The Buffering Mechanisms in Leaching of Composites of Cement with Radioactive Waste

1982 ◽  
Vol 15 ◽  
Author(s):  
Mary W. Barnes ◽  
Della M. Roy

Composites of cement and radioactive waste are being used for disposal of low level waste and may be used for high level waste. It is important to be able to predict their behavior in case of intrusion of leaching waters. The purpose of this paper is to determine the mechanisms of leaching of the cement and how the presence of radioactive waste components affects these mechanisms in composites.

Author(s):  
Lifang Tian ◽  
Mingfen Wen ◽  
Jing Chen

A large number of nuclear reactors with graphite as moderator and reflector material are facing to be decommissioned now or later, and the radioactive graphite waste is a large part of the involved wastes. In addition, high temperature gas-cooled reactors being developed rapidly use a large quantity of graphite material (up to 95%) in the nuclear fuel elements, besides graphite material as their moderator and reflector material in the reactor cores. Therefore, it is very critical to manage these graphite wastes from the decommissioned and being decommissioned reactors. The part with low-level radioactive contamination that could not be reused now, may be disposed of as solid waste to reduce its volume, and the possibility of its being retrieved and reused in the future with advanced technology should be considered. The other graphite waste with high-level radioactive contamination requires much more consideration. Due to several factors, such as its large quantity, a lack of available disposal sites and public acceptance, it may not be disposed of directly in the repository any more. An option may be the transformation of the high-level radioactive graphite waste into low-level radioactive waste through physical and chemical processes. The current technologies involve, e.g., thermal treatment to release 36Cl, capture of the 14C from the gases of incineration of carbon material and decomposition of carbon dioxide into solid carbon. After these treatments the carbon material might be decontaminated and separated as low-level radioactive waste and a small amount of residual high-level waste could be disposed of ultimately. In order to achieve a sustainable development of graphite material, the maximum utility and the minimal disposal of radioactive graphite should be considered in the management of radioactive graphite waste. It is urgent to explore new technologies for decontaminating and recycling radioactive graphite.


Author(s):  
Philippe Van Marcke ◽  
William Wacquier

ONDRAF/NIRAS, the Belgian Agency for Radioactive Waste and Enriched Fissile Materials, considers geological disposal in poorly indurated clay as the reference solution for the long-term management of high-level waste (HLW) and intermediate and low level waste, long-lived (ILLW-LL). The disposal concept entails the post-conditioning of the waste in disposal packages and the subsequent disposal of these packages in an underground repository. The R&D feasibility programme on geological disposal aims at demonstrating, at a conceptual level, that the proposed disposal system can be constructed, operated and closed.


1977 ◽  
Vol 19 (81) ◽  
pp. 607-617 ◽  
Author(s):  
K. Philberth

AbstractThe waste containers should be retrievable for a few centuries until further research has solved all problems and 90Sr and 137Cs have decayed to less than 0.1%. Safe and fairly cheap retrievability can be guaranteed without container mooring. The paper presents an example: The high-level waste of the whole world for the next 30 years could be put in to 3 × 107 spherical containers with 0.2 m radius and disposed of in an area with 15 km radius and a depth range of 20–100 m under the surface of either the Antarctic or the Green land ice sheet. The deposit does not affect the stability of the sheet. Even the most upsetting natural ice-sheet instabilities and/or climatic changes could not cause radioactive contamination.


