Electromigration properties of multigrain aluminum thin film conductors as influenced by grain boundary structure

2001 ◽  
Vol 16 (7) ◽  
pp. 2124-2129 ◽  
Author(s):  
O. V. Kononenko ◽  
V. N. Matveev ◽  
D. P. Field

Electromigration rates in polycrystalline interconnect lines are controlled by grain-boundary diffusion. As such, reliability of such interconnects is a direct function of the grain-boundary character distribution in the lines. In the present work, drift velocity experiments were performed on multicrystalline lines of pure Al to determine the electromigration activation energy of the lines. Lines cut from films processed by partially ionized beam deposition techniques were analyzed. One set of lines was analyzed in the as-deposited condition while the other film was annealed before testing. The measured drift velocities varied dramatically between these two types of films, as did the grain-boundary character distributions measured by orientation imaging. The data were analyzed based on Borisov's equation to obtain mean grain-boundary energies. Grain-boundary energy of the film with poor electromigration performance was calculated to be that reported for random boundaries, while that for the more reliable film was calculated to be that reported for twin boundaries in Al. Percolation theory was used to aid explanation of the results based upon the fraction and connectedness of special boundaries in the films.

2005 ◽  
Vol 482 ◽  
pp. 55-62 ◽  
Author(s):  
Tadao Watanabe ◽  
Sadahiro Tsurekawa

This paper discusses micropstructural aspects of brittleness fracture of polycrystalline materials caused by intergranular fracture. Structure-dependent intergranular brittle fracture in bicrystals and polycrystals are discussed and predicted theoretically. Experimental evidence for the structure-dependent intergranular fracture is shown and some general features are discussed to demonstrate the relationship between grain boundary structure/character, grain boundary energy and intergranular fracture strength. Theoretical prediction of the fracture toughness based on the strongest-link theory is introduced for polycrystals with different grain boundary microstructures, primarily defined by the grain boundary character distribution, grain boundary connectivity. Finally recent achievements of successful control of intergranular brittleness by grain boundary engineering based on the strongest-link theory are introduced for different materials.


1999 ◽  
Vol 32 (1-4) ◽  
pp. 187-195 ◽  
Author(s):  
V. Sursaeva ◽  
U. Czubayko ◽  
A. Touflin

Changes of the grain boundary character distribution and texture during normal grain growth have been investigated using the SAC-SEM based method and a 4 circle X-ray texture goniometer on A1 strips with columnar structure. The microstructure of the strips consists of regions with oriented (clusters) and randomly oriented grains. All changes of microstructure are outside the clusters during normal grain growth and consequently no texture change was observed.


2010 ◽  
Vol 659 ◽  
pp. 307-311
Author(s):  
Zoltán Gaál ◽  
Péter János Szabó ◽  
János Ginsztler ◽  
László Dévényi

This paper deals with the investigation of grain boundary engineering processes in case of AISI 304 type austenitic stainless steel. The effects of the thermo-mechanical treatments for the modification of the grain boundary structure are demonstrated on the special grain boundaries. The proper thermo-mechanical treatments can increase the fraction of the CSL-boundaries. Since the CSL-boundaries are resistant against intergranular degradation processes, materials owning enhanced properties can be developed due to these treatments. The investigation of the grain boundary character distribution is carried out by automated electron back scattered diffraction (EBSD) measurements after different thermo-mechanical treatment processes. The effect of the heat treatment duration on the grain boundary structure is examined; the optimal treatment is represented. It is shown by experimental results, that the parameter settings of the evaluation method strongly influence the obtained results.


2007 ◽  
Vol 558-559 ◽  
pp. 879-884 ◽  
Author(s):  
Patricia Gobernado ◽  
Roumen H. Petrov ◽  
Leo Kestens

The grain boundary energy anisotropy in BCC Fe-based polycrystals is considered. The correlation between the energy in BCC random grain boundaries and the distribution of grain boundary planes in the bulk was examined with a special attention on the presence of low index (low surface energy) planes in the internal surfaces. For a BCC structure, {100} and {110} planes are known to be the lowest energy planes dominating the equilibrium crystal shapes. Experimental evidences demonstrated that these planes were predominant in the texture of surfaces controlled by surface energy [2]. Moreover, the relation between the grain boundary character distribution and the crystallographic dependence on the grain boundary energy in the bulk after annealing treatment was studied. The grain character boundary distribution (GCBD) was calculated using the crystallographic information obtained from OIM-EBSD maps from samples showing columnar grains. Preliminary results showed no particular distribution trend within the standard stereographic triangle (001-101-111).


2004 ◽  
Vol 467-470 ◽  
pp. 1063-1068 ◽  
Author(s):  
D. Kinderlehrer ◽  
Irene Livshits ◽  
Gregory S. Rohrer ◽  
Shlomo Ta'asan ◽  
Peng Yu

A mesoscale, variational simulation of grain growth in two-dimensions has been used to explore the effects of grain boundary properties on the grain boundary character distribution. Anisotropy in the grain boundary energy has a stronger influence on the grain boundary character distribution than anisotropy in the grain boundary mobility. As grain growth proceeds from an initially random distribution, the grain boundary character distribution reaches a steady state that depends on the grain boundary energy. If the energy depends only on the lattice misorientation, then the population and energy are related by the Boltzmann distribution. When the energy depends on both lattice misorientation and boundary orientation, the steady state grain boundary character distribution is more complex and depends on both the energy and changes in the gradient of the energy with respect to orientation.


Author(s):  
Khaled J. Al-Fadhalah

The effect of texture on grain boundary character distribution (GBCD) in thermomechanically processed oxygen-free high-conductivity copper has been investigated. Copper samples were cold rolled to a reduction in thickness of 50% and then annealed for 60 min in the range of 400–600°C. GBCD and texture were measured using electron backscatter diffraction. The fraction of special boundaries (Σ3, Σ9, and Σ27) varied from 59% to 71%, with the maximum in the sample annealed at 500°C. The results indicate that cold rolling provided a strong texture of brass type. It was found that the sample annealed at 500°C have texture components of cube, Goss, rotated-Goss, and Y orientations. These texture components were in relation with the formation of annealing twins and Σ3 boundaries. It was also shown that twin-induced GBCD evolution occurred by strain-induced boundary migration, multiple twinning, and conventional recrystallization. Annealing at 600°C caused full recrystallization and grain growth, showing a strong cube recrystallization texture. The grain growth was found to hinder the formation of special boundaries.


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