Study of the undercooling of Pb-free, flip-chip solder bumps and in situ observation of solidification process

2007 ◽  
Vol 22 (3) ◽  
pp. 557-560 ◽  
Author(s):  
Sung K. Kang ◽  
M.G. Cho ◽  
P. Lauro ◽  
Da-Yuan Shih

The undercooling of flip-chip Pb-free solder bumps was investigated by differential scanning calorimetry (DSC) to understand the effects of solder composition and volume, with and without the presence of an under bump metallurgy (UBM). A large amount of the undercooling (as large as 90 °C) was observed with Sn-rich, flip-chip size solder bumps sitting in a glass mold, while the corresponding undercooling was significantly reduced in the presence of a wettable UBM surface. In addition, the solidification of an array of individual solder bumps was monitored in situ by a video imaging technique during both heating-up and cooling-down cycles. Data obtained by the optical imaging method were used to complement the DSC thermal measurements. A random solidification of the array of bumps was demonstrated during cooling, which also spans a wide temperature range of 40–80 °C. In contrast, an almost simultaneous melting of the bumps was observed during heating.

1991 ◽  
Vol 237 ◽  
Author(s):  
Toyohiko J. Konno ◽  
Robert Sinclair

ABSTRACTThe crystallization of sputter-deposited Si/Al amorphous alloys was examined by transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). In-situ high-resolution TEM reveals the existence of an Al layer between the amorphous matrix and the growing crystalline phase. The activation energy for the growth is about 1.2eV, roughly corresponding to the activation energy of Si diffusion in Al. These two observations support the view that a crystallization mechanism, in which an Al buffer layer provides the shortest reaction path, is responsible for the reaction. The product microstructure exhibits secondary crystallization at a higher temperature.


2015 ◽  
Vol 2015 (1) ◽  
pp. 000799-000805
Author(s):  
Marek Gorywoda ◽  
Rainer Dohle ◽  
Bernd Kandler ◽  
Bernd Burger

Electromigration comprises one of the processes affecting the long-term reliability of electronic devices; it has therefore been the focus of many investigations in recent years. In regards to flip chip packaging technology, the majority of published data is concerned with electromigration in solder connections to metallized organic substrates. Hardly any information is available in the literature on electromigration in lead-free solder connections on thin film ceramic substrates. This work presents results of a study of electromigration in lead-free (SAC305) flip chip solder bumps with a nominal diameter of 40 μm or 30 μm with a pitch of 100 μm on silicon chips assembled onto thin film Al2O3 ceramic substrates. The under bump metallization (UBM) comprised of a 5 μm thick electroless nickel immersion gold (ENIG) layer directly deposited on the AlCu0.5 trace. The ceramic substrates were metallized using a thin film multilayer (NiCr-Au(1.5 μm)-Ni(2 μm) structure on the top of which wettable areas were produced with high precision by depositing flash Au (60 nm) of the required diameter (40 μm or 30 μm). All electromigration tests were performed at the temperature of 125 °C. Initially, one chip assembly with 40 μm and one with 30 μm solder bumps was loaded with the current density of 8 kA/cm2 for 1,000 h. The assemblies did not fail and an investigation with SEM revealed no significant changes to the microstructure of the bumps. Thereafter seven chip assemblies with 40 μm solder bumps and five assemblies with 30 μm bumps were subjected to electromigration tests of 14 kA/cm2 or 25 kA/cm2, respectively. Six of the 40 μm-assemblies failed after 7,000 h and none of the 30 μm-assemblies failed after 2,500 h of test duration so far. Investigation of failed samples performed with SEM and EDX showed asymmetric changes of microstructure in respect to current flow. Several intermetallic phases were found to form in the solder. The predominant damage of the interconnects was found to occur at the cathode contact to chip; the Ni-P layers there showed typical columnar Kirkendall voids caused by migration of Ni from the layers into the solder. Failure of the contacts apparently occurred at the interface between Ni-P and solder. In summary, the results of the study indicate a very high stability of lead-free solder connections on ceramic substrates against electromigration. This high stability is primarily due to a better heat dissipation and thus to a relatively low temperature increase of the ceramic packages caused by resistive heating during flow of electric current. In addition, the type of the metallization used in the study seems to be more resistant to electromigration than the standard PCB metallization as it does not contain a copper layer.


Applied laser ◽  
2015 ◽  
Vol 35 (1) ◽  
pp. 20-24
Author(s):  
王永辉 Wang Yonghui ◽  
林鑫 Lin Xin ◽  
王理林 Wang Lilin ◽  
杨海欧 Yang Haiou ◽  
黄卫东 Huang Weidong

2006 ◽  
Vol 35 (10) ◽  
pp. 1781-1786 ◽  
Author(s):  
C. M. Tsai ◽  
Yi-Shao Lai ◽  
Y. L. Lin ◽  
C. W. Chang ◽  
C. R. Kao

1993 ◽  
Vol 311 ◽  
Author(s):  
Robert Sinclair ◽  
Toyohiko J. Konno

ABSTRACTWe have studied the reactions at metal-metalloid interfaces using high resolution transmission electron microscopy, including in situ observation, and differential scanning calorimetry. There is contrasting behavior depending on the affinity for interaction or segregation. For reactive systems, compound formation ultimately results, but this can be preceded by solidstate amorphization. For non-reactive systems, crystallization of the metalloid is often achieved with nucleation and growth mediated by the metal phase.


2013 ◽  
Vol 750-752 ◽  
pp. 473-476
Author(s):  
Qing Jun Zhang ◽  
Chun Liang Yan ◽  
Zhi Min Cui ◽  
Yao Guang Wu

Using confocal laser microscope with an infrared heater for 45 steel under different rate of solidification dendrite formation in the process of in situ observation, in the melt solidification phase has different cooling rate the cooling of dendrite formation, analysis of cooling rate on final solidified structure. Results show that with the reduction of temperature in the solidification process dendrite growth continuously, new nuclear has been formed, with the speeding up of the cooling rate, the dendritic structure refinement.


2008 ◽  
Vol 15 (6) ◽  
pp. 78-82 ◽  
Author(s):  
Fu-xiang Huang ◽  
Xin-hua Wang ◽  
Jiong-ming Zhang ◽  
Chen-xi Ji ◽  
Yuan Fang ◽  
...  

1996 ◽  
Vol 445 ◽  
Author(s):  
Xiang Dai ◽  
Connie Kim ◽  
Ralf Willecke ◽  
Paul S. Ho

AbstractAn experimental technique of environmental moiré interferometry has been developed for in‐situ monitoring and analysis of thermomechanical deformation of microelectronics packages subjected to thermal loading under a controlled atmosphere. Coupled with fractional fringe analysis and digital image processing, the environmental moiré interferometry technique achieves accurate and realistic deformation monitoring with high sensitivity and excellent spatial resolution. It has been applied to investigate the thermomechanical deformations induced by thermal loading in an underfilled flip‐chip‐on‐board packaging. The effects of temperature change in the range of 102 °C to 22 °C are analyzed for underfill and solder bumps. In addition, shear deformation and shear strains across the solder bumps are determined as a function of temperature. The experimental results are compared with the results of a finite element analysis for modeling verification. Good agreement between the modeling results and experimental measurements has been found in the overall displacement fields. Through this study, the role of underfill in the thermomechanical deformation of the underfilled flip‐chip package is determined.


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