What really happens to the “vanishing overpack”?

2012 ◽  
Vol 1475 ◽  
Author(s):  
I. G. McKinley ◽  
F. B. Neall ◽  
E. M. Scourse ◽  
H. Kawamura
Keyword(s):  
Radionuclide Transport ◽  
Spent Fuel ◽  
Geological Disposal ◽  
Failure Times ◽  
Bentonite Buffer ◽  
Physical Barriers ◽  
Safety Assessments ◽  
High Level ◽  
Radionuclide Release

ABSTRACTConcepts for the disposal of high-level radioactive waste (HLW) and spent fuel (SF) in several countries include a massive steel overpack within a bentonite buffer. In past conservative safety assessments to demonstrate feasibility of geological disposal, overpacks are assumed to provide complete containment for a given lifetime, after which all fail simultaneously. After failure, they are ignored as physical barriers to radionuclide transport. In order to compare different repository designs for specific sites, however, a more realistic treatment of overpack failure and its subsequent behaviour is needed. In addition to arguing for much longer lifetimes before mechanical failure and a distribution of overpack failure times, such assessment indicates that the presence of the failed overpack greatly constrains radionuclide release from the waste matrix and subsequent migration through the engineered barrier system. It also emphasises the key role of the bentonite buffer and the need to be able to assure its performance over relevant timescales.

Durability of potential plutonium wasteforms under repository conditions

2012 ◽  
Vol 76 (8) ◽  
pp. 2911-2918 ◽  
Author(s):  
G. Deissmann ◽  
S. Neumeier ◽  
G. Modolo ◽  
D. Bosbach
Keyword(s):  
Chemical Reactivity ◽  
Final Decision ◽  
Geological Disposal ◽  
Aqueous Environments ◽  
Safety Case ◽  
Key Issues ◽  
The Uk ◽  
High Level ◽  
Radionuclide Release

AbstractSeparated stocks of UK civil plutonium are currently held as a zero value asset in storage, as there is no final decision about whether they should be treated as a resource for future use as nuclear fuel or as waste. Irrespective of future UK government strategies regarding plutonium, at least a portion of the UK civil plutonium inventory will be designated for geological disposal. In this context, we performed a high-level review of the performance of potential wasteforms for the disposal of separated civil plutonium. The key issues considered were the durability and chemical reactivity of the wasteforms in aqueous environments and the long-term radionuclide release under conditions relevant to geological disposal. The major findings of the review, relevant not only to the situation in the UK but to plutonium disposal in general, are summarized in this paper. The review showed that, in the event of a decision being taken to declare plutonium as a waste for disposal, more systematic studies would be required to constrain the wasteform performance under repository conditions in order to derive realistic source terms for a safety case.

Reactions in the System Basalt/Simulated Spent Fuel/Water

1983 ◽  
Vol 26 ◽  
Author(s):  
D.E. Grandstaff ◽  
G.L. Mckeon ◽  
E.L. Moore ◽  
G.C. Ulmer
Keyword(s):  
Water System ◽  
Potassium Feldspar ◽  
Nuclear Waste Repository ◽  
Spent Fuel ◽  
Secondary Phases ◽  
Glass Dissolution ◽  
Ph Values ◽  
C 30 ◽  
High Level ◽  
Radionuclide Release

