Mechanical Properties of Diamond Schwarzites: From Atomistic Models to 3D-Printed Structures

MRS Advances ◽  
2020 ◽  
Vol 5 (33-34) ◽  
pp. 1775-1781 ◽  
Author(s):  
Levi C. Felix ◽  
Vladimir Gaál ◽  
Cristiano F. Woellner ◽  
Varlei Rodrigues ◽  
Douglas S. Galvao
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Uniaxial Compression ◽  
Chemical Vapour ◽  
Md Simulations ◽  
Atomic Model ◽  
Fused Deposition Modelling ◽  
Fused Deposition ◽  
Structural Applications ◽  
3D Printed

ABSTRACTTriply Periodic Minimal Surfaces (TPMS) possess locally minimized surface area under the constraint of periodic boundary conditions. Different families of surfaces were obtained with different topologies satisfying such conditions. Examples of such families include Primitive (P), Gyroid (G) and Diamond (D) surfaces. From a purely mathematical subject, TPMS have been recently found in materials science as optimal geometries for structural applications. Proposed by Mackay and Terrones in 1991, schwarzites are 3D crystalline porous carbon nanocrystals exhibiting a TPMS-like surface topology. Although their complex topology poses serious limitations on their synthesis with conventional nanoscale fabrication methods, such as Chemical Vapour Deposition (CVD), schwarzites can be fabricated by Additive Manufacturing (AM) techniques, such as 3D Printing. In this work, we used an optimized atomic model of a schwarzite structure from the D family (D8bal) to generate a surface mesh that was subsequently used for 3D-printing through Fused Deposition Modelling (FDM). This D schwarzite was 3D-printed with thermoplastic PolyLactic Acid (PLA) polymer filaments. Mechanical properties under uniaxial compression were investigated for both the atomic model and the 3D-printed one. Fully atomistic Molecular Dynamics (MD) simulations were also carried out to investigate the uniaxial compression behavior of the D8bal atomic model. Mechanical testings were performed on the 3D-printed schwarzite where the deformation mechanisms were found to be similar to those observed in MD simulations. These results are suggestive of a scale-independent mechanical behavior that is dominated by structural topology.

scholarly journals Parameters Affecting the Mechanical Properties of Three-Dimensional (3D) Printed Carbon Fiber-Reinforced Polylactide Composites

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2456
Author(s):  
Demei Lee ◽  
Guan-Yu Wu
Keyword(s):  
Mechanical Properties ◽  
Carbon Fiber ◽  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Layer By Layer ◽  
Fused Deposition ◽  
Bed Temperature ◽  
3D Printed ◽  
The Impact

Three-dimensional (3D) printing is a manufacturing technology which creates three-dimensional objects layer-by-layer or drop-by-drop with minimal material waste. Despite the fact that 3D printing is a versatile and adaptable process and has advantages in establishing complex and net-shaped structures over conventional manufacturing methods, the challenge remains in identifying the optimal parameters for the 3D printing process. This study investigated the influence of processing parameters on the mechanical properties of Fused Deposition Modelling (FDM)-printed carbon fiber-filled polylactide (CFR-PLA) composites by employing an orthogonal array model. After printing, the tensile and impact strengths of the printed composites were measured, and the effects of different parameters on these strengths were examined. The experimental results indicate that 3D-printed CFR-PLA showed a rougher surface morphology than virgin PLA. For the variables selected in this analysis, bed temperature was identified as the most influential parameter on the tensile strength of CFR-PLA-printed parts, while bed temperature and print orientation were the key parameters affecting the impact strengths of printed composites. The 45° orientation printed parts also showed superior mechanical strengths than the 90° printed parts.

scholarly journals Mechanical properties comparison of PLA, tough PLA and PC 3D printed materials with infill structure – Influence of infill pattern on tensile mechanical properties

2021 ◽  
Vol 1208 (1) ◽  
pp. 012019
Author(s):  
Adi Pandzic ◽  
Damir Hodzic
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
3D Printing ◽  
Material Testing ◽  
Fused Deposition Modelling ◽  
Fused Deposition ◽  
3D Printed ◽  
Printed Materials ◽  
Product Weight

Abstract One of the advantages provided by fused deposition modelling (FDM) 3D printing technology is the manufacturing of product materials with infill structure, which provides advantages such as reduced production time, product weight and even the final price. In this paper, the tensile mechanical properties, tensile strength and elastic modulus, of PLA, Tough PLA and PC FDM 3D printed materials with the infill structure were analysed and compared. Also, the influence of infill pattern on tensile properties was analysed. Material testing were performed according to ISO 527-2 standard. All results are statistically analysed and results showed that infill pattern have influence on tensile mechanical properties for all three materials.

