Photochemical Vapor Deposition of Aluminum Thin Films

1988 ◽  
Vol 129 ◽  
Author(s):  
Mitsugu Hanabusa ◽  
Akira Oikawa ◽  
Peng Ying Cai ◽  
Shigeo Furuno ◽  
Satoshi Iguchi

ABSTRACTUsing dimethylaluminum hydride as the source gas and an ArF laser as the light source, aluminum thin films with low electrical conductivity were deposited via photochemical reactions. To emphasize surface reactions, vapor pressure was kept low with a t pical value of 6.7×10−3 Pa. The laser energy density was typically 23 mJ/cm2 per pulse. The deposition rate of aluminum films became reasonably high above a substrate temperature of 90 °C and increased thereafter with substrate temperature. The electrical resistivity was about four times greater than the bulk aluminum value. A strongly nonlinear dependence of the deposition rates on laser energy density was observed. The incremental change in thickness per pulse increased with the inverse of the pulse repetition rate, which indicated, together with area selectivity, the importance of surface photolysis of absorbed molecules.

1991 ◽  
Vol 219 ◽  
Author(s):  
R. I. Johnson ◽  
G. B. Anderson ◽  
S. E. Ready ◽  
J. B. Boyce

ABSTRACTLaser crystallization of a-Si thin films has been shown to produce materials with enhanced electrical properties and devices that are faster and capable of carrying higher currents. The quality of these polycrystalline films depends on a number of parameters such as laser energy density, shot density, substrate temperature, and the quality of the starting material. We find that the average grain size and transport properties of laser crystallized amorphous silicon films increase substantially with laser energy density, increase only slightly with laser shot density, and are unaffected by substrate temperatures of up to 400°C. The best films are those processed in vacuum but films of fair quality can also be obtained in air and nitrogen atmospheres.


2017 ◽  
Vol 111 (15) ◽  
pp. 152905 ◽  
Author(s):  
Min Gao ◽  
Ravindranath Viswan ◽  
Xiao Tang ◽  
Chung Ming Leung ◽  
Jiefang Li ◽  
...  

2001 ◽  
Vol 693 ◽  
Author(s):  
Man Young Sung ◽  
Woong-Je Sung ◽  
Yong-Il Lee ◽  
Chun-Il Park ◽  
Woo-Boem Choi ◽  
...  

Abstract:GaN thin films on sapphire were grown by RF magnetron sputtering with ZnO buffer layer. The tremendous mismatch between the lattices of GaN and sapphire can be partly overcome by the use of thin buffer layer of ZnO. The dependence of GaN film quality on ZnO buffer layer was investigated by X-ray diffraction(XRD). The properties of the sputtered GaN are strongly dependent on ZnO buffer layer thickness. The optimum thickness of ZnO buffer layer is around 30nm. Using XRD analysis, we have found the optimal substrate temperature which can grow high quality GaN thin film. In addition, the effect of excimer laser annealing(ELA) on structural and electrical properties of GaN thin films was investigated. The surface roughness and images according to the laser energy density were investigated by atomic force microscopy(AFM) and it was confirmed that the crystallization was improved by increasing laser energy density.


Nanomaterials ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 53
Author(s):  
Jian Yu ◽  
Tingting Xiao ◽  
Xuemin Wang ◽  
Xiuwen Zhou ◽  
Xinming Wang ◽  
...  

An appropriate writing field is very important for magnetic storage application of L10 FePt nanocomposite thin films. However, the applications of pure L10 FePt are limited due to its large coercivity. In this paper, the ratios of L10 and non-L10 phase FePt alloy nanoparticles in FePt/MgO (100) nanocomposite thin films were successfully tuned by pulsed laser deposition method. By adjusting the pulsed laser energy density from 3 to 7 J/cm2, the ordering parameter initially increased, and then decreased. The highest ordering parameter of 0.9 was obtained at the pulsed laser energy density of 5 J/cm2. At this maximum value, the sample had the least amount of the soft magnetic phase of almost 0%, as analyzed by a magnetic susceptibility study. The saturation magnetization decreased with the increase in the content of soft magnetic phase. Therefore, the magnetic properties of FePt nanocomposite thin films can be controlled, which would be beneficial for the magnetic applications of these thin films.


1994 ◽  
Vol 343 ◽  
Author(s):  
R. I. Johnson ◽  
G. B. Anderson ◽  
J. B. Boyce ◽  
D. K. Fork ◽  
P. Mei ◽  
...  

ABSTRACTLaser crystallized amorphous silicon thin films on quartz exhibit a peak in the grain size, electron mobility and the Si (111) x-ray intensity as a function of the laser fluence, substrate temperature, film thickness, and the number of laser shots per unit area. The peak in grain size has also been shown to be dependent: on the stability of the pulse-to-pulse laser energy density, particularly at high shot densities. The shape of the distribution profile of the pulse-to-pulse laser fluence can significantly alter the grain growth at higher shot densities. The modified growth can be expressed by a simple model based on the mean and standard deviation of the laser energy density relative to the characteristic fluence at which the grain size, mobility, and Si (111) x-ray intensities are maximized.


2014 ◽  
Vol 783-786 ◽  
pp. 1973-1978
Author(s):  
Fei Chen ◽  
Jun Yan Wu ◽  
Qiang Shen ◽  
Julie M. Schoenung ◽  
Lian Meng Zhang

Good crystalline of ATO thin films is necessary to improve the electrical and optical properties. In this paper, ATO thin films were fabricated using PLD method at high temperature of 550 °C, and the effect of laser energy density on the microstructure, electrical property and optical property of the ATO films is discussed. The results suggest that ATO films show good crystalline when deposited at high temperature of 550 °C. Both the electrical and optical properties have been enhanced with the increasing of laser energy density. When the laser energy density is 5.4 J/cm2, the lowest resistivity of ATO thin film is obtained with the value of 6.52×10-4 Ω·cm and the average optical transmittances is 82.0 %.


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