Low Resistance Ohmic Contacts to n-Hg1−xCdxTe Using a HgTe Cap Layer

1994 ◽  
Vol 299 ◽  
Author(s):  
Patrick W. Leech ◽  
Geoffrey K. Reeves

AbstractNon-alloyed ohmic contacts of HgTe on Hg1−xCdxTe (x = 0.60) with metallisations of Ti, In and Au have been investigated. Layers of HgTe with thickness in the range from 0.1 μm to 1.0 μm were grown by organometallic epitaxy either as an abrubt or a graded junction, depending on the in-situ annealing conditions. The layer thickness and the extent of interdiffusion with the Hg1−CdxTe were determined using Rutherford backscattering spectrometry (RBS). The results have shown that an abrupt rather than a graded structure was essential in order to achieve the minimum value of specific contact resistance, ρc, of ≈5 × 10−5 Ωcm2. In addition, a critical thickness of HgTe (≥0.2 μm) was required in order to obtain a substantial reduction in ρc. For these metal/HgTe/Hg1−xCdxTe contacts, the metal Ti has produced the lowest values of ρc and greatest adhesion to the HgTe. Both of these properties have been attributed to the strong interfacial reaction of the overlayer of Ti with HgTe.

1993 ◽  
Vol 318 ◽  
Author(s):  
Patrick W. Leech ◽  
Geoffrey K. Reeves

ABSTRACTOhmic contacts to p-type InP with an In0.47Ga0.53As buffer layer and an interposed superlattice of 50 Å In0.47Ga0.53As/ 50 Å InP have been investigated. Initial studies of contacts to In0.47Ga0.53As/ InP without the superlattice structure have shown that Pd/Zn/Pd/Au metallization produced a lower specific contact resistance (pc = 1.1 × 10−4 Ω cm2) than Pd/Ge/Au, and over a wider range of anneal temperature than Au/Zn/Au. The incorporation of the superlattice in the p-In0.47Ga0.53As/ InP structure resulted in Pd/Zn/Pd/Au contacts with pc of 3.2 × 10−5 Ω cm2 as-deposited and 7.5 × 10−6 Ω.cm2 after a 500 °C anneal. The presence of Pd/Zn in the metallization was shown as important in reducing pc. Significant intermixing of the metal layers and In0.47Ga0.53As occured at ≥ 350 °C, as revealed by Rutherford backscattering spectrometry.


2012 ◽  
Vol 717-720 ◽  
pp. 825-828
Author(s):  
Alessia Frazzetto ◽  
Fabrizio Roccaforte ◽  
Filippo Giannazzo ◽  
R. Lo Nigro ◽  
M. Saggio ◽  
...  

This paper reports on the effects of different post-implantation annealings on the electrical properties of interfaces to p-type implanted 4H-SiC. The morphology of p-type implanted 4H-SiC was controlled using a capping layer during post-implantation activation annealing of the dopant. Indeed, the surface roughness of Al-implanted regions strongly depends on the use of the protective capping layer during the annealing. However, while the different morphological conditions do not affect the macroscopical electrical properties of the implanted SiC (such as the sheet resistance), they led to an improvement of the morphology and of the specific contact resistance of Ti/Al Ohmic contacts formed on the implanted regions. These electrical and morphologic improvements were associated with a lowering of Schottky barrier height. Preliminary results showed that the different activation annealing conditions of p-type implanted SiC can affect also the electrical parameters (like threshold voltage and mobility) of lateral MOSFETs.


2001 ◽  
Vol 680 ◽  
Author(s):  
K. O. Schweitz ◽  
T. G. Pribicko ◽  
S. E. Mohney ◽  
T. F. Isaacs-Smith ◽  
J. Williams ◽  
...  

