Selective Mn Doping of Thin Film Zns:Mn Electroluminescent Devices by Laser Photochemical Vapor Deposition

1982 ◽  
Vol 17 ◽  
Author(s):  
A. Kitai ◽  
G.J. Wolga

ABSTRACTU.V. laser radiation from a krypton ion laser was used to dissociate manganese carbonyl [Mn2 (CO)10*] at the surface of a ZnS thin film. The resulting Mn deposit was thermally diffused into the film to form a ZnS:Mn thin film electroluminescent (TFEL) device with spatially selective Mn doping. Process parameters and techniques are described as well as electroluminescence measurements on display elements. Finally we suggest applications of this process to future TFEL displays.

Solar Cells ◽  
1987 ◽  
Vol 21 (1-4) ◽  
pp. 453
Author(s):  
B.N. Baron ◽  
S.S. Hegedus ◽  
S.C. Jackson ◽  
R.E. Rocheleau

1986 ◽  
Vol 75 ◽  
Author(s):  
K. K. King ◽  
V. Tavitian ◽  
D. B. Geohegan ◽  
E. A. P. Cheng ◽  
S. A. Piette ◽  
...  

AbstractThe photochemical growth of polycrystalline and amorphous Ge films on SiO2, GaAs and NaCl by photodissociating GeH4 with excimer laser radiation in parallel geometry is reported. For substrate temperatures (TS) below the pyrolytic threshold for GeH4 (553 K), two distinct regions of film growth are observed. In the 425< TS < 553 K range, the ultraviolet (UV) laser “seeds” the reactor with Ge2H6 which readily pyrolyzes at the surface, forming several monolayers of Ge which subsequently catalyze the pyrolysis of GeH4. The activation energy (Ea) in this region is the same as that for the normal CVD growth of Ge from GeH4 (Ea = 0.9 eV). If, however, the laser is pulsed throughout the film growth run, Ea falls by a factor of at least 2 and growth is observed for TS as low as 300 K. In this laser sustained region, film growth ceases in the absence of UV laser radiation. These results clearly demonstrate the ability of a UV laser to alter the reactor chemistry and dictate the species responsible for film growth.


2014 ◽  
Vol 988 ◽  
pp. 113-116
Author(s):  
Qi Ming Xiao ◽  
Bin Xu ◽  
Jian Feng Xu

Based on chemical vapor deposition (CVD) reaction and numerical analysis of the transmission process, analysis the influence law of the process parameters has been conducted for silicon carbide thin film. A detailed analysis on impact of the chamber pressure, substrate temperature and inlet flow has been realized through the use of CFD and chemical reactions software, coupling fluid flow, chemical reactions and mass transfer process in the deposition of SiC thin film. The result of simulation fully proved that the process parameters have different influence law, especially the chamber pressure.


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