Gluconate controls one-dimensional growth of tellurium nanostructures

2006 ◽  
Vol 21 (2) ◽  
pp. 343-348 ◽  
Author(s):  
Feng Gao ◽  
Qingyi Lu ◽  
Sridhar Komarneni

In this paper, we show for the first time that by using sodium gluconate-assisted solution route, fine, uniform, and single-crystalline tellurium nanorods and nanowires can be synthesized. Sodium gluconate is a green and safe chemical with strong chelating function, and this property may be useful in the fabrication of nanomaterials, especially one-dimensional (1D) nanomaterials. The sodium gluconate acts as both reducing agent and morphology-directing agent and by adjusting the experimental parameters, the lengths and the diameters of the tellurium nanorods could be further controlled in a certain range. This method is a simple and economical route for 1D nanostructure fabrication and might bring about a novel concept for the synthesis of 1D nanostructures with bio-ligand, sodium gluconate.

2008 ◽  
Vol 8 (3) ◽  
pp. 1468-1472 ◽  
Author(s):  
Na Zhang ◽  
Wenbo Bu ◽  
Yunpeng Xu ◽  
Danyu Jiang ◽  
Jianlin Shi

In this paper, we report for the first time the successful synthesis of novel uniform La2(MoO4)3 dendritic single-crystalline nanostructures via a surfactant-assisted hydrothermal approach. The dendritic nanostructure is composed of trunks with length of several micrometers and plenty of side branches. Both of the trunks and the branches are composed of nanoflakes with thickness of 30–50 nm. The branches are oriented nearly parallel to each other and form an angle of about 45° to the trunk. The polyethylene glycol (PEG) acts as a morphology-directing agent, and by adjusting the experimental parameters, the microstructure of the processed materials could be further controlled in a certain range. The action mechanism of the surfactant has been proposed. This method is a simple and economical route for nanostructure fabrication and might provide a practical reference to the controlled synthesis of other micro-architectures. In addition, the photoluminescence properties of La2(MoO4)3:Eu dendritic nanostructures were studied.


Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 469
Author(s):  
Peng Zhao ◽  
Yu Zhang ◽  
Shuai Tang ◽  
Runze Zhan ◽  
Juncong She ◽  
...  

One-dimensional (1D) nanostructures are extensively used in the design of novel electronic devices, sensors, and energy devices. One of the major challenges faced by the electronics industry is the problem of contact between the 1D nanostructure and electrode, which can limit or even jeopardize device operations. Herein, a universal method that can realize good Ohmic and mechanical contact between an individual 1D nanostructure and a tungsten needle at sub-micron or micron scale is investigated and presented in a scanning electron microscope (SEM) chamber with the synergy of an electron beam and electrical current flowing through the welded joint. The linear I‒V curves of five types of individual 1D nanostructures, characterized by in-situ electrical measurements, demonstrate that most of them demonstrate good Ohmic contact with the tungsten needle, and the results of in-situ tensile measurements demonstrate that the welded joints possess excellent mechanical performance. By simulation analysis using the finite element method, it is proved that the local heating effect, which is mainly produced by the electrical current flowing through the welded joints during the welding process, is the key factor in achieving good Ohmic contact.


2015 ◽  
Vol 181 ◽  
pp. 403-421 ◽  
Author(s):  
Gurvinder Singh ◽  
Henry Chan ◽  
T. Udayabhaskararao ◽  
Elijah Gelman ◽  
Davide Peddis ◽  
...  

Self-assembly of inorganic nanoparticles has been studied extensively for particles having different sizes and compositions. However, relatively little attention has been devoted to how the shape and surface chemistry of magnetic nanoparticles affects their self-assembly properties. Here, we undertook a combined experiment–theory study aimed at better understanding of the self-assembly of cubic magnetite (Fe3O4) particles. We demonstrated that, depending on the experimental parameters, such as the direction of the magnetic field and nanoparticle density, a variety of superstructures can be obtained, including one-dimensional filaments and helices, as well as C-shaped assemblies described here for the first time. Furthermore, we functionalized the surfaces of the magnetic nanocubes with light-sensitive ligands. Using these modified nanoparticles, we were able to achieve orthogonal control of self-assembly using a magnetic field and light.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
René Schwonnek ◽  
Koon Tong Goh ◽  
Ignatius W. Primaatmaja ◽  
Ernest Y.-Z. Tan ◽  
Ramona Wolf ◽  
...  

