Residual Impurities And Transport Properties of High Purity Movpe Gaas

1996 ◽  
Vol 442 ◽  
Author(s):  
G. Steude ◽  
D. M. Hofmann ◽  
M. Drechsler ◽  
B. K. Meyer ◽  
H. Hardtdegen ◽  
...  

AbstractHigh purity GaAs grown by metal organic vapor phase epitaxy (MOVPE) using nitrogen as a carrier gas has been studied by optically detected cyclotron resonance (ODCR) at microwave and far infrared frequencies. Upon variation of the experimental parameters such as sample temperature, optical excitation density and microwave power the residual ionized (donor) and neutral (acceptor) impurity concentrations can be estimated, they are 2×1012 cm−3 and 5×1013 cm−3, respectively. The luminescence results indicate C to be the dominant residual acceptor. The residual donors were identified as S, Se, Sn from the observation of the internal 1s - 3p×105 cm2/Vs.

2001 ◽  
Vol 16 (5) ◽  
pp. 1358-1362 ◽  
Author(s):  
W. I. Park ◽  
S-J. An ◽  
Gyu-Chul Yi ◽  
Hyun M. Jang

High-quality ZnO thin films were grown epitaxially at 250–550 °C Al2O3(00·1) substrates using low-pressure metalorganic vapor phase epitaxy. The reactants for the growth were diethylzinc and oxygen. Growth temperature, one of the important experimental parameters for epitaxial layers, was optimized. The films grown at 500 °C exhibited good crystallinity and strong ultraviolet absorption and emission. Photoluminescence spectra of the films showed a dominant excitonic emission with a weak deep level emission. More importantly, a strong stimulated emission peak was observed even at room temperature.


1994 ◽  
Vol 08 (11) ◽  
pp. 653-665 ◽  
Author(s):  
H. NAKATA ◽  
R. KOMEDA ◽  
T. OHYAMA ◽  
E. OTSUKA

We report on a study of the far-infrared (FIR) magneto-absorption of ZnSe layers epitaxially grown on GaAs by metal-organic vapor-phase epitaxy (MOVPE) or molecular-beam epitaxy (MBE). The Zeeman absorption of the residual donors is observed in undoped and p -type ZnSe layers. A main absorption peak is assigned to a 1s to 2p+ transition of an electron bound to a Cl donor. Polaron pinning effect is included to explain the peak position within the framework of Wigner–Brillouin second order perturbation theory.


Author(s):  
L. Solymar ◽  
D. Walsh ◽  
R. R. A. Syms

Both intrinsic and extrinsic semiconductors are discussed in terms of their band structure. The acceptor and donor energy levels are introduced. Scattering is discussed, from which the conductivity of semiconductors is derived. Some mathematical relations between electron and hole densities are derived. The mobilities of III–V and II–VI compounds and their dependence on impurity concentrations are discussed. Band structures of real and idealized semiconductors are contrasted. Measurements of semiconductor properties are reviewed. Various possibilities for optical excitation of electrons are discussed. The technology of crystal growth and purification are reviewed, in particular, molecular beam epitaxy and metal-organic chemical vapour deposition.


2003 ◽  
Vol 32 (7) ◽  
pp. 656-660 ◽  
Author(s):  
C. D. Maxey ◽  
J. P. Camplin ◽  
I. T. Guilfoy ◽  
J. Gardner ◽  
R. A. Lockett ◽  
...  

2008 ◽  
Vol 1 ◽  
pp. 071102 ◽  
Author(s):  
Tomonari Shioda ◽  
Masakazu Sugiyama ◽  
Yukihiro Shimogaki ◽  
Yoshiaki Nakano

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