1994 ◽  
Vol 50 (6) ◽  
pp. 40-45
Author(s):  
Kristin Shrader-Frechette

2009 ◽  
Vol 1193 ◽  
Author(s):  
Jan Marivoet ◽  
Eef Weetjens

AbstractIn recent years the increasing oil prices and the need for carbon-free energy to limit global warming have resulted in a revival of interests in nuclear energy. Advanced nuclear fuel cycles are being studied worldwide. They aim at making more efficient use of the available resources, reducing the risk of proliferation of nuclear weapons, and facilitating the management of the resulting radioactive waste. Recently, the Red-Impact project has investigated the impact of a number of representative advanced fuel cycles on radioactive waste management, and more specific on geological disposal. The thermal output of the high-level waste arising from advanced fuel cycles in which all the actinides are recycled is reduced with a factor 3 for a 50 years cooling time and with a factor 5 for a 100 years cooling time in comparison with the spent fuel arising from the once-through fuel cycle. This reduction of the thermal output allows for a significant reduction of the length of the disposal galleries and of the size of the repository. Separation of Cs and Sr drastically reduces further the thermal output of the high-level waste, but it requires a long-term management of those heat generating separated waste streams, which contain the very long-lived 135Cs. Recycling all the actinides strongly reduces the radiotoxicity in the waste, resulting in significantly lower doses to an intruder in the case of a human intrusion into the repository. However, the reduction of radiotoxicity has little impact on the main safety indicator of a geological repository, i.e. the effective dose in the case of the expected evolution scenario; for disposal in clay formations, this dose is essentially due to mobile fission and activation products. The deployment of advanced fuel cycles will necessitate the development of low activation materials for the new nuclear facilities and fuels and of specific waste matrices to condition the high-level and medium-level waste streams that will arise from the advanced reprocessing plants.


Author(s):  
Marnix Braeckeveldt ◽  
Luc Ooms ◽  
Gustaaf Geenen

Abstract The BR3 reactor (10.5 MWe) at the Nuclear Research Center SCK•CEN was the first PWR plant installed in Europe and has been shut down in 1987. The BR3 reactor is from 1989 in a decommissioning stage and most of the spent fuel is presently still stored in the deactivation pool of the BR3 plant and has to be evacuated. The BR3 was used as a test-reactor for new fuel types and assemblies (Mixed Oxide (MOX) fuel, fuel rods containing burnable poison (Gd2O3) and other types of fuels). Some fuel rods, having undergone a destructive analysis, are stored in different laboratories at the SCK•CEN. In total, the BR3 spent fuel comprises the equivalent of almost 200 fuel assemblies corresponding to some 5000 fuel rods. Beside the spent BR3 fuel, a limited number of spent fuel rods, with equivalent characteristics as the BR3 fuel but irradiated in research reactors outside Belgium and stored in other buildings at the SCK•CEN nuclear site, were added to the inventory of spent fuel to be evacuated. Various options such as reprocessing and intermediate storage awaiting final disposal were evaluated against criteria as available techniques, safety, waste production and overall costs. Finally the option of an AFR (away-from-reactor) intermediate dry storage of the BR3 and other spent fuel in seven CASTOR BR3® casks was adopted. As the SCK•CEN declared this spent fuel as radioactive waste, NIRAS/ONDRAF, the Belgian radioactive waste management agency became directly involved and the decision was taken to construct a small building at the Belgoprocess nuclear site for storing the CASTOR BR3® casks. Loading at the SCK•CEN followed by transport to Belgoprocess and storage is scheduled to take place at the end of 2001. The CASTOR BR3® cask weighing some 25 tonnes, consists of a monolithic body and has two independent lids with metal seals guaranteeing the long term leak-tightness of the cask. The CASTOR BR3® cask is designed for transport and the intermediate storage of at least 50 years. Although a defect of the leaktightness of a CASTOR BR3® cask is very unlikely to occur, an intervention scenario had to be developed. As no pool is present at the Belgoprocess nuclear site to unload the fuel, an innovative procedure is developed that consists of transferring the basket, containing the spent fuel, into another CASTOR BR3® cask. This operation can be performed in the hot cell of the existing storage building for high level waste at the Belgoprocess site.


Author(s):  
Ewoud Verhoef ◽  
Charles McCombie ◽  
Neil Chapman

The basic concept within both EC funded SAPIERR I and SAPIERR II projects (FP6) is that of one or more geological repositories developed in collaboration by two or more European countries to accept spent nuclear fuel, vitrified high-level waste and other long-lived radioactive waste from those partner countries. The SAPIERR II project (Strategic Action Plan for Implementation of Regional European Repositories) examines in detail issues that directly influence the practicability and acceptability of such facilities. This paper describes the work in the SAPIERR II project (2006–2008) on the development of a possible practical implementation strategy for shared, regional repositories in Europe and lays out the first steps in implementing that strategy.


