Self-protective Oxide Nano-Coatings for Enhanced Surface Biocompatibility of Titanium

2015 ◽  
Vol 1806 ◽  
pp. 7-12
Author(s):  
Zeynep Ozdemir ◽  
Valentin Craciun ◽  
Bahar Basim

ABSTRACTThe biocompatibility of an implant material depends on the bulk physical properties in addition to the surface properties. In biomedical engineering and industry Ti and Ti-alloys are very popular biological implant material for their bulk physical properties and strength to weight ratio resembling those of nature bone. It is possible to modify the surface properties of titanium for enhanced surface biocompatibility. The main objective of the this study is to engineer a smart Ti-based prosthesis surface by self induced chemically modified titanium oxide nano-film by the chemical mechanical polishing process (CMP). This new process applied on bio-implants aims at significantly reducing the out-diffusion of Ti and other metallic impurities from prosthesis in contact with body fluids and tissue and simultaneously enhancing the surface mechanical, chemical and biological properties. CMP technique enables the growth of a thicker and denser self-protective native oxide on Ti and Ti alloy samples, while simultaneously inducing a controlled surface roughness. It is demonstrated that the Ti based dental implants with self-protective oxide induced surfaces help minimize chemical and bacterial reactivity in addition to Ti ion dissolution while promoting their biocompatibility through surface patterning. The studied self-protective oxide films can also be utilized for many additional applications including bio-sensors.

Alloy Digest ◽  
2012 ◽  
Vol 61 (5) ◽  

Abstract Tungum alloy combines an unusually high strength-to-weight ratio, with ductility, excellent corrosion resistance, and good fatigue properties. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming. Filing Code: Cu-806. Producer or source: Tungum Ltd.


Alloy Digest ◽  
2008 ◽  
Vol 57 (1) ◽  

Abstract Haynes Ti-3Al-2.5V alloy is used where the strength/weight ratio is of prime importance; the alloy is 43% lighter than 21-6-9 stainless steel. It is most often used in the form of seamless tubing for aircraft hydraulic systems. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on forming, heat treating, and joining. Filing Code: TI-145. Producer or source: Haynes International Inc.


Alloy Digest ◽  
1959 ◽  
Vol 8 (1) ◽  

Abstract G-E ALLOY J-1300 is a precipitation hardening iron-base alloy with an excellent strength to weight ratio. It is recommended for applications in the 1350 F. range. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: SS-83. Producer or source: General Electric Company.


Alloy Digest ◽  
1954 ◽  
Vol 3 (8) ◽  

Abstract Donegal DC-50 is a precipitation hardening stainless steel having high strength-weight ratio. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as casting, heat treating, machining, joining, and surface treatment. Filing Code: SS-17. Producer or source: Donegal Manufacturing Corporation.


Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2295 ◽  
Author(s):  
Ryung Il Kim ◽  
Ju Ho Shin ◽  
Jong Suk Lee ◽  
Jung-Hyun Lee ◽  
Albert S. Lee ◽  
...  

A series of UV-curable hybrid composite blends containing a carboxylic acid functionalized polyimidewith varying amounts of high molecular weight (~1 K) PEG-grafted ladder-structured polysilsesquioxanes copolymerized with methacryl groups were fabricated and their structural, thermal, mechanical, and surface properties characterized. At a composite weight ratio of polyimide above 50 wt.%, a stark shift from amorphous to crystalline polyethylene glycol (PEG) phases were observed, accompanied by a drastic increase in both surface moduli and brittleness index. Moreover, fabricated composites were shown to have a wide range water contact angle, 9.8°–73.8°, attesting to the tunable surface properties of these amphiphilic hybrid polymer composites. The enhanced mechanical properties, combined with the utility of tunable surface hydrophilicity allows for the possible use of these hybrid polymer composites to be utilized as photosensitive polyimide negative photoresists for a myriad of semiconductor patterning processes.


2021 ◽  
Vol 22 (21) ◽  
pp. 11600
Author(s):  
Dong Jin Choi ◽  
Kyoung Choi ◽  
Sang Jun Park ◽  
Young-Jin Kim ◽  
Seok Chung ◽  
...  

Gelatin has excellent biological properties, but its poor physical properties are a major obstacle to its use as a biomaterial ink. These disadvantages not only worsen the printability of gelatin biomaterial ink, but also reduce the dimensional stability of its 3D scaffolds and limit its application in the tissue engineering field. Herein, biodegradable suture fibers were added into a gelatin biomaterial ink to improve the printability, mechanical strength, and dimensional stability of the 3D printed scaffolds. The suture fiber reinforced gelatin 3D scaffolds were fabricated using the thermo-responsive properties of gelatin under optimized 3D printing conditions (−10 °C cryogenic plate, 40–80 kPa pneumatic pressure, and 9 mm/s printing speed), and were crosslinked using EDC/NHS to maintain their 3D structures. Scanning electron microscopy images revealed that the morphologies of the 3D printed scaffolds maintained their 3D structure after crosslinking. The addition of 0.5% (w/v) of suture fibers increased the printing accuracy of the 3D printed scaffolds to 97%. The suture fibers also increased the mechanical strength of the 3D printed scaffolds by up to 6-fold, and the degradation rate could be controlled by the suture fiber content. In in vitro cell studies, DNA assay results showed that human dermal fibroblasts’ proliferation rate of a 3D printed scaffold containing 0.5% suture fiber was 10% higher than that of a 3D printed scaffold without suture fibers after 14 days of culture. Interestingly, the supplement of suture fibers into gelatin biomaterial ink was able to minimize the cell-mediated contraction of the cell cultured 3D scaffolds over the cell culture period. These results show that advanced biomaterial inks can be developed by supplementing biodegradable fibers to improve the poor physical properties of natural polymer-based biomaterial inks.


RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105202-105205 ◽  
Author(s):  
Liting Zhang ◽  
Yaofei Sun ◽  
Wenji Yao ◽  
Guoying Dai ◽  
Ping Wang

Cotton fabric surface functionalization by physical adsorption of CBDIII through a sample soaking process.


Author(s):  
Rui Dai ◽  
Beomjin Kwon ◽  
Qiong Nian

Abstract Stochastic foam with hierarchy order pore structure possesses distinguished physical properties such as high strength to weight ratio, super lightweight, and extremely large specific area. These exceptional properties make stochastic foam as a competitive material for versatile applications e.g., heat exchangers, battery electrodes, automotive components, magnetic shielding, catalyst devices and etc. Recently, the more advanced hollow cellular (shellular) architectures with well-developed structure connections are studied and expected to surpass the solid micro/nanolattices. However, in terms of theoretical predicting and studying of the cellular foam architecture, currently no systematic model can be utilized to accurately capture both of its mechanical and thermal properties especially with hollow struts due to complexity induced by its stochastic and highly reticulate nature. Herein, for the first time, a novel packing three-dimensional (3D) hollow dodecahedron (HPD) model is proposed to simulate the cellular architecture. An electrochemical deposition process is utilized to manufacture the metallic foam with hollow struts. Mechanical and thermal testing of the as-manufactured foams are carried out to compare with the HPD model. HPD model is proved to accurately capture both the topology and the physical properties of stochastic foam at the similar relative density. Particularly, the proposed model makes it possible to readily access and track the physical behavior of stochastic foam architecture. Accordingly, this work will also offer inspiration for designing an efficient foam for specific applications.


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