Improving the Crystallization Resistance of Aluminum(III) 8-Hydroxyquinoline-Based Emitting Materials by Entropic Stabilization

1999 ◽  
Vol 561 ◽  
Author(s):  
Keith A. Higginson ◽  
Baocheng Yang ◽  
Fotios Papadimitrakopoulos

ABSTRACTThe morphological stability of evaporated films of aluminum(III) 8-hydroxyquinoline (Alq3) was investigated. Films which were found to be non-crystalline by x-ray diffraction upon deposition, crystallized rapidly upon annealing, especially where defects were present. Blends of Alq3with aluminum(III) 5-methyl-8-hydroxyquinoline were proposed for thermally stable amorphous emitting layers in light-emitting diodes. Films coevaporated at a 1:1 ratio did not show evidence of crystallization or phase separation even after long annealing periods at temperatures as high as 160°C.

Author(s):  
Vini. K ◽  
Padmakumar H. ◽  
K.M. Nissamudeen

This paper explains the role of bismuth in the luminescence enhancement of Y2O3 :Eu nanophosphors prepared by Combustion method. Bi ions serve as effective sensitizers for visible emitting rare earths for Light Emitting Diodes. From the X-ray diffraction studies, bismuth co-activated nanophosphors exhibit an early crystallization. Bismuth incorporation not only results in the luminescence enhancement at 612 nm, due to 5D0 to 7F2 transition but also reduces the processing temperature for intense photoemission.


2016 ◽  
Vol 27 (32) ◽  
pp. 325707 ◽  
Author(s):  
Thilo Krause ◽  
Michael Hanke ◽  
Zongzhe Cheng ◽  
Michael Niehle ◽  
Achim Trampert ◽  
...  

2010 ◽  
Vol 43 (2) ◽  
pp. 337-340 ◽  
Author(s):  
Simon K. Brayshaw ◽  
Jason W. Knight ◽  
Paul R. Raithby ◽  
Teresa L. Savarese ◽  
Stefanie Schiffers ◽  
...  

With the increase in interest in photocrystallographic experiments, the use of light-emitting diodes (LEDs) provides an alternative, low-budget light source (by comparison to lasers) and allows photocrystallographic experiments to be carried out readily. Here the design of an LED array device suitable for use in single-crystal X-ray diffraction experiments is reported, and the experimental methodology used for determining the structures of metastable species is described.


1995 ◽  
Vol 51 (18) ◽  
pp. 12747-12753 ◽  
Author(s):  
M. A. G. Aranda ◽  
D. C. Sinclair ◽  
J. P. Attfield ◽  
A. P. Mackenzie

The Analyst ◽  
2011 ◽  
Vol 136 (4) ◽  
pp. 716-723 ◽  
Author(s):  
Bang-Ying Yu ◽  
Che-Hung Kuo ◽  
Wei-Ben Wang ◽  
Guo-Ji Yen ◽  
Shin-ichi Iida ◽  
...  

2011 ◽  
Vol 23 (48) ◽  
pp. 5767-5772 ◽  
Author(s):  
Seung-Yeon Kwak ◽  
SeungCheol Yang ◽  
Na Ree Kim ◽  
Jae Hong Kim ◽  
Byeong-Soo Bae

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