Laser-Induced Pretransitional Ordering And Nonlinear Optical Properties Of Rigid-Rod Polymer Suspensions
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ABSTRACTWe investigate the pretransitional behavior in laser-induced alignment of rigid rod-like polytetraflouroethylene (PTFE) suspensions. Using a laser-induced birefringence experiment, we measure both the orientational order parameter and the orientational relaxation time. We find that both increase as the volume fraction of colloidal particles approaches the critical value for the isotropic-nematic phase transition. Experimental results are compared with theory which takes into account the possibility of a first-order phase transition induced by a laser electric field.
2013 ◽
Vol 28
(28)
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pp. 1350140
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1999 ◽
Vol 14
(06)
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pp. 407-415
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2014 ◽
Vol 28
(03)
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pp. 1450008
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1993 ◽
Vol 97
(10)
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pp. 1376-1380
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