ABSTRACTThe Grande Ronde Basalts underlying the Hanford Site are being evaluated as a possible site for a high-level nuclear waste repository. Experiments, in which basalt from the Umtanun flow of the Grande Ronde Basalt and basalt with simulated spent fuel were reacted with synthetic Hanford groundwater, were conducted to determine steady state concentrations which can be used in radionuclide release-rate models. Tests were performed at temperatures of 100°, 200°, and 300°C; 30 MPa pressure, and a solution:solid mass ratio of 10:1 for durations up to 7,000 hr. Solution aliquots were extracted periodically during the experiments for analysis. The pH was measured at 250°C and recalculated to higher temperatures. In the basalt-water system the stable high-temperature pH values achieved were 7.2 (100°C), 7.5 (200°C), and 7.6 (300°C). Solution composition variations are due to mesostasis (glass) dissolution and precipitation of secondary phases. Solution measurements indicate a redox potential (Eh) of about -0.7 volts at 300°C. Secondary phases produced include silica, potassium feldspar, iron oxides, clays, scapolite, and zeolites. Tests in the basalt + simulated spent fuel + water systen show that calculated pH values stabilized near 7.6 (100°C), 7.2 (200°C), and 7.7 (300°C). At higher temperatures, solution concentrations were controlled by secondary phases similar to those found in basalt-water tests. Less than 1% of uranium, thorium, samarium, rhenium, cerium, and palladium were released to solution while somewhat higher amounts of iodine, molybdenum, and cesium were released. The UO2 component was unreactive; however, other components (e.g., cesium-bearing phases) were almost completely dissolved. Secondary phases incorporating radionuclide-analog elements include clays, palladium sulfide, powellite, coffinite, and a potassium-uranium silicate.

Use of Level 1 PSA in the Frame of EPR Licensing

2014 ◽  
Author(s):  
Gabriel Georgescu ◽  
Patricia Dupuy ◽  
Francois Corenwinder
Keyword(s):  
Probabilistic Methods ◽  
Spent Fuel ◽  
Pressurized Water ◽  
Spent Fuel Pool ◽  
Level 1 ◽  
Water Reactors ◽  
High Level ◽  
Design Construction

The French “Technical Guidelines for the design and construction of the next generation of NPPs with Pressurized Water Reactors” specify that the safety demonstration has to be achieved in a deterministic way, supplemented by probabilistic methods. In this context, for the EPR reactor of Flamanville (EPR-FA3), the PSA has been used from the beginning of the design. In the frame of the application for commissioning of EPR-FA3, EdF has to provide an “as-build” full scope PSA for the reactor and for the spent fuel pool, covering the internal events, as well as the internal and external hazards of significant impact. Some of these probabilistic studies were developed and evolved during the EPR design (PSA for “internal events”, specific studies for practically eliminated sequences, long term accident sequences…) and were analysed by IRSN, as French Safety Authority (ASN) technical support, at different EPR project stages (initial design, detailed design, construction application….) leading to many design and studies improvements. Today, in order to make the analysis of the application for the commissioning of the EPR-FA3 reactor more effective, the “anticipated” analysis of this application is in progress in France. In this context, the updated versions of the level 1 probabilistic studies for internal events and hazards were analysed by IRSN in 2013. The results and conclusions of this analysis were presented by IRSN early 2014 during a dedicated meeting of French Standing Group of experts for Reactors safety (SGR). The paper presents the analysis performed by IRSN of EdF EPR-FA3 level 1 probabilistic studies, highlighting the role of PSA to the achievement of high level of safety of EPR reactor.

The Implementing Geological Disposal Technology Platform: Key Challenges in Research and Development in Radioactive Waste Management

2014 ◽  
Author(s):  
Jacques Delay ◽  
Jiri Slovak ◽  
Raymond Kowe
Keyword(s):  
Radioactive Waste ◽  
Waste Management ◽  
Added Value ◽  
High Level Waste ◽  
Spent Fuel ◽  
Geological Disposal ◽  
Technology Platform ◽  
Joint Activities ◽  
The Individual ◽  
High Level

