Microstructures in Rapidly Solidified Ll2-TYPE Ni-Al-Cr Alloys

1984 ◽  
Vol 39 ◽  
Author(s):  
S. C. Huang ◽  
K. M. Chang ◽  
E. L. Hall ◽  
R. F. Laforce
Keyword(s):  
Phase Separation ◽  
Cooling Rate ◽  
Phase Reaction ◽  
Microstructural Study ◽  
Melt Spun ◽  
Rapidly Solidified

ABSTRACTA microstructural study of the melt spun alloys Ni75 Al25. Ni72.5 Al22.5Cr5. and Ni67.5A120Cr12.5 was carried out. Variations in grain morpfology; phase separation and ordering structure were observed. The results are discussed in terms of alloy stoichiometry, Cr effect on phase reaction, microsegregation of Al and the cooling rate.

Liquid-Liquid Phase Separation in Quenched Fe71Cu10P10B9 Multi-Component Alloy

2017 ◽  
Vol 727 ◽  
pp. 82-87
Author(s):  
Chang Rong Qu ◽  
Xue Lian Li ◽  
Li Wang ◽  
Jin Bao Liu ◽  
Xing Hua Tong
Keyword(s):  
Phase Separation ◽  
Liquid Phase ◽  
Cooling Rate ◽  
Magnetic Measurements ◽  
Solidification Process ◽  
Liquid Phase Separation ◽  
Saturation Induction ◽  
The Matrix ◽  
Rapidly Solidified ◽  
Liquid Liquid Phase Separation

Liquid-liquid phase separation (LLPS) in the rapidly solidified Fe71Cu10P10B9 alloy under different casting conditions is investigated based on the XRD, DSC, and SEM measurements. It is found that during rapid solidification process, Cu-rich globules precipitated in the matrix which mainly consists of α-Fe and Fe3B0.82P0.18 crystals. With increasing cooling rate, LLPS becomes weaker, leading to less precipitation of Cu-rich globules, while the microstructure of the matrix became finer. Magnetic measurements show that the saturation induction and the coercivity of the present samples increase first and then decrease with increasing cooling rate. The corresponding mechanisms related to magnetic performance are also discussed details.

Suppression of γ’ Precipitation in a Laser-Melted Nickel-Base Alloy

1977 ◽  
Vol 35 ◽  
pp. 270-271
Author(s):  
J. M. Walsh ◽  
J. C. Whittles ◽  
B. H. Kear ◽  
E. M. Breinan
Keyword(s):  
Cooling Rate ◽  
Base Alloy ◽  
Material Surface ◽  
Intimate Contact ◽  
Absorbed Power ◽  
Perfect Contact ◽  
Nickel Base ◽  
Rapidly Solidified ◽  
Limiting Case ◽  
The Heat Transfer Coefficient

Conventionally cast γ’ precipitation hardened nickel-base superalloys possess well-defined dendritic structures and normally exhibit pronounced segregation. Splat quenched, or rapidly solidified alloys, on the other hand, show little or no evidence for phase decomposition and markedly reduced segregation. In what follows, it is shown that comparable results have been obtained in superalloys processed by the LASERGLAZE™ method.In laser glazing, a sharply focused laser beam is traversed across the material surface at a rate that induces surface localized melting, while avoiding significant surface vaporization. Under these conditions, computations of the average cooling rate can be made with confidence, since intimate contact between the melt and the self-substrate ensures that the heat transfer coefficient is reproducibly constant (h=∞ for perfect contact) in contrast to the variable h characteristic of splat quenching. Results of such computations for pure nickel are presented in Fig. 1, which shows that there is a maximum cooling rate for a given absorbed power density, corresponding to the limiting case in which melt depth approaches zero.

Microstructural Variations in Melt-Spun Rapidly Solidified Ribbons

1985 ◽  
Vol 43 ◽  
pp. 54-55
Author(s):  
L. A. Bendersky ◽  
W. J. Boettinger
Keyword(s):  
Solid State ◽  
Processing Parameters ◽  
Heat Extraction ◽  
Solid State Reactions ◽  
Careful Examination ◽  
Ion Milling ◽  
Melt Spun ◽  
Wheel Side ◽  
Rapidly Solidified ◽  
Heat Extraction Rate

Rapid solidification produces a wide variety of sub-micron scale microstructure. Generally, the microstructure depends on the imposed melt undercooling and heat extraction rate. The microstructure can vary strongly not only due to processing parameters changes but also during the process itself, as a result of recalescence. Hence, careful examination of different locations in rapidly solidified products should be performed. Additionally, post-solidification solid-state reactions can alter the microstructure.The objective of the present work is to demonstrate the strong microstructural changes in different regions of melt-spun ribbon for three different alloys. The locations of the analyzed structures were near the wheel side (W) and near the center (C) of the ribbons. The TEM specimens were prepared by selective electropolishing or ion milling.

