New Substituted Pyrochlore-Type Manganates with Magnetoresistive Properties
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AbstractSubstitutions in the pyrochlore-type oxide Tl2Mn2O7 have been carried out on both the Mn and the TI site, using high pressure synthesis at 4-6 GPa. We show that a continuous solid solution exists between Tl2Mn2O7, and Tl2Ru2O7, and that the replacement of a fraction of Mn by Ru dramatically changes the transport properties from metallic to semiconducting and induces magnetoresistance (MR) in this system. MRs up to 95% (vs. RO) have been observed. The Tl site, already known to accept In or Sc, can also be substituted by the larger cation Bi3+, which also induces a metal-insulator transition at low substitution level.
2017 ◽
Vol 56
(14)
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pp. 8187-8194
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1997 ◽
Vol 32
(12)
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pp. 1637-1642
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2014 ◽
Vol 2
(18)
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pp. 6384-6395
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1992 ◽
Vol 27
(8)
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pp. 939-943
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