Author(s):  
Jacques Delay ◽  
Jiri Slovak ◽  
Raymond Kowe

The Implementing Geological Disposal of Radioactive Waste Technology Platform (IGD-TP) was launched in November 2009 to tackle the remaining research, development and demonstration (RD&D) challenges with a view to fostering the implementation of geological disposal programmes for high-level and long-lived waste in Europe. The IGD-TP’s Vision is that “by 2025, the first geological disposal facilities for spent fuel, high-level waste and other long-lived radioactive waste will be operating safely in Europe”. Aside from most of European waste management organisations, the IGD-TP now has 110 members covering most of the RD&D actors in the field of implementing geological disposal of radioactive waste in Europe. The IGD-TP Strategic Research Agenda (SRA), that defines shared RD&D priorities with an important cooperative added value, is used as a basis for the Euratom programme. It provides a vehicle to emphasise RD&D and networking activities that are important for establishing safety cases and fostering disposal implementation. As the IGD-TP brings together the national organisations which have a mandate to implement geological disposal and act as science providers, its SRA also ensures a balance between fundamental science, implementation-driven RD&D and technological demonstration. The SRA is in turn supported by a Deployment Plan (DP) for the Joint Activities to be carried out by the Technology Platform with its members and participants. The Joint Activities were derived from the individual SRA Topics and prioritized and assigned a timeline for their implementation. The deployment scheme of the activities is updated on a yearly basis.


MRS Advances ◽  
2020 ◽  
Vol 5 (5-6) ◽  
pp. 275-282 ◽  
Author(s):  
Vsevolod Igin ◽  
Victor Krasilnikov

Abstract:The paper provides generic overview of legal and regulatory framework of radioactive waste management activities held in Russian Federation and national operator responsibilities and accomplishments. It gives a short description of waste classification scheme used and plans for radioactive waste disposal. In particular the paper provides information on the plans of the FEDERAL STATE UNITARY ENTERPRISE "National operator for radioactive waste management" to construct and operate several near-surface disposal facilities for low and intermediate level waste with total capacity up to 550 000 cubic meter. The paper also provides detailed information on the steps of high-level waste disposal program including site-selection, construction phase of the underground research laboratory (URL) near the city of Zheleznogorsk, Krasnoyarsk Region and research program after the construction of the URL. The paper also describes Russian system and state policy in the field of RW management and gives recommendations for future implementers.


2021 ◽  
pp. 105678952110617
Author(s):  
Jérémy Serveaux ◽  
Carl Labergere ◽  
Frédéric Bumbieler ◽  
Khémais Saanouni

Andra, the French national radioactive waste management agency, is in charge of studying the disposal of high-level and long-lived intermediate-level waste (HLW and ILW-LL) in a deep geological repository. According to the reference concept, it is planned to encapsulate high-level waste in non-alloy P285NH steel overpacks before inserting them into horizontal steel cased micro-tunnels. This work is a part of the study about the long-term behavior of a welded steel overpack subjected to external hydrostatic pressure and several localized loading paths. Indeed, the main objective of this work is to develop the most suitable model for non-alloy steel P285NH to be used in the prediction of the long-term overpack behavior. Dealing with a ductile steel, elastoplastic constitutive equations accounting for mixed nonlinear isotropic and kinematic hardening strongly coupled with ductile isotropic damage are adopted. They are formulated based on the classical thermodynamics of irreversible processes framework with state variables at the macroscopic scale, (Germain, 1973) (Lemaitre 1985, Saanouni 2012). In this paper, a new coupling formulation between the scalar isotropic ductile damage and the deviatoric and spherical part of the Cauchy stress and elastic strain tensors is proposed. In order to calibrate the developed model on P285NH steel, multiple tensile tests are performed using classical cylindrical specimens, notched specimens and double notched specimens. In the last part, some experimental fields are measured using digital image correlation. Application is made to a simplified overpack represented by thick walled cylinder subject to compressive loading path. A FEM (Finite Element method) crushing operation of an overpack’s cylindrical part has simulated and analysed.


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