The Implementing Geological Disposal of Radioactive Waste Technology Platform (IGD-TP) was launched in November 2009 to tackle the remaining research, development and demonstration (RD&D) challenges with a view to fostering the implementation of geological disposal programmes for high-level and long-lived waste in Europe. The IGD-TP’s Vision is that “by 2025, the first geological disposal facilities for spent fuel, high-level waste and other long-lived radioactive waste will be operating safely in Europe”. Aside from most of European waste management organisations, the IGD-TP now has 110 members covering most of the RD&D actors in the field of implementing geological disposal of radioactive waste in Europe. The IGD-TP Strategic Research Agenda (SRA), that defines shared RD&D priorities with an important cooperative added value, is used as a basis for the Euratom programme. It provides a vehicle to emphasise RD&D and networking activities that are important for establishing safety cases and fostering disposal implementation. As the IGD-TP brings together the national organisations which have a mandate to implement geological disposal and act as science providers, its SRA also ensures a balance between fundamental science, implementation-driven RD&D and technological demonstration. The SRA is in turn supported by a Deployment Plan (DP) for the Joint Activities to be carried out by the Technology Platform with its members and participants. The Joint Activities were derived from the individual SRA Topics and prioritized and assigned a timeline for their implementation. The deployment scheme of the activities is updated on a yearly basis.

scholarly journals Preliminary modelling of radionuclide migration in the argillaceous sediments of the Sumer Formation (Northwestern Bulgaria)

2020 ◽  
Vol 49 (3) ◽  
pp. 13-18
Author(s):  
Dimitar Antonov ◽  
Madlena Tsvetkova ◽  
Doncho Karastanev
Keyword(s):  
Radioactive Waste Disposal ◽  
High Level Waste ◽  
Spent Fuel ◽  
Radionuclide Migration ◽  
Geological Disposal ◽  
Disposal Facility ◽  
Deep Geological Disposal ◽  
High Level ◽  
Host Rocks ◽  
Selection Of

In Bulgaria, from the preliminary analyses performed for site selection of deep geological disposal of high-level waste (HLW) and spent fuel (SF), it was concluded that the most promising host rocks are the argillaceous sediments of the Sumer Formation (Lower Cretaceous), situated in the Western Fore-Balkan Mts. The present paper aims to compare the transport of three major radionuclides from a hypothetical radioactive waste disposal facility, which incorporates an engineering barrier of bentonite into the argillaceous (marl) medium. The simulations were performed by using HYDRUS-1D computer programme. The results are used for a preliminary estimation of argillaceous sediments as a host rock for geological disposal of HLW.

Safety Assessment of Geological Disposal of High-Level Radioactive Waste in Boom Clay: Relation With the Radionuclide Inventory

2009 ◽  
Author(s):  
Pierre Van Iseghem ◽  
Jan Marivoet
Keyword(s):  
Radioactive Waste ◽  
Safety Assessment ◽  
High Level Waste ◽  
Spent Fuel ◽  
Geological Disposal ◽  
High Level Radioactive Waste ◽  
Boom Clay ◽  
High Level ◽  
Clay Formation ◽  
Parameter Values

This paper discusses the impact of the parameter values used for the transport of radionuclides from high-level radioactive waste to the far-field on the long-term safety of a proposed geological disposal in the Boom Clay formation in Belgium. The methodology of the Safety Assessment is explained, and the results of the Safety Assessment for vitrified high-level waste and spent fuel are presented. The radionuclides having the strongest impact on the dose-to-man for both HLW glass and spent fuel are 79Se, 129I, 126Sn, 36Cl, and 99Tc. Some of them are volatile during the vitrification process, other radionuclides are activation products, and for many of them there is no accurate information on their inventory in the waste form. The hypotheses in the selection of the main parameter values are further discussed, together with the status of the R&D on one of the main dose contributing radionuclides (79Se).

Exploiting Synergies Between the UK and Japanese Geological Disposal Programmes

2010 ◽  
Author(s):  
Ellie Scourse ◽  
Hideki Kawamura ◽  
Ian G. McKinley
Keyword(s):  
Radioactive Waste ◽  
Waste Management ◽  
Geological Disposal ◽  
Nuclear Decommissioning ◽  
Novel Approach ◽  
Deep Geological Disposal ◽  
Safety Assessments ◽  
Site Characterisation ◽  
The Uk ◽  
High Level