Investigations on 3D printed thermosetting and ceramic-reinforced recycled thermoplastic-based functional prototypes

2019 ◽  
pp. 089270571986462 ◽  
Author(s):  
Rupinder Singh ◽  
Ranvijay Kumar ◽  
Inderpreet Singh
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Surface Hardness ◽  
Acrylonitrile Butadiene Styrene ◽  
Experimental Investigations ◽  
Fused Deposition Modelling ◽  
Ceramic Particles ◽  
Fused Deposition ◽  
Thermoplastic Matrix ◽  
3D Printed

The 3D printing of thermoplastic polymers (both virgin and reinforced with metal/ceramic particles) has been widely explored in recent past with fused deposition modelling (FDM) process. But hitherto very little has been reported on 3D printing of thermoplastics polymers with reinforcement of thermosetting polymers and ceramic particles. This article is an extension of work reported on thermo-mechanical investigations on waste thermosetting polymer bakelite and ceramic (silicon carbide and aluminium oxide) as reinforcement in recycled acrylonitrile butadiene styrene (ABS) thermoplastic matrix for sustainability. The study reports the experimental investigations on mechanical (tensile), morphological, surface hardness and thermal stability analysis of 3D printed functional prototype as tensile specimen (as per ASTM D 638). In the present case study, it has been ascertained that composition/proportion of thermoplastic matrix has a significant role in controlling the mechanical properties, whereas other input process parameters of FDM are insignificant. The results of the study suggest that thermosetting and ceramic-reinforced ABS thermoplastic-based 3D printed parts have mechanical properties at par with unreinforced ABS.

Effect of heat treatment on mechanical properties of 3D printed polylactic acid parts

2021 ◽  
Vol 63 (1) ◽  
pp. 73-78
Author(s):  
Pulkin Gupta ◽  
Sudha Kumari ◽  
Abhishek Gupta ◽  
Ankit Kumar Sinha ◽  
Prashant Jindal
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Polylactic Acid ◽  
Recrystallization Temperature ◽  
Fused Deposition Modelling ◽  
Fused Deposition ◽  
Dog Bone ◽  
Heat Treated ◽  
Maximum Decrease ◽  
3D Printed

Abstract Fused deposition modelling (FDM) is a layer-by-layer manufacturing process type of 3D-printing (3DP). Significant variation in the mechanical properties of 3D printed specimens is observed because of varied process parameters and interfacial bonding between consecutive layers. This study investigates the influence of heat treatment on the mechanical strength of FDM 3D printed Polylactic acid (PLA) parts with constant 3DP parameters and ambient conditions. To meet the objectives, 7 sets, each containing 5 dog-bone shaped samples, were fabricated from commercially available PLA filament. Each set was subjected to heat treatment at a particular temperature for 1 h and cooled in the furnace itself, while one set was left un-treated. The temperature for heat treatment (Th) varied from 30 °C to 130 °C with increments of 10 °C. The heat-treated samples were characterized under tensile loading of 400 N and mechanical properties like Young’s modulus (E), Strain % ( ε ) and Stiffness (k) were evaluated. On comparing the mechanical properties of heat-treated samples to un-treated samples, significant improvements were observed. Heat treatment also altered the geometries of the samples. Mechanical properties improved by 4.88 % to 10.26 % with the maximum being at Th of 110 °C and below recrystallization temperature (Tr) of 65 °C. Deformations also decreased significantly at higher temperatures above 100 °C, by a maximum of 36.06 %. The dimensions of samples showed a maximum decrease of 1.08 % in Tr range and a maximum decrease of 0.31 % in weight at the same temperature. This study aims to benefit the society by establishing suitable Th to recover the lost strength in PLA based FDM 3D printed parts.

scholarly journals 3D Printing of Thermo-Sensitive Drugs

Pharmaceutics ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1524
Author(s):  
Sadikalmahdi Abdella ◽  
Souha H. Youssef ◽  
Franklin Afinjuomo ◽  
Yunmei Song ◽  
Paris Fouladian ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Future Directions ◽  
Digital Light Processing ◽  
Fused Deposition ◽  
Printing Technique ◽  
3D Printed ◽  
Semi Solid ◽  
Selection Of

