Ultrashallow Junction Formation and Gate Activation in Deep-Submicron CMOS

2000 ◽  
Vol 610 ◽  
Author(s):  
P. A. Stolk ◽  
F. N. Cubaynes ◽  
V. M. H. Meyssen ◽  
G. Mannino ◽  
N. E. B. Cowern ◽  
...  

AbstractThis paper addresses the optimization of ion implantation and rapid thermal annealing for the fabrication of shallow junctions and the activation of polycrystalline silicon gates in deepsubmicron CMOS transistors. Achieving ultrashallow, low-resistance junctions was studied by combining low-energy B and As implantation with spike annealing. In addition, experiments using B doping marker superlattices were performed to identify the critical physical effects underlying dopant activation and diffusion. The combination of high ramp rates (∼100 °C/s) and ∼1 s cycles at temperatures as high as 1100 °C can be used to improve dopant activation without inducing significant thermal diffusion after TED has completed. MOS capacitors were used to identify the implantation and annealing conditions needed for adequate activation of the gate electrode. In comparison to the conventional recrystallized amorphous Si gates, it was found that fine-grained poly-Si allows for the use of lower processing temperatures or shorter annealing times while improving the gate activation level. The fine-grained crystal structure enhances the de-activation of B dopants in PMOS gates during the thermal treatments following gate activation. Yet, the resulting dopant loss stays within acceptable limits as verified by excellent 0.18 μm device performance. The feasibility of spike annealing and poly-Si gate materials for 100-nm technology was proven by full integration using gate lengths down to 80 nm.

1989 ◽  
Vol 4 (3) ◽  
pp. 526-529 ◽  
Author(s):  
Mireille Treuil Clapp ◽  
Zhang Jian ◽  
Tariq Manzur

Alloys of Nb73Al12Si14.5B0.5 were rapidly solidified into amorphous ribbons using the melt spinning technique. These were isothermally annealed at temperatures ranging from 660 to 780 °C. The A15 phase began to crystallize at 700 °C and small amounts of second phases appeared at the higher temperatures. Crystallization was dependent on quenching rate as well as annealing conditions. Below 750 °C nucleation was nonuniform and was enhanced by surfaces and quenched-in nuclei. Above 750 °C nucleation became more uniform and completely crystalline ribbons with equiaxed grains ∼30 nm in diameter were obtained. These ultra fine grained ribbons had extremely high superconducting critical current densities of 8 × 1010 A/m2 and 5 × 1010 A/m2 at magnetic fields of 0.5 and 15 tesla, respectively, at 4.2 K.


2000 ◽  
Vol 29 (8) ◽  
pp. 1027-1032 ◽  
Author(s):  
H. -F. Li ◽  
S. Dimitrijev ◽  
D. Sweatman ◽  
H. B. Harrison

2019 ◽  
Vol 954 ◽  
pp. 104-108
Author(s):  
Heng Yu Xu ◽  
Cai Ping Wan ◽  
Jin Ping Ao

We fabricated SiO2/4H-SiC (0001) MOS capacitors with oxidation temperature at 1350°C, followed by post-oxide-annealing (POA) in NO simply by the control of POA temperatures and times. A correlation between the reduction of interface state density and the increasing of N concentration at the interface has been indicated by C-ψs measurement and secondary ion mass spectrometry (SIMS). The SiO2/4H-SiC interface density decreased when POA temperature was elevated, and the sample annealed at 1300°C for 30min showed the lowest interface state density about 1.5×1012 cm-2eV-1 at Ec-E=0.3 eV when the N concentration is 11.5×1020 cm-3. Meanwhile, the SiO2 /4H-SiC interface annealed at 1200°C for 120min showed the highest N concentration at the 4H-SiC/SiO2 interface is 12.5×1020 cm-3, whereas the interface state density is 2.5×1012 cm-2eV-1 at Ec-E=0.3 eV higher than 1300°C for 30min. The results suggested that higher temperature POA might be much more efficiency in decreased the 4H-SiC MOS interface density with increasing the N area concentration.


