Modeling The Evolution of Ellipsometric Data During The Thermally Induced Pt-Silicide Formation: Activation Energies and Prefactors

1999 ◽  
Vol 569 ◽  
Author(s):  
L. Ley ◽  
T. Stark ◽  
M. Hundhausen ◽  
H. Gruenleitner
Keyword(s):  
Accurate Determination ◽  
Reaction Model ◽  
Activation Energies ◽  
Optical Data ◽  
Heating Rates ◽  
Actual Distribution ◽  
Thermally Induced ◽  
Reaction Rate Constants ◽  
Reaction Fronts ◽  
Temperature Signal

ABSTRACTThe formation of Pt silicide (PtSi) by the thermally activated reaction of a 23 nm Pt layer on Si was monitored in situ by ellipsometry. Characteristic changes in the ellipsometric angles as a function of temperature signal the approach of two reaction fronts to the surface: one belonging to the Pt/Pt2Si and the other to the Pt2Si/PtSi interface. An analysis of the evolution of the ellipsometric angles as a function of temperature for different heating rates allows the accurate determination of the average activation energies of the two reactions. From a modeling of the optical data in terms of a specific reaction model further kinetic parameters such as the reaction rate constants and the actual distribution of activation energies have been deduced.

Heat Transfer and Thermal Stress Analysis of an Optoelectronic Package

1991 ◽  
Vol 113 (3) ◽  
pp. 258-262 ◽  
Author(s):  
J. G. Stack ◽  
M. S. Acarlar
Keyword(s):  
Heat Transfer ◽  
Thermal Management ◽  
Power Dissipation ◽  
Point Of View ◽  
Optical Data ◽  
Data Link ◽  
Element Analysis ◽  
Thermally Induced ◽  
Temperature Changes ◽  
Induced Stresses

The reliability and life of an Optical Data Link transmitter are inversely related to the temperature of the LED. It is therefore critical to have efficient packaging from the point of view of thermal management. For the ODL® 200H devices, it is also necessary to ensure that all package seals remain hermetic throughout the stringent military temperature range requirements of −65 to +150°C. For these devices, finite element analysis was used to study both the thermal paths due to LED power dissipation and the thermally induced stresses in the hermetic joints due to ambient temperature changes

Global Reaction Model to Describe the Kinetics of Catalytic Pyrolysis of Coffee Grounds Waste

2017 ◽  
Vol 899 ◽  
pp. 173-178 ◽  
Author(s):  
Ronydes Batista Jr. ◽  
Bruna Sene Alves Araújo ◽  
Pedro Ivo Brandão e Melo Franco ◽  
Beatriz Cristina Silvério ◽  
Sandra Cristina Danta ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Large Scale ◽  
Catalytic Pyrolysis ◽  
Petroleum Products ◽  
Reaction Model ◽  
Heating Rates ◽  
Coffee Grounds ◽  
One Step ◽  
Global Reaction ◽  
The One

In view of the constant search for new sources of renewable energy, the particulate agro-industrial waste reuse emerges as an advantageous alternative. However, despite the advantages of using the biomass as an energy source, there is still strong resistance as the large-scale replacement of petroleum products due to the lack of scientifically proven efficient conversion technologies. In this context, the pyrolysis is presented as one of the most widely used thermal decomposition processes. The knowledge of aspects of chemical kinetics, thermodynamics these will, heat and mass transfer, are so important, since influence the quality of the product. This paper presents a kinetic study of slow pyrolysis of coffee grounds waste from dynamic thermogravimetric experiments (TG), using different powder catalysts. The primary thermal decomposition was described by the one-step reaction model, which considers a single global reaction. The kinetic parameters were estimated using nonlinear regression and the differential evolution method. The coffee ground waste was dried at 105°C for 24 hours. The sample in nature was analyzed at different heating rates, being 10, 15, 20, 30 and 50 K/min. In the catalytic pyrolysis, about 5% (w/w) of catalyst were added to the sample, at a heating rate of 30 K/min. The results show that the one-step model does not accurately represent the data of weight loss (TG) and its derivative (DTG), but can do an estimative of the activation energy reaction, and can show the differences caused by the catalysts. Although no one can say anything about the products formed with the addition of the catalyst, it would be necessary to micro-pyrolysis analysis, we can say the influence of the catalyst in the samples, based on the data obtained in thermogravimetric tests.

