the TOSCs. The synergistic optimization of the surface and bulk morphology of the ternary active layer suppresses the attenuation of Jsc and FF. The smooth surface and suitable phase separation size effectively guarantee the separation, transport and extraction of the charge. Moreover, the addition of IC70BA can significantly improve the hole transport capacity of the active layer, and the optimal hole mobility is 5.13 – 10”4 cm2V–1S–1. Finally, the TOSCs with 10% weight ratio of IC70BA gives the optimal PCE of 9.24% and ideality factor of 2.3.

Comparative Study of Efficient Design, Control and Monitoring of Solar Power Using Internet of Things

2020 ◽  
Vol 18 (5) ◽  
pp. 419-426
Author(s):  
Parminder Kaur ◽  
Vikas Pandey ◽  
Balwinder Raj
Keyword(s):  
Internet Of Things ◽  
Solar Power ◽  
Short Circuit ◽  
Cost Effective ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Dust Particles ◽  
Efficient Design ◽  
Factors Affecting ◽  
Module Efficiency

The shortage of electricity is a major constraint to economic growth. Renewable energy such as solar energy has many advantages but also has many challenges to enhance its efficiency which is limited by the weather changes, dust particles, and material dependant properties. This affect various parameters like fill factor, short circuit current (jsc), open-circuit voltage (Voc) and module efficiency. This paper represents different materials used in solar cell structures and gives a realistic approach of factors affecting the performance of photovoltaic modules. The material used must produce cost-effective solar cells by reducing the amount of silicon material used in its production and enhance the power output. To enhance the performance of the PV cell, various methods and technologies are used. Effective use of solar power can be obtained using Internet of Things (IoT) technology which is used for solar tracking, monitoring, and forecasting.

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