Non-Destructive X-Ray Diffraction Analysis of the Under-Film Corrosion Processes in Zinc-Coated Steel Sheets by Synchrotron Radiation

1992 ◽  
Vol 280 ◽  
Author(s):  
K. Nose ◽  
K. Kawasaki ◽  
K. Hayashi ◽  
H. Morikawa ◽  
S. Sasaki
Keyword(s):  
Synchrotron Radiation ◽  
Diffraction Analysis ◽  
Salt Spray ◽  
Coated Steel ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Steel Sheets ◽  
Zinc Coated Steel ◽  
Non Destructive

ABSTRACTA highly brilliant x-ray beam from a synchrotron radiation source is a powerful tool to perform non-destructive x-ray diffraction analysis of an under-film corroded region of zinc-coated steel sheets. Investigations to identify corrosion products under the outdoor salt-spray test condition and to reveal their one-dimensional distribution were carried out Simonkolleite (ZnCl2•4Zn(OH)2 ) was identified for the first time at the tip of the under-film corroded region. By the one-dimensional analysis, it was shown that the x-ray diffraction intensity of simonkolleite increased, where that of metal zinc decreased. It was suggested that simonkolleite was formed as the first corrosion product under the outdoor salt-spray test condition.

Hydroxyapatite Precursor Phases Identification by X-Ray Diffraction Using Synchrotron Radiation

2007 ◽  
Vol 330-332 ◽  
pp. 115-118 ◽  
Author(s):  
Silvia R. A. Santos ◽  
Antonella M. Rossi ◽  
Marcelo Henrique Prado da Silva
Keyword(s):  
Synchrotron Radiation ◽  
Diffraction Analysis ◽  
Intermediate Phase ◽  
Octacalcium Phosphate ◽  
Alkali Solution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Low Intensity ◽  
Synchrotron Light ◽  
Precursor Phases

The present study presents the relevance of X-ray diffraction analysis using synchrotron light in the identification of phases with low intensity peaks. Niobium sheets were coated with monetite and then converted to hydroxyapatite in an alkali solution. Octacalcium phosphate was identified as an intermediate phase in the conversion monetite-hydroxyapatite.

scholarly journals Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5400
Author(s):  
Roman D. Marchenko ◽  
Taisiya S. Sukhikh ◽  
Alexey A. Ryadun ◽  
Andrei S. Potapov
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Metal Ions ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray

Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)2(NO3)2]n was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO3)2(CH3OH)]·0.5CH3OH}n was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.

X-ray diffraction analysis of three-dimensional residual stress fields reveals origins of thermal fatigue in uncoated and coated steel

2010 ◽  
Vol 62 (10) ◽  
pp. 774-777 ◽  
Author(s):  
C. Kirchlechner ◽  
K.J. Martinschitz ◽  
R. Daniel ◽  
C. Mitterer ◽  
J. Donges ◽  
...  
Keyword(s):  
Residual Stress ◽  
Diffraction Analysis ◽  
Thermal Fatigue ◽  
Three Dimensional ◽  
Stress Fields ◽  
Coated Steel ◽  
X Ray Diffraction ◽  
X Ray

Synchrotron radiation X-ray diffraction analysis for Bi-based oxide superconducting wire

2010 ◽  
Vol 1 (SRMS-7) ◽  
Author(s):  
S. Uemura ◽  
J. Iihara ◽  
Y. Saito ◽  
K. Yamaguchi ◽  
J. Matsumoto ◽  
...  
Keyword(s):  
Synchrotron Radiation ◽  
Diffraction Analysis ◽  
Crystal Orientation ◽  
Power Transmission ◽  
Process Conditions ◽  
X Ray Diffraction ◽  
Cooling Process ◽  
X Ray ◽  
Superconducting Wire

The Bi-based oxide superconducting wire is one of the most promising materials for practical uses such as electric power transmission, electromagnets and so on. For the higher performances required in these applications, it is necessary to increase the critical current (Ic). We have carried out synchrotron radiation X-ray diffraction analysis to improve our manufacturing processes and thus to achieve higher Ic. We have performed in situ X-ray diffraction measurements during the sintering and cooling processes, and observed the decrease of Bi-2223(=(Bi,Pb)2Sr2Ca2Cu3Ox) phase during the cooling process. We have also evaluated the distribution of the crystal orientation in whole wire thickness, by measuring the rocking curves. We have observed that the distribution of the crystal orientation is improved by a refinement of the process conditions.

Synchrotron radiation in situ X-ray absorption fine structure and in situ X-ray diffraction analysis of a high-performance cobalt catalyst towards the oxygen reduction reaction

2017 ◽  
Vol 19 (45) ◽  
pp. 30749-30755
Author(s):  
Haiying Qin ◽  
Longxia Lin ◽  
Junkang Jia ◽  
Huangliang Ni ◽  
Yan He ◽  
...  
Keyword(s):  
Fine Structure ◽  
Synchrotron Radiation ◽  
Diffraction Analysis ◽  
High Performance ◽  
Cobalt Catalyst ◽  
Reduction Reaction ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Absorption

The evolution of metallic Co to Co(OH)2 and then to CoOOH during the ORR was revealed by in situ XRD combined with in situ XAFS tests.

Effect of Coating with Hydroxyapatite on the Bonding of Bone to Implant

2012 ◽  
Vol 706-709 ◽  
pp. 1661-1666
Author(s):  
Abdelilah Benmarouane ◽  
Pierre Millet ◽  
Thomas Buslaps ◽  
Alain Lodini ◽  
Veijo Honkimäki
Keyword(s):  
Synchrotron Radiation ◽  
Spatial Resolution ◽  
Orthopaedic Surgery ◽  
High Spatial Resolution ◽  
High Energy ◽  
Direct Connection ◽  
X Ray Diffraction ◽  
X Ray ◽  
Natural Bone ◽  
Non Destructive

The aim of the present study was to study the interface implant-bone by synchrotron radiation, the implant has two faces the first one coated with hydroxyapatite and the second uncoated. In orthopaedic surgery, Titanium (Ti-Al-4V) implants are currently coated with hydroxyapatite (HAp), Ca10(PO4)6(OH)2, in order to obtain a stable and functional direct connection between the bone and the implant. At the implant-bone interface, the new bone reconstituted after two months of implantation must have the same properties like the natural bone in order to accept the implant. Therefore we studied the texture of the reconstituted bone crystals at the interface applying non destructive x-ray diffraction. The required high spatial resolution was achieved utilizing high-energy synchrotron radiation on ID15 at ESRF in Grenoble, France.

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