scholarly journals Electrically flat/optically rough substrates for efficiencies above 10% in n-i-p thin-film silicon solar cells

2012 ◽  
Vol 1426 ◽  
pp. 39-44 ◽  
Author(s):  
Karin Söderström ◽  
Grégory Bugnon ◽  
Franz-Josef Haug ◽  
Christophe Ballif

ABSTRACTSubstrates with extremely low roughness to allow the growth of good-quality silicon material but that nevertheless present high light trapping properties are presented. In a first application, silver reflectors are used in single and tandem-junction amorphous silicon (a-Si:H) solar cells. High initial (stable) efficiencies of 10.4 % (8.1 %) for single-junction a-Si:H cells on glass and 11.1 % (9.2 %) for tandem-junction a-Si:H/a-Si:H cells on plastic are obtained. A second application better suited to multi-junction solar cells based on microcrystalline silicon (μc-Si:H) solar cells is presented: the substrate consists of rough zinc oxide (ZnO) grown on a flat silver reflector which is covered with a-Si:H; polishing of this structure yields an a-Si:H/ZnO interface that provides high light scattering even though the cell is deposited on a flat interface. We present results of ∼ 4-μm-thick μc-Si:H solar cells prepared on such substrates with high open-circuit voltages of 520 mV. A large relative efficiency gain of 20% is observed compared to a co-deposited cell grown directly on an optimized textured substrate.

1998 ◽  
Vol 507 ◽  
Author(s):  
J. Meier ◽  
H. Keppner ◽  
S. Dubail ◽  
U. Kroll ◽  
P. Torres ◽  
...  

ABSTRACTHigher open circuit voltages of the microcrystalline silicon bottom cell have a direct impact on the efficiency of the micromorph (μc-Si:H/a-Si:H) tandem cell. In this paper it is shown that open circuit voltages over 500 mV can be achieved leading to gc-Si:H cell efficiencies of 8.5 %. The behaviour of such cells is characterised both by the illuminated and the dark I-V characteristics in function of cell temperature. Microcrystalline cells with Voc-values higher than 500 mV and micromorph tandems possess in general a lower value of the temperature coefficient of the fill factor and thus of the efficiency, when compared to c-Si. Temperature-dependent dark I-V measurements suggest that the dominant recombination mechanism in lgc-Si:H cells is different from that prevailing in a-Si:H solar cells.


2015 ◽  
Vol 212 (4) ◽  
pp. 840-845 ◽  
Author(s):  
Simon Hänni ◽  
Mathieu Boccard ◽  
Grégory Bugnon ◽  
Matthieu Despeisse ◽  
Jan-Willem Schüttauf ◽  
...  

Author(s):  
James P. Connolly

The analytical modelling of bulk and quantum well solar cells is reviewed. The analytical approach allows explicit estimates of dominant generation and recombination mechanisms at work in charge neutral and space charge layers of the cells. Consistency of the analysis of cell characteristics in the light and in the dark leaves a single free parameter, which is the mean Shockley-Read-Hall lifetime. Bulk PIN cells are shown to be inherently dominated by non-radiative recombination as a result of the doping related non-radiative fraction of the Shockley injection currents. Quantum well PIN solar cells on the other hand are shown to operate in the radiative limit as a result of the dominance of radiative recombination in the space charge region. These features are exploited using light trapping techniques leading to photon recycling and reduced radiative recombination. The conclusion is that the mirror backed quantum well solar cell device features open circuit voltages determined mainly by the higher bandgap neutral layers, with an absorption threshold determined by the lower gap quantum well superlattice.


2006 ◽  
Vol 511-512 ◽  
pp. 415-419 ◽  
Author(s):  
C. Voz ◽  
D. Muñoz ◽  
M. Fonrodona ◽  
I. Martin ◽  
J. Puigdollers ◽  
...  

2008 ◽  
Vol 92 (9) ◽  
pp. 1037-1042 ◽  
Author(s):  
Michael Berginski ◽  
Jürgen Hüpkes ◽  
Aad Gordijn ◽  
Wilfried Reetz ◽  
Timo Wätjen ◽  
...  

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