Carbon Fiber Reinforced Triazin Resin for Endoprostheses

1985 ◽  
Vol 55 ◽  
Author(s):  
F. J. Esper ◽  
J. Harms ◽  
H. Mittelmeier ◽  
W. Gohl

ABSTRACTMetal alloys, ceramics, and thermoplastics are commonly used as materials for endoprostheses, especially artificial hip joints. Prostheses made of these materials still retain disadvantages which have been responsible for failures in the past. A new material, without the abovementioned disadvantages, has been developed. It is a carbon fiber reinforced thermo set based on the triazin resin. Its principle mechanical properties can be matched with those of bone. The new material (referred to as TCF) has a higher bending and fatigue strength than cast metallic alloys if endless fibers are applied. Its creep rate at 37°C under high load (3000 N), as well as its wear rate against metallic or ceramic wear partners, is negligible. Experiments with animals based on ten years of experience show good osteocompatibility of the TCF. Toxic reactions of the tissue caused by the TCF implants themselves, or by fine wear debris found in membranes of connective tissue (or lymph nodes), were not observed at all. Tissue reacts on large particles of TCF wear debris in the same manner as it does on particulates of the same size of polyethylene. It can be expected that the favorable biomechanical and biological properties of the TCF material will make it a good alternative to other materials already in use for construction of endoprostheses, especially hip joints.

2003 ◽  
Vol 67B (2) ◽  
pp. 758-764 ◽  
Author(s):  
G. I. Howling ◽  
H. Sakoda ◽  
A. Antonarulrajah ◽  
H. Marrs ◽  
T. D. Stewart ◽  
...  

Biomaterials ◽  
2002 ◽  
Vol 23 (16) ◽  
pp. 3441-3448 ◽  
Author(s):  
J.L. Tipper ◽  
A. Hatton ◽  
J.E. Nevelos ◽  
E. Ingham ◽  
C. Doyle ◽  
...  

Author(s):  
Hong-Ming Lin ◽  
C. H. Liu ◽  
R. F. Lee

Polyetheretherketone (PEEK) is a crystallizable thermoplastic used as composite matrix materials in application which requires high yield stress, high toughness, long term high temperature service, and resistance to solvent and radiation. There have been several reports on the crystallization behavior of neat PEEK and of CF/PEEK composite. Other reports discussed the effects of crystallization on the mechanical properties of PEEK and CF/PEEK composites. However, these reports were all concerned with the crystallization or melting processes at or close to atmospheric pressure. Thus, the effects of high pressure on the crystallization of CF/PEEK will be examined in this study.The continuous carbon fiber reinforced PEEK (CF/PEEK) laminate composite with 68 wt.% of fibers was obtained from Imperial Chemical Industry (ICI). For the high pressure experiments, HIP was used to keep these samples under 1000, 1500 or 2000 atm. Then the samples were slowly cooled from 420 °C to 60 °C in the cooling rate about 1 - 2 degree per minute to induce high pressure crystallization. After the high pressure treatment, the samples were scanned in regular DSC to study the crystallinity and the melting temperature. Following the regular polishing, etching, and gold coating of the sample surface, the scanning electron microscope (SEM) was used to image the microstructure of the crystals. Also the samples about 25mmx5mmx3mm were prepared for the 3-point bending tests.


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