Translational Diffusion of Liquids Confined in Nanopores

1996 ◽  
Vol 464 ◽  
Author(s):  
J.-P. Korb ◽  
M. Whaley ◽  
R. G. Bryant

ABSTRACTWe present a theory of nuclear spin relaxation and experiments to probe the microdynamics of polar solvents at the surface of calibrated microporous glass beads. The theory is tested using the magnetic field dependence of the proton spin-lattice relaxation rate recorded with a field-switched magnetic relaxation dispersion spectrometer.

2011 ◽  
Vol 208 (2) ◽  
pp. 195-203 ◽  
Author(s):  
Galina Diakova ◽  
Yanina Goddard ◽  
Jean-Pierre Korb ◽  
Robert G. Bryant

1967 ◽  
Vol 45 (11) ◽  
pp. 3533-3554 ◽  
Author(s):  
Myer Bloom ◽  
Frank Bridges ◽  
Walter N. Hardy

The spin-lattice relaxation time T1 for protons and deuterons in CH4, CH3D, CH2D2, CHD3, and CD4 has been measured as a function of density ρ and temperature T for 0.1 Amagat [Formula: see text] Amagats and [Formula: see text] The results are interpreted, using the approximation that the correlation function of each operator in the angular momentum coordinates is expressed as a product of the free molecule correlation function and an exponentially decaying function of time. The proton spin relaxation is found to be due to the spin-rotation interaction, while the deuteron spin relaxation is due to the intramolecular quadrupolar interaction.


1983 ◽  
Vol 44 (10) ◽  
pp. 1179-1184 ◽  
Author(s):  
M. Vilfan ◽  
R. Blinc ◽  
J. Dolinšek ◽  
M. Ipavec ◽  
G. Lahajnar ◽  
...  

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