Three-dimensional (3D) printing is among the rapidly evolving technologies with applications in many sectors. The pharmaceutical industry is no exception, and the approval of the first 3D-printed tablet (Spiratam®) marked a revolution in the field. Several studies reported the fabrication of different dosage forms using a range of 3D printing techniques. Thermosensitive drugs compose a considerable segment of available medications in the market requiring strict temperature control during processing to ensure their efficacy and safety. Heating involved in some of the 3D printing technologies raises concerns regarding the feasibility of the techniques for printing thermolabile drugs. Studies reported that semi-solid extrusion (SSE) is the commonly used printing technique to fabricate thermosensitive drugs. Digital light processing (DLP), binder jetting (BJ), and stereolithography (SLA) can also be used for the fabrication of thermosensitive drugs as they do not involve heating elements. Nonetheless, degradation of some drugs by light source used in the techniques was reported. Interestingly, fused deposition modelling (FDM) coupled with filling techniques offered protection against thermal degradation. Concepts such as selection of low melting point polymers, adjustment of printing parameters, and coupling of more than one printing technique were exploited in printing thermosensitive drugs. This systematic review presents challenges, 3DP procedures, and future directions of 3D printing of thermo-sensitive formulations.

Use of polymer concrete for large-scale 3D printing

2021 ◽  
Vol 27 (3) ◽  
pp. 465-474
Author(s):  
Martin Krčma ◽  
David Škaroupka ◽  
Petr Vosynek ◽  
Tomáš Zikmund ◽  
Jozef Kaiser ◽  
...  
Keyword(s):  
3D Printing ◽  
Large Scale ◽  
Mechanical Performance ◽  
Construction Material ◽  
Polymer Concrete ◽  
Fused Deposition Modelling ◽  
Cast State ◽  
Content Type ◽  
Fused Deposition ◽  
3D Printed

Purpose This paper aims to focus on the evaluation of a polymer concrete as a three-dimensional (3D) printing material. An associated company has developed plastic concrete made from reused unrecyclable plastic waste. Its intended use is as a construction material. Design/methodology/approach The concrete mix, called PolyBet, composed of polypropylene and glass sand, is printed by the fused deposition modelling process. The process of material and parameter selection is described. The mechanical properties of the filled material were compared to its cast state. Samples were made from castings and two different orientations of 3D-printed parts. Three-point flex tests were carried out, and the area of the break was examined. Computed tomography of the samples was carried out. Findings The influence of the 3D printing process on the material was evaluated. The mechanical performance of the longitudinal samples was close to the cast state. There was a difference in the failure mode between the states, with cast parts exhibiting a tougher behaviour, with fractures propagating in a stair-like manner. The 3D-printed samples exhibited high degrees of porosity. Originality/value The results suggest that the novel material is a good fit for 3D printing, with little to no degradation caused by the process. Layer adhesion was shown to be excellent, with negligible effect on the finished part for the longitudinal orientation. That means, if large-scale testing of buildability is successful, the material is a good fit for additive manufacturing of building components and other large-scale structures.

scholarly journals Biogenic Composite Filaments Based on Polylactide and Diatomaceous Earth for 3D Printing

Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4632
Author(s):  
Marta Dobrosielska ◽  
Robert Przekop ◽  
Bogna Sztorch ◽  
Dariusz Brząkalski ◽  
Izabela Zgłobicka ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Mechanical Characteristics ◽  
Filler Particle ◽  
Fused Deposition Modelling ◽  
Water Contact ◽  
Rheological Analysis ◽  
Fused Deposition ◽  
Filler Particle Size ◽  
Composite Properties

New composites containing a natural filler made of diatom shells (frustules), permitting the modification of polylactide matrix, were produced by Fused Deposition Modelling (3D printing) and were thoroughly examined. Two mesh fractions of the filler were used, one of <40 µm and the other of 40−63 µm, in order to check the effect of the filler particle size on the composite properties. The composites obtained contained diatom shells in the concentrations from 0% to 5% wt. (0−27.5% vol.) and were subjected to rheological analysis. The composites obtained as filaments of 1.75 mm in diameter were used for 3D printing. The printed samples were characterized as to hydrophilic–hydrophobic, thermal and mechanical properties. The functional parameters of the printed objects, e.g., mechanical characteristics, stability on contact with water and water contact angle, were measured. The results revealed differences in the processing behavior of the samples as well as the effect of secondary granulation of the filler on the parameters of the printing and mechanical properties of the composites.

