Interplay of Soret vs. Normal Impurity Diffusion During Laser or E-Beam Induced Heat Flow Transients in Metals

1981 ◽  
Vol 4 ◽  
Author(s):  
L.F. Dona' Dalle Rose ◽  
A. Miotello

ABSTRACTIn the growing amount of the experimental data on the diffu sion processes of implanted impurities in a metal sample irradiated by highly energetic and very short pulses, some order may be introduced by the knowledge of the structure of induced thermal transient. The differences in such a structure due to two different energy sources (laser and electron beam) are de scribed with reference to the conditions under which Soret diffusion may be experimentally observed as distinct from nor mal diffusion. Laser induced transient seem to offer this possibility.Some previously reported diffusion processes in laser irra diated systems are reinterpreted on this basis, showing the importance of the Soret effect.

2014 ◽  
Vol 11 (8) ◽  
pp. 2201-2209 ◽  
Author(s):  
O. Monga ◽  
P. Garnier ◽  
V. Pot ◽  
E. Coucheney ◽  
N. Nunan ◽  
...  

Abstract. This paper deals with the simulation of microbial degradation of organic matter in soil within the pore space at a microscopic scale. Pore space was analysed with micro-computed tomography and described using a sphere network coming from a geometrical modelling algorithm. The biological model was improved regarding previous work in order to include the transformation of dissolved organic compounds and diffusion processes. We tested our model using experimental results of a simple substrate decomposition experiment (fructose) within a simple medium (sand) in the presence of different bacterial strains. Separate incubations were carried out in microcosms using five different bacterial communities at two different water potentials of −10 and −100 cm of water. We calibrated the biological parameters by means of experimental data obtained at high water content, and we tested the model without changing any parameters at low water content. Same as for the experimental data, our simulation results showed that the decrease in water content caused a decrease of mineralization rate. The model was able to simulate the decrease of connectivity between substrate and microorganism due the decrease of water content.


1974 ◽  
Vol 14 (06) ◽  
pp. 573-592 ◽  
Author(s):  
K.H. Coats ◽  
W.D. George ◽  
Chieh Chu ◽  
B.E. Marcum

Coats, K.H., Member SPE-AIME, Intercomp Resource Development and Engineering, Inc., Houston, Texas George, W.D., Chu, Chieh, Member SPE-AIME, Getty Oil Co., Houston, Tx. Marcum, B.E., Member SPE-AIME, Getty Oil Co., Los Angeles, Calif. Abstract This paper describes a three-dimensional model for numerical simulation of steam injection processes. The model describes three-phase flow processes. The model describes three-phase flow of water, oil, and steam and heat flow in the reservoir and overburden. The method of solution simultaneously solves for the mass and energy balances and eliminates the need for iterating on the mass transfer (condensation) term.Laboratory data are reported for steamfloods of 5,780-cp oil in a 1/4 five-spot sand pack exhibiting three-dimensional flow effects. These experiments provide additional data for checking accuracy and provide additional data for checking accuracy and assumptions in numerical models. Comparisons of model results with several sets of experimental data indicate a need to account for effects of temperature on relative permeability. Calculated areal conformance of a steamflood in a confined five-spot depends strongly upon the alignment of the x-y grid axes relative to the diagonal joining injection and production wells. It has not been determined which, if either, of the two grid types yields the correct areal conformance.Model calculations indicate that steamflood pressure level strongly affects oil recovery. pressure level strongly affects oil recovery. Calculated oil recovery increases with decreasing pressure level. An example application illustrates pressure level. An example application illustrates the ability of the model formulation to efficiently simulate the single-well, cyclic steam stimulation problem. problem Introduction The literature includes many papers treating various aspects of oil recovery by steamflooding, hot waterflooding, and steam stimulation. The papers present laboratory experimental data, field papers present laboratory experimental data, field performance results, models for calculating fluid performance results, models for calculating fluid and heat flow, and experimental data regarding effects of temperature on relative permeability. The ultimate goal of all this work is a reliable engineering analysis to estimate oil recovery for a given mode of operation and to determine alternative operating conditions to maximize oil recovery.Toward that end, our study proposed to develop and validate an efficient, three-dimensional numerical model for simulating steamflooding, hot waterflooding, and steam stimulation. Laboratory steamflood experiments were conducted to provide additional data for validation. Desired model specifications included three-dimensional capability and greater efficiency than reported for previous models. Omitted from the specifications were temperature-dependent relative permeability and steam distillation effects.This paper describes the main features of the three-dimensional, steamflood model developed. Those features include a new method of solution that includes implicit water transmissibilities, that simultaneously solves for mass and energy balances, and that eliminates the need for iteration on the condensation term. Laboratory data are reported for steamfloods in a 1/4 five-spot model exhibiting three-dimensional flow effects. Numerical model applications described include comparisons with experimental data, a representative field-scale steamflood, and a cyclic steam stimulation example. REVIEW OF PREVIOUS WORK Early efforts in mathematical modeling of thermal methods concentrated on simulation of the heat flow and heat loss. Gottfried, in his analysis of in-situ combustion, initiated a series of models that solve fluid mass balances along with the energy balance. Davidson et al. presented an analysis for well performance during cyclic steam injection. Spillette and Nielsen treated hot waterflooding in two dimensions. Shutler described three-phase models for linears and two-dimensional steamflooding, and Abdalla and Coats treated a two-dimensional steamflood model using the IMPES method of solution. SPEJ P. 573


