Binder System Containing Polycarbosilane and Polysiiazane for Injection-Molded Si3N4 Parts

1991 ◽  
Vol 249 ◽  
Author(s):  
Sophia R. Su
Keyword(s):  
Thermal Decomposition ◽  
Injection Molding ◽  
Decomposition Rate ◽  
Gas Diffusion ◽  
Removal Mechanism ◽  
Binder System ◽  
Diffusion Effect ◽  
Binder Removal ◽  
Key Factor ◽  
Injection Molded

ABSTRACTPolycarbosilane and polysilazane, precursors of SiC and Si3N4, have been incorporated into the binder system for injection-molded Si3N4-based parts. Property requirements for these precursors as the injection-molding binder are briefly described. The binder removal mechanism is proposed and discussed based on the experimental results. Instead, the gas diffusion effect, rather than fluid wicking, is a key factor. Controlling the thermal decomposition rate of the binder is the key for achieving crack-free dense sintered parts.

Binder Design for Fabricating Internal Crack-Free Injection-Molded Si3N4-Based Ceramics

1991 ◽  
Vol 249 ◽  
Author(s):  
Sophia R. Su
Keyword(s):  
Mass Transfer ◽  
Injection Molding ◽  
Cross Section ◽  
Decomposition Temperature ◽  
Internal Crack ◽  
Large Cross Section ◽  
Binder Removal ◽  
Ceramic Injection Molding ◽  
Injection Molded ◽  
The Right

ABSTRACTBinder design is an important issue in ceramic injection molding technology. The binder decomposition mechanism, which involves thermodynamics, kinetics, as well as heat and mass transfer, controls the binder removal process. This process, in turn, is governed by the thermal and physical characteristics of the organic waxes used, and is the most critical step in injection molding ceramics. In this paper, we present the binder design philosophy and the method of binder selection. A systematic binder removal study focusing on heating rate, setter powder, and sublimable materials was carried out with the selected compositions. As a result of this study, we concluded that the fluid wicking controls the binder removal at the molten temperature of the binder, and the diffusion and permeation-controlled mechanism dominate at the decomposition temperature range of the binder. With the right binder selection, it is feasible to produce internal and external crack-free large cross-section injection-molded ceramic parts.

An Influence of a Binder System to the Rheological Behavior of the SS316L Metal Injection Molding (MIM) Feedstock

2011 ◽  
Vol 264-265 ◽  
pp. 554-558 ◽  
Author(s):  
Khairur Rijal Jamaludin ◽  
Norhamidi Muhamad ◽  
Hooman Abolhasani ◽  
Hadi Murthadha ◽  
Mohd Nizam Ab. Rahman
Keyword(s):  
Activation Energy ◽  
Shear Rate ◽  
Injection Molding ◽  
Rheological Behavior ◽  
Flow Behavior ◽  
Palm Stearin ◽  
Metal Injection Molding ◽  
Binder System ◽  
Flow Behavior Index ◽  
Injection Molded

The influence of a binder system to the rheological behavior of a Metal Injection Molding (MIM) feedstock is presented in the paper. The binder systems used are: a) PEG & PMMA b) Palm stearin & LLDPE and, c) Tapioca starch & LLDPE. The viscosity and shear rate of the feedstocks were measured at various range of temperature and shear rate across the L/D = 10 capillary rheometer. The flow behavior index, n and activation energy, E of each feedstock were measured to show its significance as MIM feedstock. Generally, the result indicates all feedstock exhibits a shear thinning behavior and the binders are suitable as MIM binder. Additionally, the present paper has discovered that the binder system does not have much influence to the activation energy. In order to show the relevance of the rheological behavior to the actual injection molding performance, green parts has been injection molded and the result shows an agreement with the rheological behavior result.

scholarly journals The Effect of Masterbatch Recipes on the Homogenization Properties of Injection Molded Parts

2017 ◽  
Vol 2017 ◽  
pp. 1-7
Author(s):  
László Zsíros ◽  
Dániel Török ◽  
József Gábor Kovács
Keyword(s):  
Injection Molding ◽  
Evaluation Method ◽  
Surface Defects ◽  
Visual Appearance ◽  
Individual Effects ◽  
Key Factor ◽  
Molded Parts ◽  
Injection Molded ◽  
The Individual

Appearance is a key factor in most injection molding applications. Unfortunately, there is no widespread method to objectively test visual appearance, such as color inhomogeneity of the parts or other surface defects. We developed an evaluation method to characterize the color inhomogeneity of injection molded parts. First, we examined manufacturing conditions and masterbatch recipes and then the individual effects of the components and their interactions on homogeneity.

scholarly journals Are We Able to Print Components as Strong as Injection Molded?—Comparing the Properties of 3D Printed and Injection Molded Components Made from ABS Thermoplastic

2021 ◽  
Vol 11 (15) ◽  
pp. 6946
Author(s):  
Bartłomiej Podsiadły ◽  
Andrzej Skalski ◽  
Wiktor Rozpiórski ◽  
Marcin Słoma
Keyword(s):  
Tensile Strength ◽  
Injection Molding ◽  
Mechanical Strength ◽  
Cross Section ◽  
Fused Deposition Modeling ◽  
High Strength ◽  
Large Cross Section ◽  
Fused Deposition ◽  
Injection Molded ◽  
The Cross