AbstractDevice-independent quantum key distribution (DIQKD) is the art of using untrusted devices to distribute secret keys in an insecure network. It thus represents the ultimate form of cryptography, offering not only information-theoretic security against channel attacks, but also against attacks exploiting implementation loopholes. In recent years, much progress has been made towards realising the first DIQKD experiments, but current proposals are just out of reach of today’s loophole-free Bell experiments. Here, we significantly narrow the gap between the theory and practice of DIQKD with a simple variant of the original protocol based on the celebrated Clauser-Horne-Shimony-Holt (CHSH) Bell inequality. By using two randomly chosen key generating bases instead of one, we show that our protocol significantly improves over the original DIQKD protocol, enabling positive keys in the high noise regime for the first time. We also compute the finite-key security of the protocol for general attacks, showing that approximately 108–1010 measurement rounds are needed to achieve positive rates using state-of-the-art experimental parameters. Our proposed DIQKD protocol thus represents a highly promising path towards the first realisation of DIQKD in practice.


Author(s):  
Zhibin Liu ◽  
Keda Ding ◽  
Zhifu Liu ◽  
Faqiang Zhang ◽  
Huarong Zeng ◽  
...  

2021 ◽  
Vol 87 (2) ◽  
Author(s):  
P. Kim ◽  
R. Jorge ◽  
W. Dorland

A simplified analytical form of the on-axis magnetic well and Mercier's criterion for interchange instabilities for arbitrary three-dimensional magnetic field geometries is derived. For this purpose, a near-axis expansion based on a direct coordinate approach is used by expressing the toroidal magnetic flux in terms of powers of the radial distance to the magnetic axis. For the first time, the magnetic well and Mercier's criterion are then written as a one-dimensional integral with respect to the axis arclength. When compared with the original work of Mercier, the derivation here is presented using modern notation and in a more streamlined manner that highlights essential steps. Finally, these expressions are verified numerically using several quasisymmetric and non-quasisymmetric stellarator configurations including Wendelstein 7-X.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2609
Author(s):  
Abniel Machín ◽  
Kenneth Fontánez ◽  
Juan C. Arango ◽  
Dayna Ortiz ◽  
Jimmy De León ◽  
...  

At present, the world is at the peak of production of traditional fossil fuels. Much of the resources that humanity has been consuming (oil, coal, and natural gas) are coming to an end. The human being faces a future that must necessarily go through a paradigm shift, which includes a progressive movement towards increasingly less polluting and energetically viable resources. In this sense, nanotechnology has a transcendental role in this change. For decades, new materials capable of being used in energy processes have been synthesized, which undoubtedly will be the cornerstone of the future development of the planet. In this review, we report on the current progress in the synthesis and use of one-dimensional (1D) nanostructured materials (specifically nanowires, nanofibers, nanotubes, and nanorods), with compositions based on oxides, nitrides, or metals, for applications related to energy. Due to its extraordinary surface–volume relationship, tunable thermal and transport properties, and its high surface area, these 1D nanostructures have become fundamental elements for the development of energy processes. The most relevant 1D nanomaterials, their different synthesis procedures, and useful methods for assembling 1D nanostructures in functional devices will be presented. Applications in relevant topics such as optoelectronic and photochemical devices, hydrogen production, or energy storage, among others, will be discussed. The present review concludes with a forecast on the directions towards which future research could be directed on this class of nanostructured materials.


Author(s):  
M. Fang ◽  
S. Chandra ◽  
C. B. Park

Experiments were conducted to determine conditions under which good metallurgical bonding was achieved in vertical walls composed of multiple layers of droplets that were fabricated by depositing tin droplets layer by layer. Molten tin droplets (0.75 mm diameter) were deposited using a pneumatic droplet generator on an aluminum substrate. The primary parameters varied in experiments were those found to most affect bonding between droplets on different layers: droplet temperature (varied from 250°C to 325°C) and substrate temperature (varied from 100°C to 190°C). Considering the cooling rate of droplet is much faster than the deposition rate previous deposition layer cooled down too much that impinging droplets could only remelt a thin surface layer after impact. Assuming that remelting between impacting droplets and the previous deposition layer is a one-dimensional Stefan problem with phase change an analytical solution can be found and applied to predict the minimum droplet temperature and substrate temperature required for local remelting. It was experimentally confirmed that good bonding at the interface of two adjacent layers could be achieved when the experimental parameters were such that the model predicted remelting.


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