Monte Carlo Study of Etching at Silica-Water Interface
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AbstractA surface adsorption-diffusion-reaction model is proposed and tested by Monte Carlo simulations. The solvent shell effect is considered as a geometric constraint and the Langmuir adsorption mechanism is also incorporated. An anomalous power law of t1/2 is obtained for the amount of material removed from the surface vs. time. The result agrees well with etching experiments of SAM on a silica surface. We conclude that the unusual power law results from an interplay of vacancy growth and fusion at the surface.
2017 ◽
Vol 147
(8)
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pp. 084305
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1999 ◽
Vol 103
(11)
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pp. 1930-1933
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1987 ◽
Vol 48
(C5)
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pp. C5-199-C5-202