scholarly journals Farmland Parcel Mapping in Mountain Areas Using Time-Series SAR Data and VHR Optical Images

2020 ◽  
Vol 12 (22) ◽  
pp. 3733
Author(s):  
Wei Liu ◽  
Jian Wang ◽  
Jiancheng Luo ◽  
Zhifeng Wu ◽  
Jingdong Chen ◽  
...  
Keyword(s):  
Time Series ◽  
Time Profile ◽  
Classification Method ◽  
Guizhou Province ◽  
Optical Data ◽  
Time Series Classification ◽  
Mountainous Areas ◽  
Mountain Areas ◽  
Actual Distribution ◽  
Sar Data

Accurate, timely, and reliable farmland mapping is a prerequisite for agricultural management and environmental assessment in mountainous areas. However, in these areas, high spatial heterogeneity and diversified planting structures together generate various small farmland parcels with irregular shapes that are difficult to accurately delineate. In addition, the absence of optical data caused by the cloudy and rainy climate impedes the use of time-series optical data to distinguish farmland from other land use types. Automatic delineation of farmland parcels in mountain areas is still a very difficult task. This paper proposes an innovative precise farmland parcel extraction approach supported by very high resolution(VHR) optical image and time series synthetic aperture radar(SAR) data. Firstly, Google satellite imagery with a spatial resolution of 0.55 m was used for delineating the boundaries of ground parcel objects in mountainous areas by a hierarchical extraction scheme. This scheme divides farmland into four types based on the morphological features presented in optical imagery, and designs different extraction models to produce each farmland type, respectively. The potential farmland parcel distribution map is then obtained by the layered recombination of these four farmland types. Subsequently, the time profile of each parcel in this map was constructed by five radar variables from the Sentinel-1A dataset, and the time-series classification method was used to distinguish farmland parcels from other types. An experiment was carried out in the north of Guiyang City, Guizhou Province, Southwest China. The result shows that, the producer’s accuracy of farmland parcels obtained by the hierarchical scheme is increased by 7.39% to 96.38% compared with that without this scheme, and the time-series classification method produces an accuracy of 80.83% to further obtain the final overall accuracy of 96.05% for the farmland parcel maps, showing a good performance. In addition, through visual inspection, this method has a better suppression effect on background noise in mountainous areas, and the extracted farmland parcels are closer to the actual distribution of the ground farmland.

scholarly journals Kinetic Analysis of the Thermal Degradation of Recycled Acrylonitrile-Butadiene-Styrene by non-Isothermal Thermogravimetry

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 281 ◽  
Author(s):  
Rafael Balart ◽  
David Garcia-Sanoguera ◽  
Luis Quiles-Carrillo ◽  
Nestor Montanes ◽  
Sergio Torres-Giner
Keyword(s):  
Thermal Degradation ◽  
Kinetic Analysis ◽  
Acrylonitrile Butadiene Styrene ◽  
Isoconversional Methods ◽  
Reaction Model ◽  
Integral Model ◽  
Heating Rates ◽  
Exponential Factor ◽  
Model Free ◽  
Butadiene Styrene

