Effects of the Electrolyte Composition on the Electrode Characteristics of Rechargeable Lithium Batteries

1995 ◽  
Vol 393 ◽  
Author(s):  
Masayuki Morita ◽  
Masashi Ishikawa ◽  
Yoshiharu Matsuda

ABSTRACTA variety of organic solvent-based electrolytes have been studied for ambient temperature, rechargeable lithium (ion) batteries. The ionic behavior of the electrolyte system was investigated through conductivity measurements. The electrochemical characteristics of carbon-based materials (carbon fiber and graphite) as the negative electrode were examined in different compositions of the organic electrolytes. The electrolyte composition as well as the structure of the electrode material greatly influenced the charge/discharge profiles of the electrode.

2016 ◽  
Vol 4 (19) ◽  
pp. 7091-7106 ◽  
Author(s):  
Jian Xie ◽  
Qichun Zhang

Different organic electrode materials in lithium-ion batteries are divided into three types: positive electrode materials, negative electrode materials, and bi-functional electrode materials, and are further discussed.


2020 ◽  
Vol 86 (9) ◽  
pp. 14-27
Author(s):  
Nataliy Globa ◽  
Tatyana Lisnycha ◽  
Yurii Shmatok ◽  
Vitalii Sirosh ◽  
Sviatoslav Kirillov

The paper presents structural, surface, thermodynamic and kinetic characteristics of titanium dioxide samples obtained by means of alkaline hydrolysis of TiCl4 by LiOH solutions and further heat treatment. TiO2 samples have the anatase structure with crystallite size of 7–10 nm. An increase in the heat treatment temperature from 150 °C to 470 °C leads to a decrease in the specific surface area from 404 to 80 m2/g and the total pore volume from 0.340 to 0.152 cm3/g. The influence of electrolyte composition and surface properties of TiO2 on its behavior in cells with lithium anode investigated by means of galvanostatic cycling and impedance spectroscopy is discussed.


1992 ◽  
Vol 139 (5) ◽  
pp. 1227-1230 ◽  
Author(s):  
Masayuki Morita ◽  
Tomoyuki Hanada ◽  
Hiromori Tsutsumi ◽  
Yoshiharu Matsuda ◽  
Masayuki Kawaguchi

2018 ◽  
Vol 4 (3) ◽  
Author(s):  
Giovanni Battista Appetecchi

AbstractAmong the electrochemical energy storage systems, rechargeable lithium batteries are considered very promising candidates for the next generation power sources because of their high gravimetric and volumetric energy density with respect to other cell chemistries. The lithium-ion battery technology is based on the use of electrode materials able to reversibly intercalate lithium cations, which are continuously transferred between two host structures (negative and positive electrodes) during the charge and discharge processes. Commercial lithium-ion batteries commonly use liquid electrolytes based on suitable lithium salts (solute) and organic compounds (solvents). The latter, volatile and flammable, represent serious concerns for the safety of the electrochemical devices, this so far preventing their large diffusion in applications as automotive, storage from renewable sources, smart grids.One of the most appealing approaches is the partial or total replacement of the organic solvents with safer, less hazardous, electrolyte components. Here, a concise survey of ones of the most investigated types of alternative electrolyte components, proposed for safer and more reliable rechargeable lithium batteries, is reported.Graphical Abstract:


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