ABSTRACTAs the group III nitride semiconductor technology matures, an increasing number of devices are being fabricated with high Al fraction AlGaN. In this study, ohmic behavior is achieved using Ti/Al/Pt/Au contacts to n-Al0.4Ga0.6N, which is the highest Al fraction for which ohmic contact formation has been reported. The effect of contact composition, pretreatment, and annealing conditions is studied by 30 s isochronal annealing experiments between 500°C and 1000°C. A specific contact resistance ρC of (5±3) × 10−5 ωcm2 is obtained using Ti(26 nm)/Al(74 nm)/Pt(50 nm)/Au(50 nm) contacts to n-Al0.4Ga0.6N annealed in N2 at 800°C; however, this value is shown to be artificially high because the metal sheet resistance RM is 4 ω/⊏ causing an artifact in the data analysis. All contacts with ρC < 10−3 ωcm2 exhibit a local minimum in ρC after annealing at 800°C. The observed increase in ρC upon annealing at 850°C and 900°C, however, is not an artifact originating from a change in RM. The top Au layer is found to play an active role in forming ohmic contacts with low ρC, since omitting the Au layer yields an increase in ρC of two orders of magnitude after annealing at 800°C. Furthermore, leaving out the Au layer requires an annealing temperature of 700°C to result in linear I-V curves for currents up to 100 µA, as opposed to 500°C when the Au layer is present. The role of Au is further studied in Ti(26 nm)/Al(74 nm)/Ni(50 nm)/Au(50 nm) contacts, where Rutherford backscattering spectroscopy reveals Ga in the metal layer and/or Au buried deeper than the original semiconductor-metal interface, and x-ray diffraction indicates the formation of new phases to happen concurrently with a decrease in ρC of three orders of magnitude.


1998 ◽  
Vol 514 ◽  
Author(s):  
P. W. Leech ◽  
G. K. Reeves ◽  
P. Ressel

ABSTRACTPd/Zn/Au contacts to p-In0.53Ga0.47As/InP with various barrier layers (Pd, Pt or LaB,) to the indiffusion of Au have been examined by Rutherford Backscattering Spectrometry (RBS). For the metallisations with a barrier layer of Pd, the ageing of the contacts at 400°C for 20 h produced a widespread indiffusion of Au. In comparison, the incorporation of a layer of Pt or amorphous LaB6 prevented an indiffusion of Au and significantly reduced any outdiffusion of the semiconductor elements. The presence of the barrier layer of Pt or LaB6 produced little or no detrimental increase in specific contact resistance, ρc, for this contact system. Values of ρc in the range 8–10 × 10−6 Ω cm2 were obtained for all of the contacts based on Pd/Zn/Au after annealing at 500°C. A comparison has been made with the characteristics of Pt/Ti/Pt/Au contacts to p-In0.53Ga0.47As/ InP which were shown as stable against the indiffusion of Au.


1994 ◽  
Vol 337 ◽  
Author(s):  
Patrick W Leech ◽  
Geoffrey K. Reeves

ABSTRACTThe electrical properties of Pd/Zn/Pd/Au based ohmic contacts to p-type In0 47Ga0 53As/ InP with an interposed superlattice of 50Å In047Gao 53As/ 50 Å InP have been investigated. In this study, several configurations of the Pd/Zn/Pd/Au metallization were fabricated with varying thicknesses of the Zn and interfacial Pd layers in the range 0 to 400 Å. The lowest values of specific contact resistance, ρc, were 1.2 x 10-5 Ω cm2 as-deposited and 7.5 x 106 Ω cm2 for samples annealed at 500 °C. In the as-deposited structures, ρc was reduced by an increase in thickness of both the Zn and Pd layers to 300 Å. For annealed samples, a critical thickness of the Zn ≥ 50 Å and Pd ≥ 100 Å layers was required in order to significantly reduce the magnitude of ρc. These results are consistent with a model of Pd/Zn contacts based on Zn doping of the interface. Studies of thermal stability of the contacts at 400 °C and 500 °C have shown that the Zn/Pd/Au and Pd/Zn/Pd/Au configurations were significanty lower in ρc at extended ageing times than the Pd/Au contacts.


1992 ◽  
Vol 260 ◽  
Author(s):  
Patrick W. Leech ◽  
Geoffrey K. Reeves ◽  
Yuan H. Li

ABSTRACTThe application of ion beam mixing and ion implantation techniques in the formation of ohmic contacts to n-Hg1-xCdxTe (x = 0.6, 0.7) has been investigated. For experiments in ion beam mixing, an indium layer (15nm thick) on Hg1-xCdxTe wasbombarded with 45keV Te+ ions at doses ranging from 1 × 1013 to 1 × 1016 cm2. Minimum values of specific contact resistance, pc, of 4 × 10-4Ωcm-2 were measured for a dose of 1 × 1016 cm-2 after 200°C annealing; pc was independent of dose in this range. Analysis of the interfaces by Auger depth profile and Rutherford backscattering spectrometry has shown that ion beam mixing produced an enhanced indiffusion of indium. In comparison, samples which were ion implanted with In+ at 50keV prior to metalisation showed a reduction in pc which was strongly dependent on dosage.


