Properties of a Carbon Negative Electrode in Completely Inorganic Thin Film Li-Ion Batteries with a LiCoO2 Positive Electrode

1994 ◽  
Vol 369 ◽  
Author(s):  
R.B. Goldner ◽  
S. Slaven ◽  
T.Y. Liu ◽  
T.E. Haas ◽  
F.O. Arnt ◽  
...  
Keyword(s):  
Thin Film ◽  
Diffusion Constant ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Chemical Diffusion ◽  
Carbon Films ◽  
Rechargeable Batteries ◽  
Metallic Lithium ◽  
Disordered Carbon ◽  
Deposition Processes

AbstractCompletely inorganic thin film lithium ion battery cells have been prepared by vapor deposition processes (vacuum evaporation and sputtering). The negative and positive electrodes were films of disordered carbon and lithium cobalt oxide, respectively. The results of battery charging/discharging and other measurements (e.g., in-situ lithium chemical diffusion constant measurements for the carbon films) indicate that disordered carbon films have a relatively high reversible charge capacity, (> 160 mC/μmand possibly higher than 360 mC/cm2-μm, or > 296 and possibly 667 mAh/g, respectively, assuming the measured film density of 1.5g/cm3), and a lithium chemical diffusion constant at room temperature ≈10-9 cm2/s. These results suggest that disordered carbon films should be good substitutes for metallic lithium in thin film rechargeable batteries.

PROPERTIES OF ALL-SOLID-STATE LITHIUM-ION RECHARGEABLE BATTERIES DEPOSITED BY RF MAGNETRON SPUTTERING

2013 ◽  
Vol 27 (22) ◽  
pp. 1350156 ◽  
Author(s):  
R. J. ZHU ◽  
Y. REN ◽  
L. Q. GENG ◽  
T. CHEN ◽  
L. X. LI ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Magnetron Sputtering ◽  
Coulombic Efficiency ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Rf Magnetron Sputtering ◽  
Rechargeable Batteries ◽  
Voltage Range

Amorphous V 2 O 5, LiPON and Li 2 Mn 2 O 4 thin films were fabricated by RF magnetron sputtering methods and the morphology of thin films were characterized by scanning electron microscopy. Then with these three materials deposited as the anode, solid electrolyte, cathode, and vanadium as current collector, a rocking-chair type of all-solid-state thin-film-type Lithium-ion rechargeable battery was prepared by using the same sputtering parameters on stainless steel substrates. Electrochemical studies show that the thin film battery has a good charge–discharge characteristic in the voltage range of 0.3–3.5 V, and after 30 cycles the cell performance turned to become stabilized with the charge capacity of 9 μAh/cm2, and capacity loss of single-cycle of about 0.2%. At the same time, due to electronic conductivity of the electrolyte film, self-discharge may exist, resulting in approximately 96.6% Coulombic efficiency.

scholarly journals Lithium-Ion-Conducting Ceramics-Coated Separator for Stable Operation of Lithium Metal-Based Rechargeable Batteries

Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 322
Author(s):  
Ryo Shomura ◽  
Ryota Tamate ◽  
Shoichi Matsuda
Keyword(s):  
Negative Electrode ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Rechargeable Batteries ◽  
Stable Operation ◽  
Lithium Metal ◽  
Interfacial Resistance ◽  
Metal Anode ◽  
Ion Conducting ◽  
Coated Separator

Lithium metal anode is regarded as the ultimate negative electrode material due to its high theoretical capacity and low electrochemical potential. However, the significantly high reactivity of Li metal limits the practical application of Li metal batteries. To improve the stability of the interface between Li metal and an electrolyte, a facile and scalable blade coating method was used to cover the commercial polyethylene membrane separator with an inorganic/organic composite solid electrolyte layer containing lithium-ion-conducting ceramic fillers. The coated separator suppressed the interfacial resistance between the Li metal and the electrolyte and consequently prolonged the cycling stability of deposition/dissolution processes in Li/Li symmetric cells. Furthermore, the effect of the coating layer on the discharge/charge cycling performance of lithium-oxygen batteries was investigated.

scholarly journals Erratum to: “Thin film negative electrode based on silicon composite for lithium-ion batteries”

2017 ◽  
Vol 46 (4) ◽  
pp. 297-297
Author(s):  
A. A. Airapetov ◽  
S. V. Vasiliev ◽  
T. L. Kulova ◽  
M. E. Lebedev ◽  
A. V. Metlitskaya ◽  
...  
Keyword(s):  
Thin Film ◽  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion

New 7Li-NMR Evidence for Lithium Insertion in Disordered Carbon

1997 ◽  
Vol 496 ◽  
Author(s):  
S. Wang ◽  
H. Matsui ◽  
Y. Matsumura ◽  
T. Yamabe
Keyword(s):  
Room Temperature ◽  
Direct Evidence ◽  
Carbon Materials ◽  
Variable Temperature ◽  
Lithium Ion ◽  
Rechargeable Batteries ◽  
Lithium Insertion ◽  
Disordered Structure ◽  
7Li Nmr ◽  
Disordered Carbon

ABSTRACTIn fully-charged carbon materials, we tried to determine the nature of the interaction between Li species and carbon using variable temperature measurements of the Li Knight shift Only one interaction between the Li species and graphite carbon was observed from room temperature to -10°C. However, while only one average interaction between the Li species and the disordered carbon was observed at room temperature, three kinds of interactions were observed at low temperature. These results provide direct evidence for the model which explains why the discharge capacity of the carbon electrode with a disordered structure as an anode can exceed the theoretical capacity of a graphite anode in lithium ion rechargeable batteries.

Interactions between disordered carbon and lithium in lithium ion rechargeable batteries

Carbon ◽  
1995 ◽  
Vol 33 (10) ◽  
pp. 1457-1462 ◽  
Author(s):  
Y. Matsumura ◽  
S. Wang ◽  
J. Mondori
Keyword(s):  
Lithium Ion ◽  
Rechargeable Batteries ◽  
Disordered Carbon

Thin film negative electrode based on silicon composite for lithium-ion batteries

2016 ◽  
Vol 45 (4) ◽  
pp. 285-291
Author(s):  
A. A. Airapetov ◽  
S. V. Vasiliev ◽  
T. L. Kulova ◽  
M. E. Lebedev ◽  
A. V. Metlitskaya ◽  
...  
Keyword(s):  
Thin Film ◽  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion

In situ electrochemical impedance spectroscopy to investigate negative electrode of lithium-ion rechargeable batteries

2004 ◽  
Vol 135 (1-2) ◽  
pp. 255-261 ◽  
Author(s):  
Masayuki Itagaki ◽  
Nao Kobari ◽  
Sachiko Yotsuda ◽  
Kunihiro Watanabe ◽  
Shinichi Kinoshita ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Rechargeable Batteries

Li Storage of Calcium Niobates for Lithium Ion Batteries

2015 ◽  
Vol 15 (10) ◽  
pp. 8103-8107
Author(s):  
Haena Yim ◽  
Seung-Ho Yu ◽  
So Yeon Yoo ◽  
Yung-Eun Sung ◽  
Ji-Won Choi
Keyword(s):  
Thin Film ◽  
Lithium Ion Batteries ◽  
Discharge Capacity ◽  
Coulombic Efficiency ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Potassium Cation ◽  
Layered Perovskite ◽  
Perovskite Layer ◽  
Negative Material

New types of niobates negative electrode were studied for using in lithium-ion batteries in order to alternate metallic lithium anodes. The potassium intercalated compound KCa2Nb3O10 and proton intercalated compound HCa2Nb3O10 were studied, and the electrochemical results showed a reversible cyclic voltammetry profile with acceptable discharge capacity. The as-prepared KCa2Nb3O10 negative electrode had a low discharge capacity caused by high overpotential, but the reversible intercalation and deintercalation reaction of lithium ions was activated after exchanging H+ ions for intercalated K+ ions. The initial discharge capacity of HCa2Nb3O10 was 54.2 mAh/g with 92.1% of coulombic efficiency, compared with 10.4 mAh/g with 70.2% of coulombic efficiency for KCa2Nb3O10 at 1 C rate. The improved electrochemical performance of the HCa2Nb3O10 was related to the lower bonding energy between proton cation and perovskite layer, which facilitate Li+ ions intercalating into the cation site, unlike potassium cation and perovskite layer. Also, this negative material can be easily exfoliated to Ca2Nb3O10 layer by using cation exchange process. Then, obtained two-dimensional nanosheets layer, which recently expected to be an advanced electrode material because of its flexibility, chemical stable, and thin film fabricable, can allow Li+ ions to diffuse between the each perovskite layer. Therefore, this new type layered perovskite niobates can be used not only bulk-type lithium ion batteries but also thin film batteries as a negative material.

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