Spherulite Structures in a Melt Spun Fe-Ni Austenitic Steel

1985 ◽  
Vol 43 ◽  
pp. 52-53
Author(s):  
G. M. Michal ◽  
T. K. Glasgow ◽  
T. J. Moore
Keyword(s):  
Austenitic Steel ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Large Range ◽  
Amorphous Structure ◽  
Nucleation And Growth ◽  
Ni Alloys ◽  
Melt Spun ◽  
Crystal Fibers ◽  
Rapidly Solidified

Large additions of B to Fe-Ni alloys can lead to the formation of an amorphous structure, if the alloy is rapidly cooled from the liquid state to room temperature. Isothermal aging of such structures at elevated temperatures causes crystallization to occur. Commonly such crystallization pro ceeds by the nucleation and growth of spherulites which are spherical crystalline bodies of radiating crystal fibers. Spherulite features were found in the present study in a rapidly solidified alloy that was fully crysstalline as-cast. This alloy was part of a program to develop an austenitic steel for elevated temperature applications by strengthening it with TiB2. The alloy contained a relatively large percentage of B, not to induce an amorphous structure, but only as a consequence of trying to obtain a large volume fracture of TiB2 in the completely processed alloy. The observation of spherulitic features in this alloy is described herein. Utilization of the large range of useful magnifications obtainable in a modern TEM, when a suitably thinned foil is available, was a key element in this analysis.

Rapidly Solidified Melt-spun Bi-Sn Ribbons: Surface Composition Issues

2016 ◽  
pp. 3287-3297
Author(s):  
Tarek El Ashram ◽  
Ana P. Carapeto ◽  
Ana M. Botelho do Rego
Keyword(s):  
Chemical Composition ◽  
Optical Microscopy ◽  
Melt Spinning ◽  
Surface Composition ◽  
Electrochemical Process ◽  
Melt Spun ◽  
Bismuth Alloy ◽  
The One ◽  
Rapidly Solidified ◽  
Melt Spinning Technique

Tin-bismuth alloy ribbons were produced using melt-spinning technique. The two main surfaces (in contact with the rotating wheel and exposed to the air) were characterized with Optical Microscopy and AFM, revealing that the surface exposed to the air is duller (due to a long-range heterogeneity) than the opposite surface. Also the XPS chemical composition revealed many differences between them both on the corrosion extension and on the total relative amounts of tin and bismuth. For instance, for the specific case of an alloy with a composition Bi-4 wt % Sn, the XPS atomic ratios Sn/Bi are 1.1 and 3.7 for the surface in contact with the rotating wheel and for the one exposed to air, respectively, showing, additionally, that a large segregation of tin at the surface exists (nominal ratio should be 0.073). This segregation was interpreted as the result of the electrochemical process yielding the corrosion products.

The effect of composition and cooling rate on the structure of rapidly solidified (Fe, Ni)3Al–C alloys

1989 ◽  
Vol 4 (1) ◽  
pp. 44-49 ◽  
Author(s):  
S. A. Myers ◽  
C. C. Koch
Keyword(s):  
Cooling Rate ◽  
Base Alloy ◽  
Weight Percent ◽  
Quench Rate ◽  
Transmission Electron ◽  
Metastable Structures ◽  
Metastable Structure ◽  
The Matrix ◽  
Rapidly Solidified ◽  
Kinetics Of

There is controversy in the literature regarding the existence of the metastable γ′ phase with an ordered Ll2 structure in rapidly solidified Fe–Ni–Al–C alloys. In this study, the quench rate–metastable structure dependence was examined in the Fe–20Ni–8Al–2C (weight percent) alloy. The effect of silicon on the kinetics of phase formation was studied by adding two weight percent silicon to a base alloy of Fe–20Ni–8Al–2C. Samples were rapidly solidified in an arc hammer apparatus and examined by transmission electron microscopy. In the Fe–20Ni–8Al–2C alloy, the nonequilibrium γ′ and γ phases were found in foils 65 to 100 μm thick. At higher quench rates, i.e., thinner samples, the matrix was observed to be disordered fcc γ with K-carbide precipitates. Samples containing silicon were found to have a matrix composed of γ′ and γ structures when the foils were thicker than 40 μm. At higher quench rates, the matrix was disordered fcc γ with K-carbide precipitates. The nonequilibrium γ′ and γ structures are present in samples with or without silicon, but are observed at higher cooling rates with the addition of silicon. This sensitivity to cooling rate and composition in resulting metastable structures may explain the differences reported in the literature for these rapidly solidified materials.

Phase Selection in Sub-Rapidly Solidified Au-20Sn Alloys

2015 ◽  
Vol 817 ◽  
pp. 325-330
Author(s):  
Yu Hai Qu ◽  
Kai Jin Yang ◽  
Yan Tian Zhou ◽  
Yong Mao ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Cooling Rate ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Copper Mold ◽  
Cooling Rates ◽  
Phase Selection ◽  
Graphite Mold ◽  
Injection Casting ◽  
Rapidly Solidified ◽  
Ausn Phase

The sub-rapidly solidified Au-20Sn eutectic alloys were prepared by four different solidification pathways, such as, graphite mold conventional casting, graphite mold injection casting, copper mold injection casting, and water-cooled copper mold suction casting. The precipitating sequences of competing primary phases of sub-rapidly solidified Au-20Sn alloys with four different cooling rates were investigated. The results show that phase selection process is related to the cooling rates during sub-rapid solidification process. The primary ζ'-Au5Sn phase with developed dendrites precipitate at low cooling rate (2.4×10−4.2×102K/min) and the morphologies of the primary ζ'-Au5Sn change to rosette-like at higher cooling rate (9.0×103K/min). While the cooling rate reaches to 3.5×104K/min, the primary ζ'-Au5Sn phase can be suppressed but δ-AuSn phase will precipitate prior to the ζ'-Au5Sn phase. On the basis of the classical nucleation theory and transient nucleation theory, the process of competitive nucleation between the ζ'-Au5Sn phase and the δ-AuSn phase were analyzed for sub-rapid solidified Au-20Sn alloy. The theoretical calculations are consistent with the experimental investigations.

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