1994 ◽  
Vol 339 ◽  
Author(s):  
Nils Lundberg ◽  
M. Östling

ABSTRACTMaterials and electrical evaluation were performed to determine the characteristics of ohmic contacts to 6H-SiC. Both elemental metal (Co) and suicides (CoSi and CoSi2) were studied following heat treatments at 500 °C and 900 °C for 5 hours and 2 hours, respectively. Materials analysis by Rutherford Backscattering Spectrometry (RBS) and X-ray Diffraction (XRD) monitored the temperature stability of the contacts after the annealings. Current density-voltage measurements at elevated temperatures established the specific contact resistance pc.


2014 ◽  
Vol 806 ◽  
pp. 57-60
Author(s):  
Nicolas Thierry-Jebali ◽  
Arthur Vo-Ha ◽  
Davy Carole ◽  
Mihai Lazar ◽  
Gabriel Ferro ◽  
...  

This work reports on the improvement of ohmic contacts made on heavily p-type doped 4H-SiC epitaxial layer selectively grown by Vapor-Liquid-Solid (VLS) transport. Even before any annealing process, the contact is ohmic. This behavior can be explained by the high doping level of the VLS layer (Al concentration > 1020 cm-3) as characterized by SIMS profiling. Upon variation of annealing temperatures, a minimum value of the Specific Contact Resistance (SCR) down to 1.3x10-6 Ω.cm2 has been obtained for both 500 °C and 800 °C annealing temperature. However, a large variation of the SCR was observed for a same process condition. This variation is mainly attributed to a variation of the Schottky Barrier Height.


2007 ◽  
Vol 556-557 ◽  
pp. 1027-1030 ◽  
Author(s):  
Ferdinando Iucolano ◽  
Fabrizio Roccaforte ◽  
Filippo Giannazzo ◽  
A. Alberti ◽  
Vito Raineri

In this work, the structural and electrical properties of Ti/Al/Ni/Au contacts on n-type Gallium Nitride were studied. An ohmic behaviour was observed after annealing above 700°C. The structural analysis showed the formation of an interfacial TiN layer and different phases in the reacted layer (AlNi, AlAu4, Al2Au) upon annealing. The temperature dependence of the specific contact resistance demonstrated that the current transport occurs through thermoionic field emission in the contacts annealed at 600°C, and field emission after annealing at higher temperatures. By fitting the data with theoretical models, a reduction of the Schottky barrier from 1.21eV after annealing at 600°C to 0.81eV at 800°C was demonstrated, together with a strong increase of the carrier concentration at the interface. The reduction of the contact resistance upon annealing was discussed by correlating the structural and electrical characteristics of the contacts.


2012 ◽  
Vol 711 ◽  
pp. 213-217 ◽  
Author(s):  
Anne Elisabeth Bazin ◽  
Frédéric Cayrel ◽  
Mohamed Lamhamdi ◽  
Arnaud Yvon ◽  
Jean Christophe Houdbert ◽  
...  

In this paper, we evaluated gallium nitride heteroepitaxially grown on sapphire (GaN/Sa) and grown on silicon (GaN/Si) faced to implantation doping. Si+ was implanted on low doped n-type epilayers in order to create a plateau around 1020at.cm-3. All the samples were capped with a silicon oxide and annealed between 1000°C and 1150°C. The surface quality was evaluated in terms of roughness, pit density and maximum pit diameter using Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). Finally, the dopant electrical activation was studied with Ti-Al contacts using the circular Transfert Length Method (c-TLM). This study shows that low Specific Contact Resistance (SCR) values of 8x10-5Ω.cm2 and 6x10-6Ω.cm2 are respectively obtained on GaN/Sa sample annealed at 1150°C-2min and on GaN/Si sample annealed at 1150°C-30s, proving that good ohmic contacts are obtained on both materials. Nevertheless, a compromise has to be done between the low SCR values obtained and the GaN surface degradation, observed by AFM and SEM after the different annealing treatments and which could affect the good behaviour of the GaN devices.


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