Dielectric Properties of Nanocomposites of Silver in a Glass-ceramic Containing the Lithium Niobate Phase

2000 ◽  
Vol 15 (6) ◽  
pp. 1324-1330 ◽  
Author(s):  
A. Dan ◽  
D. Chakravorty
Keyword(s):  
Experimental Data ◽  
Dielectric Constant ◽  
Glass Ceramics ◽  
Metal Particles ◽  
Present Specimen ◽  
Charge Model ◽  
Two Component ◽  
Polarization Mechanism ◽  
Space Charge Model ◽  
Silver Metal

Glass-ceramics containing the LiNbO3 phase were used to grow nanometer-sized silver metal particles with median diameters in the range 10.5–17.3 nm. These nanocomposites showed large values of dielectric constant of the order of 103–104. Bergman's space charge model of a two-component composite gave results that differed from the experimental data. The polarization mechanism was concluded to be electronic in origin. An interrupted metallic strand model developed earlier by Rice and Bernasconi was used to explain the results obtained in the present specimen system.

Contributions to Silicon-Hydrogen Bond-Stretching Frequency in Amorphous Si Alloys

1992 ◽  
Vol 258 ◽  
Author(s):  
Z. Jing ◽  
J. L. Whitten ◽  
G. Lucovsky
Keyword(s):  
Experimental Data ◽  
Hydrogen Bond ◽  
Dielectric Constant ◽  
Ab Initio ◽  
Effective Dielectric Constant ◽  
Bond Energies ◽  
Calculated Frequency ◽  
Bond Stretching ◽  
Amorphous Si ◽  
Good Agreement

ABSTRACTWe have performed ab initio calculations and determined the bond-energies and vibrational frequencies of Si-H groups that are: i) attached to Si-atoms as their immediate, and also more distant neighbors; and ii) attached to three O-atoms as their immediate neighbors, but are connected to an all Si-atom matrix. These arrangements simulate bonding geometries on Si surfaces, and the calculated frequency for i) is in good agreement with that of an Si-H group on an Si surface. To compare these results with a-Si:H alloys it is necessary to take into account an additional factor: the effective dielectric constant of the host. We show how to do this, demonstrating the way results of the ab initio calculations should then be compared with experimental data.

Various Applications of Silver Nano-Particles by Ultrasonic Eco-Fabrication

2005 ◽  
Vol 486-487 ◽  
pp. 530-533 ◽  
Author(s):  
Yamato Hayashi ◽  
Hirotsugu Takizawa ◽  
Yoshitaka Saijo ◽  
Tohru Sekino ◽  
Katsuaki Suganuma ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Noble Metal ◽  
Room Temperature ◽  
Silver Oxide ◽  
Nano Particles ◽  
Metal Particles ◽  
Noble Metal Oxides ◽  
Alcohol System ◽  
Silver Metal ◽  
Suitable Process

Applications of silver nano-sized metal particles were investigated for a new, ecologically friendly and economical liquid-solid (silver oxide-alcohol) system. Silver metal oxides as starting materials have merits in metal particles fabrication because these materials are decomposed only by heating in air. That is, noble metal oxide does not use thestrong reduction atmosphere. This reduction is ecologically clean because many noble metal oxides are not toxic, and because O2 is evolved during decomposition. We reduced silver metal oxides by ultrasound and fabricated silver nano metal nanoparticles at room temperature, and various applications were investigated. By choosing a suitable process and conditions, it is reasonable to expect that ultrasonic eco-fabrications can be extended to obtain various silver nano-particles containing materials.

scholarly journals Density and Viscosity of LiCl, LiBr, LiI and Kcl in Aqueous Methanol at 313.15K

2021 ◽  
Vol 37 (5) ◽  
pp. 1083-1090
Author(s):  
V. V. Kadam ◽  
A. B. Nikumbh ◽  
T. B. Pawar ◽  
V. A. Adole
Keyword(s):  
Experimental Data ◽  
Dielectric Constant ◽  
Apparent Molar Volumes ◽  
Strong Electrolyte ◽  
Aqueous Methanol ◽  
Molar Volumes ◽  
Solvent Interactions ◽  
Viscosity Coefficients ◽  
Physicochemical Processes ◽  
Increase With Increase

The densities and viscosities of electrolytes are essential to understand many physicochemical processes that are taking place in the solution. In the present research, the densities and viscosities of lithium halides, LiX (X = Cl, Br, I ) and KCl in (0, 20, 40, 50, 60, 80 and 100) mass % of methanol + water at 313.15K were calculated employing experimental densities (ρ), the apparent molar volumes( ϕv) and limiting apparent molar volumes (0v) of the electrolytes. The (0v) of electrolyte offer insights into solute-solution interactions. In terms of the Jones-Dole equation for strong electrolyte solution, the experimental data of viscosity were explored. Viscosity coefficients A and B have been interpreted and discussed. The B-coefficient values in these systems increase with increase of methanol in the solvents mixtures. This implied that when the dielectric constant of the solvent decreases, so do the solvent-solvent interactions in these systems.

scholarly journals Description of Isotherms of Two-Component Non-Electrolyte Solution Adsorption onto Solids with Structural Heterogeneity of Adsorbents Taken into Consideration

1988 ◽  
Vol 5 (2) ◽  
pp. 106-115 ◽  
Author(s):  
P. Cysewski ◽  
J.K. Garbacz ◽  
S. Biniak ◽  
A. Swiatkowski ◽  
A. Dabrowski
Keyword(s):  
Experimental Data ◽  
Electrolyte Solution ◽  
Structural Heterogeneity ◽  
Liquid Mixtures ◽  
Two Component ◽  
Solid Adsorbents

The concepts of Stoeckli as well as those of Wojsz and Rozwadowski have been adopted for describing adsorption from two-component non-electrolyte liquid mixtures at solid adsorbents taking into account structural heterogeneity of the adsorbent. Some new global adsorption equations have been obtained and verified on the basis of experimental data.

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