1961 ◽  
Vol 9 (3) ◽  
pp. 539-553 ◽  
Author(s):  
Lucien G. Caro

If thin sections of Escherichia coli, labeled uniformly with tritium, are radioautographed calculations, based on the distribution of section sizes show that the number of H3 decays per section should be very close to a Poisson distribution. We might, therefore, expect that the distribution of radioautographic grain counts among random cross-sections should follow a Poisson distribution. It can then be inferred that a deviation from a Poisson indicates a high concentration of label in a preferred region. This region can then be identified by analysis of serial section and comparison with electron micrographs. Sections of cells labeled with leucine-H3 gave a Poisson distribution of grain counts, and it was concluded that proteins were distributed fairly uniformly throughout the cell. The situation was not changed if labeled cells were placed in chloramphenicol or if very short pulses of label were used. When Escherichia coli is grown in presence of chloramphenicol a major morphological change concerns the nuclear region: it becomes more regular in outline, nearly spherical, and occupies a smaller proportion of the cell length. The previously described association between DNA labeled with thymidine-H3 and the nuclear region was confirmed by showing that the distribution of the label in the cell followed exactly the morphological changes of the nuclear region. It was also shown that the concentration of DNA in the nuclear region was at least 45 times higher than that of the cytoplasm. Several morphological features of cells grown in chloramphenicol and examined in the electron microscope are discussed.


1980 ◽  
Vol 15 (5) ◽  
pp. 908-910 ◽  
Author(s):  
V.G. Ruediger ◽  
B.J. Hosticka

2011 ◽  
Vol 704-705 ◽  
pp. 1266-1272 ◽  
Author(s):  
Lei Chen ◽  
Wen Quan Tao

In this paper a molecular dynamics calculation model for the Nafion 117 membrane is constructed by Materials Studio (MS) software platform to study its micro-structure and transport properties. Based on the calculation model, cell structures of different water content of Nafion 117 membrane are obtained and the predicted density values of simulated cell are in good agreement with experimental data. Meanwhile, the diffusion processes of water molecules and hydrogen ions in the membrane are studied, respectively. The predicted diffusion coefficients of both water molecules and hydrogen ions increase with the water content, which agrees well with the variation trend of experimental data. The reasons for the deviation between numerical results and the experiment values in literature are analyzed.


2014 ◽  
Vol 216 ◽  
pp. 103-109
Author(s):  
Marius Bodea ◽  
Radu Mureşan

The mechanical properties of the welded structures are directly related to the weldability of the steels, thus the estimation of the microstructural constituents in the weld and maximum hardness in the HAZ according to the welding process parameters represent a problem of great interest. The microstructural changes in the HAZ are estimated using a five-parameter logistic function (5PL), which is very accurate in the fitting highly asymmetric data. Also, the same 5PL function can be used in order to predict hardness and toughness in the HAZ based on the heat flow, cooling rates between 800-500 oC and chemical composition of the material. A discussion about the parameters of the 5PL function and fitting experimental data is presented and a studied case for welding S355J2 steel plates is also analyzed.


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