In this paper, we are focusing on comparing results obtained for polymer elements manufactured with injection molding and additive manufacturing techniques. The analysis was performed for fused deposition modeling (FDM) and single screw injection molding with regards to the standards used in thermoplastics processing technology. We argue that the cross-section structure of the sample obtained via FDM is the key factor in the fabrication of high-strength components and that the dimensions of the samples have a strong influence on the mechanical properties. Large cross-section samples, 4 × 10 mm2, with three perimeter layers and 50% infill, have lower mechanical strength than injection molded reference samples—less than 60% of the strength. However, if we reduce the cross-section dimensions down to 2 × 4 mm2, the samples will be more durable, reaching up to 110% of the tensile strength observed for the injection molded samples. In the case of large cross-section samples, strength increases with the number of contour layers, leading to an increase of up to 97% of the tensile strength value for 11 perimeter layer samples. The mechanical strength of the printed components can also be improved by using lower values of the thickness of the deposited layers.

scholarly journals A Practical Numerical Approach to Characterizing Non-Linear Shrinkage and Optimizing Dimensional Deviation of Injection-Molded Small Module Plastic Gears

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2092
Author(s):  
Xiansong He ◽  
Wangqing Wu
Keyword(s):  
Injection Molding ◽  
High Speed ◽  
Numerical Approach ◽  
Linear Shrinkage ◽  
Influential Factor ◽  
Dimensional Deviation ◽  
Non Linear ◽  
Injection Molded ◽  
Plastic Gears ◽  
Circle Diameter

This paper was aimed at finding out the solution to the problem of insufficient dimensional accuracy caused by non-linear shrinkage deformation during injection molding of small module plastic gears. A practical numerical approach was proposed to characterize the non-linear shrinkage and optimize the dimensional deviation of the small module plastic gears. Specifically, Moldflow analysis was applied to visually simulate the shrinkage process of small module plastic gears during injection molding. A 3D shrinkage gear model was obtained and exported to compare with the designed gear model. After analyzing the non-linear shrinkage characteristics, the dimensional deviation of the addendum circle diameter and root circle diameter was investigated by orthogonal experiments. In the end, a high-speed cooling concept for the mold plate and the gear cavity was proposed to optimize the dimensional deviation. It was confirmed that the cooling rate is the most influential factor on the non-linear shrinkage of the injection-molded small module plastic gears. The dimensional deviation of the addendum circle diameter and the root circle diameter can be reduced by 22.79% and 22.99% with the proposed high-speed cooling concept, respectively.

scholarly journals Post-Processing Time Dependence of Shrinkage and Mechanical Properties of Injection-Molded Polypropylene

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 22
Author(s):  
Artur Kościuszko ◽  
Dawid Marciniak ◽  
Dariusz Sykutera
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Injection Molding ◽  
Accelerated Aging ◽  
Mold Temperature ◽  
Degree Of Crystallinity ◽  
Injection Mold ◽  
Secondary Crystallization ◽  
Scanning Calorimetry ◽  
Injection Molded

Dimensions of the injection-molded semi-crystalline materials (polymeric products) decrease with the time that elapses from their formation. The post-molding shrinkage is an effect of secondary crystallization; the increase in the degree of polymer crystallinity leads to an increase in stiffness and decrease in impact strength of the polymer material. The aim of this study was to assess the changes in the values of post-molding shrinkage of polypropylene produced by injection molding at two different temperatures of the mold (20 °C and 80 °C), and conditioned for 504 h at 23 °C. Subsequently, the samples were annealed for 24 h at 140 °C in order to conduct their accelerated aging. The results of shrinkage tests were related to the changes of mechanical properties that accompany the secondary crystallization. The degree of crystallinity of the conditioned samples was determined by means of density measurements and differential scanning calorimetry. It was found that the changes in the length of the moldings that took place after removal from the injection mold were accompanied by an increase of 20% in the modulus of elasticity, regardless of the conditions under which the samples were made. The differences in the shrinkage and mechanical properties of the samples resulting from mold temperature, as determined by tensile test, were removed by annealing. However, the samples made at two different injection mold temperature values still significantly differed in impact strength, the values of which were clearly higher for the annealed samples compared to the results determined for the samples immediately after the injection molding.