The early ’80s UK programme for deep geological disposal of high-level radioactive waste was advanced and at the stage of characterising potential sites. When this project was put on hold in the mid ’80s, much expertise in this field was lost. In Japan R&D in the ’80s resulted in major generic safety assessments to demonstrate feasibility in the ’90s. This led to the establishment of NUMO (Nuclear Waste Management Organization of Japan) and the initiation of siting based on volunteerism. This novel approach required more flexible methodology and tools for site characterisation, repository design and safety assessment. NUMO and supporting R&D organisations in Japan have invested much time and effort preparing for volunteers but, unfortunately, no discussions with potential host communities have yet developed to the point where technical work is initiated. Presently, the UK is moving forward; with the NDA RWMD (Nuclear Decommissioning Agency Radioactive Waste Management Directorate) adopting a NUMO-style volunteering approach and a flexible design catalogue. Communities have already shown interest in volunteering. The situation is thus ideal for collaboration. The paper will expand on the opportunities for the UK and Japan to benefit from an active collaboration and discuss how this can be most efficiently implemented.

Geochemical Processes at the Carbon steel/bentonite Interface in Repository Conditions

2006 ◽  
Vol 985 ◽  
Author(s):  
Elena Torres ◽  
María Jesús Turrero ◽  
Pedro Luis Martin
Keyword(s):  
Carbon Steel ◽  
Exchange Capacity ◽  
Spent Fuel ◽  
Compacted Bentonite ◽  
Bentonite Buffer ◽  
Geological Repository ◽  
Geological Formation ◽  
Gaseous Corrosion ◽  
High Level

AbstractThe Deep Geological Repository (DGR) is currently the most accepted management option for the isolation of high level radioactive wastes. The DGR is based on a multibarrier system, which will limit releases of mobile radionuclides to the biosphere. In the design of the repository the spent fuel is encapsulated in canisters of carbon-steel. The space between the canister and the host geological formation will be filled with bentonite buffer clay. Under the prevailing conditions in a DGR, both localized and generalized corrosion phenomena are possible.Corrosion of the canister will result in formation of solid and gaseous corrosion products, which can influence the behaviour of both the canister and the bentonite. Many studies have been carried out in order to improve the knowledge on the reactivity of these barriers. Most of them have focused on the mineralogical alteration of the bentonite as a function of temperature, time, iron/clay and liquid/rock ratio in batch conditions. The aim of this study is to provide experimental evidences, at repository conditions, on chemical and mineralogical changes during the canister-compacted bentonite interaction: determination of secondary minerals and their alteration reactions, the advance of the corrosion front in the compacted bentonite, and changes in porosity, permeability and cation exchange capacity.

The IAEA Coordinated Research Programme on the Performance of High-Level Waste Forms and Packages Under Repository Conditions

1992 ◽  
Vol 294 ◽  
Author(s):  
Vladimir S. Tsyplenkov
Keyword(s):  
Near Field ◽  
Research Programme ◽  
High Level Waste ◽  
Future Research ◽  
Spent Fuel ◽  
Waste Forms ◽  
Safety Assessments ◽  
High Level ◽  
Coordination Meeting

ABSTRACTThe IAEA initiated, in 1991, a Coordinated Research Programme (CRP), with the aim of promoting the exchange of information on the results obtained by different countries in the performance of high-level waste forms and waste packages under conditions relevant to final repository. These studies are being undertaken to obtain reliable data as input to safety assessments and environmental impact analyses, for final disposal purposes. The CRP includes studies on waste forms that are presently of interest worldwide: borosilicate glass, Synroc and spent fuel.Ten laboratories leading in investigation of high-level waste form performance have already joined the programme. The results of their studies and plans for future research were presented at the first Research Coordination Meeting, held in Karlsruhe, Germany, in November 1991. The technical contributions concentrated on effecting an understanding of dissolution mechanisms of waste forms under simulated repository conditions. A quantitative interpretation of the chemical processes in the near field is considered a prerequisite for long-term predictions and for the formulation of a "source term" for performance assessment studies.

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