This work presents an in-depth kinetic study of the thermal degradation of recycled acrylonitrile-butadiene-styrene (ABS) polymer. Non-isothermal thermogravimetric analysis (TGA) data in nitrogen atmosphere at different heating rates comprised between 2 and 30 K min−1 were used to obtain the apparent activation energy (Ea) of the thermal degradation process of ABS by isoconversional (differential and integral) model-free methods. Among others, the differential Friedman method was used. Regarding integral methods, several methods with different approximations of the temperature integral were used, which gave different accuracies in Ea. In particular, the Flynn-Wall-Ozawa (FWO), the Kissinger-Akahira-Sunose (KAS), and the Starink methods were used. The results obtained by these methods were compared to the Kissinger method based on peak temperature (Tm) measurements at the maximum degradation rate. Combined Kinetic Analysis (CKA) was also carried out by using a modified expression derived from the general Sestak-Berggren equation with excellent results compared with the previous methods. Isoconversional methods revealed negligible variation of Ea with the conversion. Furthermore, the reaction model was assessed by calculating the characteristic and functions and comparing them with some master plots, resulting in a nth order reaction model with n = 1.4950, which allowed calculating the pre-exponential factor (A) of the Arrhenius constant. The results showed that Ea of the thermal degradation of ABS was 163.3 kJ mol−1, while ln A was 27.5410 (A in min−1). The predicted values obtained by integration of the general kinetic expression with the calculated kinetic triplet were in full agreement with the experimental data, thus giving evidence of the accuracy of the obtained kinetic parameters.

scholarly journals Thermal Behavior of Sweet Potato Starch by Non-Isothermal Thermogravimetric Analysis

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 699 ◽  
Author(s):  
Ying Liu ◽  
Liutao Yang ◽  
Chunping Ma ◽  
Yingzhe Zhang
Keyword(s):  
Thermogravimetric Analysis ◽  
Thermal Degradation ◽  
Sweet Potato ◽  
Degradation Kinetics ◽  
Potato Starch ◽  
Activation Energies ◽  
Thermal Degradation Kinetics ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Sweet Potato Starch

In this study, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) methods were used to study the structure, the thermal degradation kinetics, and the thermogram of sweet potato starch, respectively. The thermal decomposition kinetics of sweet potato starch was examined within different heating rates in a nitrogen atmosphere. Different models of kinetic analysis were used to calculate the activation energies using the thermogravimetric data of the thermal degradation process. The activation energies got from Kissinger, Flynn–Wall–Ozawa, and Šatava–Šesták models were 173.85, 174.87, and 174.34 kJ·mol−1, respectively. Thermogravimetry–Fourier transform infrared spectroscopy (TG-FTIR) analysis showed that the main pyrolysis products included water, carbon dioxide, and methane.

Thermally induced nucleation. I. A new way to obtain activation energies for unimolecular reactions

1983 ◽  
Vol 79 (6) ◽  
pp. 2763-2770 ◽  
Author(s):  
Joseph L. Katz ◽  
Joseph G. Ruggiero ◽  
Richard Partch ◽  
Dale Warren ◽  
F. H. Ebetino
Keyword(s):  
Activation Energies ◽  
Unimolecular Reactions ◽  
Thermally Induced

Thermoluminescence study on TlGaSSe layered single crystals

2014 ◽  
Vol 28 (16) ◽  
pp. 1450133 ◽  
Author(s):  
Serdar Delice ◽  
Nizami M. Gasanly
Keyword(s):  
Single Crystals ◽  
Heating Rate ◽  
Thermal Quenching ◽  
Activation Energies ◽  
Temperature Peak ◽  
Heating Rates ◽  
Quenching Effect ◽  
Defect Centers ◽  
General Order ◽  
Maximum Temperatures

The defect centers in TlGaSSe single crystals have been investigated by performing thermoluminescence (TL) measurements with various heating rates between 0.5 K/s and 1.0 K/s in the temperature range of 10–180 K. The TL spectra, with peak maximum temperatures at 39 K and 131 K, revealed the existences of two defect levels. Curve fitting, initial rise and peak shape methods were used to determine the activation energies of two defect centers. The experimental results also showed that the trapping process was dominated by second-order kinetics for the trap related with low temperature peak while the general order (mixed order) kinetics was dominant for the trap donated to high temperature peak. Furthermore, heating rate dependences and traps distributions were studied for two defect centers separately. Thermal quenching effect dominates the behavior of these defects as the heating rate is increased. Also, quasi-continuous distributions were established with the increase of the activation energies from 16 meV to 27 meV and from 97 meV to 146 meV for the traps associated with the peaks observed at low and high temperatures, respectively.

