Solar-Blind Ultraviolet Photodetectors Based on Vertical Graphene-Hexagonal Boron Nitride Heterostructures

MRS Advances ◽  
2020 ◽  
Vol 5 (37-38) ◽  
pp. 1993-2002
Author(s):  
Jesse E. Thompson ◽  
Darian Smalley ◽  
Masahiro Ishigami

AbstractPhotodetectors operating in the ultraviolet (UV) play a pivotal role in applications such as ozone monitoring and biosensing. One key factor to successfully implementing such photodetectors is that they must be solar-blind to avoid detecting ambient visible and infrared light. Unfortunately, UV photodetectors based on silicon and other typical semiconductors are not natively solar-blind, since their band gap energies are in the visible range. Hexagonal boron nitride (h-BN) is an example of a wide band gap semiconductor which shows promise for use as the absorbing medium in a UV photodetector device, since its band gap is wide enough to make it inherently insensitive to light in the visible range and above. Here we report on the fabrication and characterization of a graphene-h-BN-heterostructure photodetector which utilizes a vertical geometry, in principle allowing for highly scalable production. We find that our device shows a finite photoresponse to illumination by a 254 nm light source, but not to a 365 nm source, thus suggesting that our device is solar-blind.

2009 ◽  
Vol 67 ◽  
pp. 191-196 ◽  
Author(s):  
Lubna Hashmi ◽  
M.S. Qureshi ◽  
R.N. Dubey ◽  
M.M. Malik ◽  
Ishrat Alim ◽  
...  

A broad range of II-VI materials has been investigated in order to produce light in the full visible range for optoelectronic applications. The present investigation was carried out for the spectroscopic analysis and synthesis of wide band gap cadmium sulfide nanoparticles. Large-band gap semiconductors have the added advantage in that; they can support higher electric field before breaking down, which means that they can be used for high-power electronic devices.Synthesis has been carried out using colloidal synthesis technique at low temperature. The size, stabilization and optical properties were studied using UV-vis Spectrophotometer and Spectroflourometer. Further, the structural studies of synthesized powder were carried out using X-ray diffraction technique; which also confirms the formation of desired product. The capping ligand and the impurities present in the sample were characterized by Fourier transform infra red spectroscopy. Synthesized CdS powder dispersed in aqueous media gave the value of 193 nm for the onset wavelength using UV-vis spectrophotometer, which is significantly blue-shifted compared to bulk CdS and shows the quantum confinement effect. From the onset wavelength the radius of CdS quantum dot calculated using the Brus equation was found to be ca. 0.7 nm.


2015 ◽  
Vol 137 (21) ◽  
pp. 6897-6905 ◽  
Author(s):  
Ha-Chul Shin ◽  
Yamujin Jang ◽  
Tae-Hoon Kim ◽  
Jun-Hae Lee ◽  
Dong-Hwa Oh ◽  
...  

2020 ◽  
Vol 44 (22) ◽  
pp. 9238-9247
Author(s):  
Xin Ji ◽  
Yong Guo ◽  
Shugui Hua ◽  
Huiyan Li ◽  
Sunchen Zhang

In this paper, the sensitization photodegradation of single and mixed dyes by wide band gap boron nitride (BN, 3.94 eV) under visible light irradiation has been investigated for the first time.


Nano LIFE ◽  
2012 ◽  
Vol 02 (02) ◽  
pp. 1240005
Author(s):  
YUNLONG LIAO ◽  
ZHONGFANG CHEN

First-principles computations were performed to investigate the uniform bending effect on the electronic properties of armchair boron nitride nanoribbons (aBNNRs) with experimentally obtained width. For both bare and hydrogen-terminated aBNNRs, the band gaps only slightly depend on the uniform bending. The insensitivity of the band structures of BNNRs to the uniform bending makes them ideal materials when their wide band gap character is desired.


2020 ◽  
Vol 8 (28) ◽  
pp. 9755-9762 ◽  
Author(s):  
Itsuki Miyazato ◽  
Tanveer Hussain ◽  
Keisuke Takahashi

The band gaps in boron nitride/phosphorene (h-BN/P) heterostructures are investigated by single-atom-embedding via first principles calculations. The modified heterostructures are potential optoelectronic materials with tunable band gaps.


Micromachines ◽  
2020 ◽  
Vol 11 (12) ◽  
pp. 1128
Author(s):  
Armin Barthel ◽  
Joseph Roberts ◽  
Mari Napari ◽  
Martin Frentrup ◽  
Tahmida Huq ◽  
...  

The suitability of Ti as a band gap modifier for α-Ga2O3 was investigated, taking advantage of the isostructural α phases and high band gap difference between Ti2O3 and Ga2O3. Films of (Ti,Ga)2O3 were synthesized by atomic layer deposition on sapphire substrates, and characterized to determine how crystallinity and band gap vary with composition for this alloy. We report the deposition of high quality α-(TixGa1−x)2O3 films with x = 3.7%. For greater compositions the crystalline quality of the films degrades rapidly, where the corundum phase is maintained in films up to x = 5.3%, and films containing greater Ti fractions being amorphous. Over the range of achieved corundum phase films, that is 0% ≤ x ≤ 5.3%, the band gap energy varies by ∼270 meV. The ability to maintain a crystalline phase at low fractions of Ti, accompanied by a modification in band gap, shows promising prospects for band gap engineering and the development of wavelength specific solar-blind photodetectors based on α-Ga2O3.


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