Mechanical Properties of Injection Molded Rubber Testing Samples

2015 ◽  
Vol 752-753 ◽  
pp. 308-311
Author(s):  
Adam Skrobak ◽  
Michal Stanek ◽  
David Manas ◽  
Martin Ovsik ◽  
Vojtech Senkerik ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Injection Molding ◽  
Standardized Testing ◽  
Rubber Compound ◽  
Testing Sample ◽  
Synthetic Rubber ◽  
Injection Molded

The aim of this article is to demonstrate and asses to what extent there is an impact on the mechanical properties of a standardized testing sample made of rubber compound based on synthetic rubber EPDM and produced by injection molding in comparison with a sample produced by classic preparation (cutting off a compression molded plate) according to the standard ISO 23529.

scholarly journals Effects of Injection Molding Screw Tips on Polymer Mixing

2018 ◽  
Vol 62 (3) ◽  
pp. 241-246 ◽  
Author(s):  
Dániel Török ◽  
József Gábor Kovács
Keyword(s):  
Injection Molding ◽  
Processing Parameters ◽  
Raw Material ◽  
Molding Machine ◽  
Surface Color ◽  
Melt Temperature ◽  
Injection Molding Machine ◽  
Aesthetic Appearance ◽  
Molded Parts ◽  
Injection Molded

In all fields of industry it is important to produce parts with good quality. Injection molded parts usually have to meet strict requirements technically and aesthetically. The aim of the measurements presented in our paper is to investigate the aesthetic appearance, such as surface color homogeneity, of injection molded parts. It depends on several factors, the raw material, the colorants, the injection molding machine and the processing parameters. In this project we investigated the effects of the injection molding machine on surface color homogeneity. We focused on injection molding screw tips and investigated five screw tips with different geometries. We produced flat specimens colored with a masterbatch and investigated color homogeneity. To evaluate the color homogeneity of the specimens, we used digital image analysis software developed by us. After that we measured the plastication rate and the melt temperature of the polymer melt because mixing depends on these factors. Our results showed that the screw tips (dynamic mixers) can improve surface color homogeneity but they cause an increase in melt temperature and a decrease in the plastication rate.

The Characterization and Flow Behavior of 316L Stainless Steel Feedstock for Micro Metal Injection Molding (μMIM)

2010 ◽  
Vol 44-47 ◽  
pp. 2872-2876
Author(s):  
Pei Li Haw ◽  
Norhamidi Muhamad ◽  
Hadi Murthadha
Keyword(s):  
Stainless Steel ◽  
Injection Molding ◽  
316L Stainless Steel ◽  
Flow Behavior ◽  
Palm Stearin ◽  
Metal Injection Molding ◽  
Injection Molding Process ◽  
Binder System ◽  
Molding Process ◽  
Rheological Characterization

The rheological behaviors of the Micro Metal Injection Molding feedstock are important for the stability of the feedstock during micro injection molding process and quality of the final micro-components. Homogeneous feedstocks are preferable for MIM process to ensure the dimensional consistency of molded components and prevent the defects of powder-binder separation or particle segregation. In this work, feedstocks with various formulations of 316L stainless steel and binder system were prepared by using Brabender Plastograph EC Plus mixer. The binder system comprises of palm stearin, polyethelene (PE) and stearic acid. In order to obtain the viscosity, activation energy, flow behavior and mold ability index, the rheological characterization of the feedstocks were investigated in numerous conditions by using Shimadzu 500-D capillary rheometer The study showed that all of the 316L stainless steel feedstocks are homogenous with pseudo-plastic behaviors.

Observation and Evaluation of Scratch Damage Characteristics of Injection Molded, Rubber Toughened Poly(Methylmethacrylate)

2013 ◽  
Author(s):  
Jihun An ◽  
Byoung-Hyun Kang ◽  
Byoung-Ho Choi ◽  
Hyoung-Jun Kim
Keyword(s):  
Electron Microscopy ◽  
Injection Molding ◽  
Acrylonitrile Butadiene Styrene ◽  
Damage Mechanism ◽  
Damage Characteristics ◽  
Rubber Toughened ◽  
Rubber Particles ◽  
Injection Molded ◽  
Engineering Polymers ◽  
Scratch Tests

Poly(methylmethacrylate) (PMMA) is one of popular engineering polymers for many engineering applications such as glass substitutes, medical applications, electronic goods, optical fibers, laser disk optical media and so on. PMMA is a lightweight material with excellent optical properties and balanced mechanical properties. However, PMMA is commonly blended with various functional fillers, and rubber particles are one of them to improve the low impact toughness of unfilled PMMA comparing with other engineering polymers such as polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS) copolymer and so on. PMMA is generally used to make exterior of a commercial product, so scratch characteristics of PMMA is very important in terms of the aesthetic point of view. In this paper, rubber toughened PMMA plates are prepared by injection molding, and static and progressive scratch tests are performed. Samples are prepared by various injection molding conditions, and two orientations (machine direction and transverse direction) of the injection molded plate are considered for scratch tests. Three scratch damage mechanism stages, i.e. mar/ploughing, whitening and cutting stages, are identified by observing the scratch damages and two critical loads to define the variation of scratch damage mechanisms are recorded to evaluate the scratch resistance of rubber toughened PMMA samples. Scratch damage characteristics are examined by various microscopy techniques such as optical microscopy, scanning electron microscopy, transmission electron microscopy, atomic force microscopy, optical profiler and so on. It is clearly observed that scratch damage characteristics of rubber toughened PMMA are changed sensitively for various test conditions due to rubber particles, so it can be known that the mold design should be carefully optimized to improve scratch characteristics of injection molded rubber toughened PMMA product.

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