scholarly journals Kinetics and mechanism of solid state imidapril hydrochloride degradation and its degradation impurities identification

2013 ◽  
Vol 11 (5) ◽  
pp. 754-762 ◽  
Author(s):  
Katarzyna Regulska ◽  
Beata Stanisz
Keyword(s):  
Solid State ◽  
Reaction Rate ◽  
Degradation Products ◽  
Reaction Model ◽  
Degradation Pathways ◽  
Reaction Rate Constants ◽  
Ich Guidelines ◽  
Imidapril Hydrochloride ◽  
The Masses ◽  
Accelerate Degradation

AbstractA detailed stability testing of solid state imidapril hydrochloride (IMD) was performed and its degradation products were identified. The analysis was conducted according to ICH guidelines Q1A(R2). Pure IMD samples were exposed to stress conditions of elevated temperature and relative humidity (T = 363 K, RH = 76.4%) in order to accelerate degradation. The regular loss of IMD content with time, and the formation of two degradation impurities were observed. The appropriate reaction rate constants k (for IMD degradation and for the formation of product I and II) were calculated using Prout-Tompkins equation. The obtained degradation products were separated and identified by means of LC-MS technique. Based on the obtained m/z values, the masses and the structures of the formed degradation impurities were established. Also IMD degradation scheme was constructed. It was demonstrated that under the applied analytical conditions, IMD degradation follows an autocatalytic reaction model with the rate constant k = (4.764 ± 0.34)×10 −6 s −1 and with the parallel formation of two degradation products: imidaprilat and the diketopiperazine derivative. The obtained experimental results are in agreement with IMD degradation pathways proposed theoretically.

scholarly journals Aromatization of light naphtha fractions on zeolites 1: Kinetic model

2003 ◽  
Vol 57 (9) ◽  
pp. 399-403 ◽  
Author(s):  
Svetlana Rovenskaja ◽  
Nikolaj Ostrovski
Keyword(s):  
Experimental Data ◽  
Kinetic Model ◽  
Rate Constants ◽  
Reaction Rate ◽  
Reaction Scheme ◽  
Activation Energies ◽  
Modeling And Optimization ◽  
Light Naphtha ◽  
Reaction Rate Constants

On the basis of analyzing kinetic experimental data performed in laboratory integral reactors a lumping kinetic model of the "Zeoforming" process was developed. A reaction scheme of the lumped components was proposed, that was adapted to the technological requirements. The reaction rate constants and activation energies were estimated, that are valid for certain feed compositions. The model is intended for further modeling and optimization of the process.

Nanoscale Energy Transport in Information Technology Research With an Application to High-Density Data Storage Devices and Systems

2002 ◽  
Author(s):  
Mehdi Asheghi ◽  
Yizhang Yang ◽  
Sadegh M. Sadeghipour ◽  
James A. Bain ◽  
Katayun Barmak ◽  
...  
Keyword(s):  
Information Technology ◽  
Data Storage ◽  
Energy Transport ◽  
Random Access ◽  
Thermal Design ◽  
Optical Data ◽  
Thermally Induced ◽  
Storage Devices ◽  
Superparamagnetic Limit ◽  
It Revolution

By all measures, the data storage industry is one of the most important components of the Information Technology (IT) revolution. In recent years, many of the emerging technologies rely heavily on energy transport at extremely short time and length scales as a mean to overcome the superparamagnetic limit - a serious impediment to future advancement of storage technology. Additionally, thermally induced failure and reliability issues at the nanoscale are becoming increasingly important due to rapid device miniaturization in data storage applications. Further advances in high-technology data storage systems will be difficult, if not impossible, without rigorous treatment of nanoscale energy transport. This manuscript reviews the thermal design issues and challenges in thermally assisted magnetic disk recording, thermally assisted scanned probe recording, phase change optical data recording, magnetoresistive random access memory (MRAM) and giant magnetoresistive (GMR) heads. Relevant thermally induced failures in GMR heads, write coil, interconnects and MRAM will be discussed as well.

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