2019 ◽  
Vol 30 (11) ◽  
pp. 10302-10310
Author(s):  
Yifan Jia ◽  
Hongliang Lv ◽  
Xiaoyan Tang ◽  
Chao Han ◽  
Qingwen Song ◽  
...  

2003 ◽  
Vol 806 ◽  
Author(s):  
Uwe Köster ◽  
Rainer Janlewing

ABSTRACTNanocrystalline materials can be produced e.g. by high energy ball milling or vacuum condensation; these methods require powder compaction as a final step. In another route - the nano-crystallization - metallic glasses are used as precursors for nanocrystalline materials without any porosity. The conditions for achieving an ultra-fine grained material by crystallization are small growth, but large nucleation rates. Whereas in Fe-Ni-B glasses the finest microstructure is produced at annealing temperatures above the glass transition close to the maximum of the nucleation rate, in Zr-based metallic glasses nanocrystallization was found to proceed only at relatively low temperatures below the glass transition. The aim of this contribution is to study systematically the micromechanisms involved in the microstructural design.Crystallization was studied in detail in Fe-Ni-B and Zr-based metallic glasses by means of TEM, X-ray diffraction and DSC. Nucleation and growth rates were estimated from crystallization statistics. By modeling the obtained time-dependent nucleation rates in the framework of diffusion controlled classical nucleation all relevant crystallization parameter could be derived. Using these data TTT-diagrams could be drawn and annealing conditions deducted, e.g. for the formation of a nanocrystalline alloy.Isothermal DSC plots for polymorphic crystallization can only be explained with a very significant decrease in the growth rate at later stages. Such a decrease is assumed to result from stresses building up during crystallization beyond the percolation limit for the crystalline phase; under this condition stresses resulting from the volume change during crystallization cannot be compensated by viscous flow as in the case of isolated crystals in an amorphous matrix.


2012 ◽  
Vol 717-720 ◽  
pp. 769-772
Author(s):  
Harsh Naik ◽  
Z. Li ◽  
H. Issa ◽  
Y.L. Tian ◽  
T. Paul Chow

The strong covalent bond of SiC imposes harsh post implantation annealing condition requirement for SiC MOS devices. As a consequence the effect of the annealing conditions on the channel region of the MOS devices becomes critical. High temperature microwave annealing has been shown to be an attractive alternative to conventional thermal annealing techniques. The effect of high temperature rapid microwave annealing on the performance of 4H-SiC MOS capacitors has been studied in this paper. Annealing temperatures ranging from 1600°C up to 2000°C for 30secs is used and the effect of annealing conditions is studied via C-V measurements on MOS capacitors.


2008 ◽  
Vol 1070 ◽  
Author(s):  
Paul J Timans ◽  
Yao Zhi Hu ◽  
Jeff Gelpey ◽  
Steve McCoy ◽  
Wilfried Lerch ◽  
...  

ABSTRACTLow thermal budget annealing approaches, such as millisecond annealing or solid-phase epitaxy (SPE) of amorphized silicon, electrically activate implanted dopants while minimizing diffusion. However, it is also important to anneal damage to the crystal lattice in order to minimize junction leakage. Annealing experiments were performed on low-energy B implants into both crystalline silicon and into wafers pre-amorphized by Ge implantation. Some wafers also received As implants for halo-style doping, and in some cases the halo implants were pre-annealed at 1050°C before the B-doping. The B-implants were annealed by either SPE at 650°C, spike annealing at 1050°C, or by millisecond annealing with flash-assisted RTP™ (fRTP™) at temperatures between 1250°C and 1350°C. Residual damage was characterized by photoluminescence and non-contact junction leakage current measurements, which permit rapid assessment of damage removal efficacy. Damage from the heavy ions used for the halo and pre-amorphization implants dominates the defect annealing behaviour. The halo doping is the critical factor in determining junction leakage current. Millisecond annealing at high temperatures helps to minimize residual damage while limiting diffusion.


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