Pressure-Enhanced Interdiffusion in Amorphous Si/Ge Multilayers: Implications for Defect-Mediated Diffusion

1994 ◽  
Vol 356 ◽  
Author(s):  
Steven D. Theiss ◽  
F. Spaepen ◽  
M. J. Aziz
Keyword(s):  
Diamond Anvil Cell ◽  
Activation Volume ◽  
Applied Pressure ◽  
Ex Situ ◽  
Dangling Bond ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diamond Anvil ◽  
Consistent Increase ◽  
Amorphous Si

AbstractWe have studied the pressure-dependence of the interdiffusion rate in amorphous Si/Ge multilayers. Samples were annealed in an externally-heated diamond anvil cell at 693 K at pressures ranging from 0 to 3.1 GPa. Interdiffusion rates were determined by ex situ x-ray diffraction measurements of the decay of the artificial Bragg peaks associated with the multilayer periodicity. Scaling experiments were performed to factor out the effects of concentration and time dependence in the diffusivity. All samples showed a consistent increase in diffusivity with applied pressure, characterized by a negative activation volume ranging from −44±3 to −37±2 percent of the atomic volume of Si for films ranging in average Si composition from 25 to 71 percent, respectively. These results are consistent with a model for diffusion in amorphous Si and Ge based on dangling bond migration.

Interdiffusion of Amorphous Si/Ge Multilayers Under Hydrostatic Pressure

1993 ◽  
Vol 321 ◽  
Author(s):  
Steven D. Theiss ◽  
S. Mitha ◽  
F. Spaepen ◽  
M. J. Aziz
Keyword(s):  
Hydrostatic Pressure ◽  
Diamond Anvil Cell ◽  
Activation Volume ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rate Of Decay ◽  
Diamond Anvil ◽  
Consistent Increase ◽  
Amorphous Si ◽  
Initial Results

ABSTRACTWe report initial results of an x-ray diffraction study of the pressure-dependence of the interdiffusion rate in amorphous Si/Ge Multilayers. Anneals were performed in a diamond anvil cell at 700 K for various pressures and durations. Interdiffusion was measured by Monitoring the rate of decay of the artificial Bragg peaks associated with the multilayer periodicity. A consistent increase in diffusivity was seen with pressure, characterized by an activation volume of -25±11 percent of the atomic volume of Si. An atomistic mechanism that Might account for such behavior is discussed.

BIRCH, a program for fitting PV data to an Eulerian finite-strain equation of state

1990 ◽  
Vol 23 (5) ◽  
pp. 439-440
Author(s):  
C. R. Ross ◽  
S. L. Webb
Keyword(s):  
Diamond Anvil Cell ◽  
Finite Strain ◽  
Applied Pressure ◽  
X Ray Diffraction ◽  
Unit Cell Parameters ◽  
Recent Improvement ◽  
X Ray ◽  
Cell Parameters ◽  
Diamond Anvil ◽  
Strain Equation

With the recent improvement of high-pressure technology, in particular the diamond-anvil cell, an ever-increasing number of studies are appearing which relate unit-cell parameters (as measured by X-ray diffraction) to the applied pressure.

scholarly journals Bulk modulus of H2O across the ice VII–ice X transition measured by time-resolved x-ray diffraction in dynamic diamond anvil cell experiments

2021 ◽  
Vol 103 (6) ◽  
Author(s):  
A. S. J. Méndez ◽  
F. Trybel ◽  
R. J. Husband ◽  
G. Steinle-Neumann ◽  
H.-P. Liermann ◽  
...  
Keyword(s):  
Bulk Modulus ◽  
Diamond Anvil Cell ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Diamond Anvil

PHASE TRANSITION IN LAYERED PEROVSKITE LIKE MANGANATE Ca3Mn2O7 UNDER HIGH PRESSURE

2001 ◽  
Vol 15 (18) ◽  
pp. 2491-2497 ◽  
Author(s):  
J. L. ZHU ◽  
L. C. CHEN ◽  
R. C. YU ◽  
F. Y. LI ◽  
J. LIU ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Diamond Anvil Cell ◽  
The Other ◽  
Layered Perovskite ◽  
X Ray Diffraction ◽  
Two Phase ◽  
X Ray ◽  
Diamond Anvil

In situ high pressure energy dispersive X-ray diffraction measurements on layered perovskite-like manganate Ca 3 Mn 2 O 7 under pressures up to 35 GPa have been performed by using diamond anvil cell with synchrotron radiation. The results show that the structure of layered perovskite-like manganate Ca 3 Mn 2 O 7 is unstable under pressure due to the easy compression of NaCl-type blocks. The structure of Ca 3 Mn 2 O 7 underwent two phase transitions under pressures in the range of 0~35 GPa. One was at about 1.3 GPa with the crystal structure changing from tetragonal to orthorhombic. The other was at about 9.5 GPa with the crystal structure changing from orthorhombic back to another tetragonal.

scholarly journals Synchrotron X-ray diffraction tomography technique using diamond anvil cell

2011 ◽  
Vol 67 (a1) ◽  
pp. C113-C113
Author(s):  
H. Liu ◽  
L. Wang ◽  
Z. Yu ◽  
L. Kong ◽  
J. Zhao ◽  
...  
Keyword(s):  
Diamond Anvil Cell ◽  
Diffraction Tomography ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diamond Anvil

Construction of laser-heated diamond anvil cell system for in situ x-ray diffraction study at SPring-8

2001 ◽  
Vol 72 (2) ◽  
pp. 1289 ◽  
Author(s):  
Tetsu Watanuki ◽  
Osamu Shimomura ◽  
Takehiko Yagi ◽  
Tadashi Kondo ◽  
Maiko Isshiki
Keyword(s):  
Diffraction Study ◽  
Diamond Anvil Cell ◽  
Cell System ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diamond Anvil ◽  
Laser Heated

Chemistry through cocrystals: pressure-induced polymerization of C2H2·C6H6to an extended crystalline hydrocarbon

2018 ◽  
Vol 20 (10) ◽  
pp. 7282-7294 ◽  
Author(s):  
Matthew D. Ward ◽  
Haw-Tyng Huang ◽  
Li Zhu ◽  
Arani Biswas ◽  
Dmitry Popov ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Single Crystal ◽  
Diamond Anvil Cell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diamond Anvil

The 1 : 1 acetylene–benzene cocrystal, C2H2·C6H6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.

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