Schottky Barrier Diodes From Electrochemically Generated Polypyrrole-Aluminium Junctions

1995 ◽  
Vol 413 ◽  
Author(s):  
J Rodriguez ◽  
J. P. Moliton ◽  
T Trigaud ◽  
T. F. Otero ◽  
H. Grande

ABSTRACTPolypyrrole films were electrogenerated and electrochemically compacted at high cathodic potentials on aluminium. Films removed from the electrode after polarization at -2000 mV show stable bulk conductivities of 10-6 S/cm for months. Planar structures metal/polymer/metal present rectifying properties. The presence of a thin oxidized surface layer having a higher conductivity than that of the bulk polymer can be deduced remaining reduced the polymer mass.

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...  

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