Geometry-based, n-type-enhanced p-type polymer/metal oxide nanocomposites for high-efficiency, high-specificity conductive systems
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ABSTRACTHematite (α-Fe2O3) nanoparticles were diffused of two different shapes (spherical and cubical) in PEDOT:PSS matrices below the percolation threshold. Increases in conductivity within a distinct range in concentration were observed in the dark and under simulated solar illumination. The effect was ascribed to a generalized Poole-Frenkel effect in conjunction with basic properties of heterojunctions and electrostatic dipoles, and verified through data fitting. A difference in behaviour between sphere- and cube-based nanocomposites was also observed.
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2015 ◽
Vol 6
(3)
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pp. 81-87
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2010 ◽
Vol 157
(6)
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pp. H633
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2015 ◽
Vol 4
(5)
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pp. 222-225
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2012 ◽
Vol 116
(45)
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pp. 23945-23950
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