scholarly journals Investigation of a Short Carbon Fibre-Reinforced Polyamide and Comparison of Two Manufacturing Processes: Fused Deposition Modelling (FDM) and Polymer Injection Moulding (PIM)

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 672 ◽  
Author(s):  
Elena Verdejo de Toro ◽  
Juana Coello Sobrino ◽  
Alberto Martínez Martínez ◽  
Valentín Miguel Eguía ◽  
Jorge Ayllón Pérez
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Injection Moulding ◽  
New Technologies ◽  
Mechanical Response ◽  
Fused Deposition Modelling ◽  
Layer By Layer ◽  
Polymer Injection ◽  
Fused Deposition

New technologies are offering progressively more effective alternatives to traditional ones. Additive Manufacturing (AM) is gaining importance in fields related to design, manufacturing, engineering and medicine, especially in applications which require complex geometries. Fused Deposition Modelling (FDM) is framed within AM as a technology in which, due to their layer-by-layer deposition, thermoplastic polymers are used for manufacturing parts with a high degree of accuracy and minimum material waste during the process. The traditional technology corresponding to FDM is Polymer Injection Moulding, in which polymeric pellets are injected by pressure into a mould using the required geometry. The increasing use of PA6 in Additive Manufacturing makes it necessary to study the possibility of replacing certain parts manufactured by injection moulding with those created using FDM. In this work, PA6 was selected due to its higher mechanical properties in comparison with PA12. Moreover, its higher melting point has been a limitation for 3D printing technology, and a further study of composites made of PA6 using 3D printing processes is needed. Nevertheless, analysis of the mechanical response of standardised samples and the influence of the manufacturing process on the polyamide’s mechanical properties needs to be carried out. In this work, a comparative study between the two processes was conducted, and conclusions were drawn from an engineering perspective.

scholarly journals GEOMETRY AND MECHANICAL PROPERTIES OF A 3D-PRINTED TITANIUM MICROSTRUCTURE

2018 ◽  
Vol 15 ◽  
pp. 104-108
Author(s):  
Luboš Řehounek ◽  
Petra Hájková ◽  
Petr Vakrčka ◽  
Aleš Jíra
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Uniaxial Compression ◽  
Elastic Moduli ◽  
Weight Ratio ◽  
Porous Structures ◽  
Compression Tests ◽  
Local Material ◽  
3D Printed ◽  
Titanium Microstructure

Construction applications sometimes require use of a material other than construction steel or concrete – mainly in cases, where strength to weight ratio needs to be considered. A suitable solution to this problem are structures manufactured using the 3D printing process, as they have a very good strength to weight ratio (i.e.: Ti-6Al-4V – σ<sub>ult</sub> = 900 MPa and ρ = 4500 kg/m<sup>3</sup>). Trabecular structures are porous structures with local material characteristics identical to their commonly manufactured counterparts, but due to their geometry, they have different global mechanical properties and are suited for special applications. We designed and manufactured six variants of these structures and subjected them to uniaxial compression tests, nanoindentation tests and subsequently evaluated their differences and elastic moduli. The values of global moduli E are in the range of 2.55 GPa – 3.55 GPa for all specimens.

Anisotropy Evaluation of Different Raster Directions, Spatial Orientations, and Fill Percentage of 3D Printed PETG Tensile Test Specimens

2019 ◽  
Vol 821 ◽  
pp. 167-173 ◽  
Author(s):  
Muammel M. Hanon ◽  
Róbert Marczis ◽  
László Zsidai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Tensile Test ◽  
Fused Deposition Modelling ◽  
Elongation At Break ◽  
Know How ◽  
Fused Deposition ◽  
Test Pieces ◽  
3D Printed ◽  
Fill Percentage

In this paper, the mechanical properties of Polyethylene terephthalate-glycol (PETG) tensile test specimens have been investigated. The test pieces were prepared using fused deposition modelling (FDM) 3D printing technology. Three print settings were examined which are: raster direction angles, print orientations, and infill percentage and patterns in order to evaluate the anisotropy of objects when employing FDM print method. The variations in stress-strain curves, tensile strength values and elongation at break among the tested samples were studied and compared. Illustration for the broken specimens after the tensile test was accomplished to know how the test pieces printed with various parameters were fractured. A comparison with some previous results regarding the elongation at break has been carried out.

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