Chloride diffusion in pore water in Olkiluoto veined gneiss and pegmatitic granite from a structural perspective

MRS Advances ◽  
2016 ◽  
Vol 1 (61) ◽  
pp. 4047-4052 ◽  
Author(s):  
J. Sammaljärvi ◽  
J. Ikonen ◽  
M. Voutilainen ◽  
P. Kekäläinen ◽  
A. Lindberg ◽  
...  
Keyword(s):  
Elemental Composition ◽  
Pore Water ◽  
Diffusion Coefficients ◽  
Spent Nuclear Fuel ◽  
Chloride Concentration ◽  
Experimental Results ◽  
Chloride Diffusion ◽  
Crystalline Bedrock ◽  
The Matrix ◽  
Pegmatitic Granite

ABSTRACTSpent nuclear fuel from Finnish power plants is planned to be deposited deep in the crystalline bedrock in Olkiluoto, Finland. The bedrock and more specifically the elemental composition of ground water, which is composed of the fracture water and the matrix pore water, needs to be well characterized to assess the risks inherent to the long term safety of the site. To this end, it is valuable to investigate elemental composition of the matrix pore water since it tends to conserve hydrogeological signals for longer time spans compared to open fracture waters.In this study, the chloride concentration of matrix pore water in veined gneiss (VGN) and pegmatitic granite (PGR) samples were investigated. Chloride was out-diffused from the naturally saturated rock cores into deionized water. Chloride pore diffusion coefficients were derived by modelling the chloride breakthrough curves obtained from the out-diffusion experiments. Two component modelling gave best fit to the experimental results. There two diffusion coefficients were (9±2)×10-11 m2/s and (0.5±0.1)×10-11 m2/s for PGR and (2.5±0.5)×10-11 m2/s and (0.4±0.1)×10-11 m2/s for VGN. Porosity distribution and total porosities of the rock samples were studied with the C-14-PMMA autoradiography. Porosity for PGR was found to be 0.6 % with large mineral transecting fissures, and porosity for VGN was found to be 0.7 % with highly porous mineral clusters connected to each other via grain boundaries and intragranular pores. The findings here show that heterogeneity has to be taken into account in modelling to find better agreement with the experimental results. C-14-PMMA autoradiography results indicate dual-component behavior for diffusion in PGR and VGN which were used in the modelling.

scholarly journals Influence of Pore Structure on Chloride Penetration in Cement Pastes Subject to Wetting-Drying Cycles

2019 ◽  
Vol 2019 ◽  
pp. 1-10
Author(s):  
Honglei Chang ◽  
Zhiwu Zuo ◽  
Mingyue Qu ◽  
Fei Wang ◽  
Zhi Ge ◽  
...  
Keyword(s):  
Pore Structure ◽  
Penetration Rate ◽  
Error Function ◽  
Chloride Concentration ◽  
Total Porosity ◽  
Chloride Penetration ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Cement Pastes ◽  
The Matrix

Copious studies have discovered a phenomenon that a chloride concentration peak appears on the surface of concrete under cyclic drying-wetting environments. In such cases, the chloride diffusion coefficient (D) obtained through directly fitting the standard error function of Fick’s second law is no longer accurate. The more reliable D obtained by the method proposed by Andrade is employed in this research to investigate the influence of pore structure on chloride penetration rate of pastes. The results show that both the effective coefficient (Deff) and the apparent coefficient (Dapp) increase with total porosity, the most probable pore size, and water absorption porosity, suggesting that the increase of the three pore structure parameters accelerates chloride penetration rate under cyclic wetting-drying condition. The increase of the three parameters makes more room available and eases the difficulty for salt solution to enter the matrix and thus leads to the augmentation of chloride transporting in matrix.

scholarly journals Retention of chlorine-36 by a cementitious backfill

2015 ◽  
Vol 79 (6) ◽  
pp. 1297-1305 ◽  
Author(s):  
E. van Es ◽  
J. Hinchliff ◽  
M. Felipe-Sotelo ◽  
A.E. Milodowski ◽  
L.P. Field ◽  
...  
Keyword(s):  
Degradation Products ◽  
Cellulose Degradation ◽  
Chloride Concentration ◽  
Organic Ligands ◽  
Chloride Diffusion ◽  
Cement Matrix ◽  
Chloride Binding ◽  
Breakthrough Time ◽  
The Matrix ◽  
Chlorine 36

AbstractRadial diffusion experiments have been carried out to assess the migration of 36Cl, as chloride, through a cementitious backfill material. Further experiments in the presence of cellulose degradation products were performed to assess the effect of organic ligands on the extent and rate of chloride diffusion. Results show that breakthrough of 36Cl is dependent on chloride concentration: as the carrier concentration increases, both breakthrough time and the quantity retained by the cement matrix decreases. Experiments in the presence of cellulose degradation products also show a decrease in time to initial breakthrough. However, uptake at various carrier concentrations in the presence of organic ligands converges at 45% of the initial concentration as equilibrium is reached. The results are consistent with organic ligands blocking sites on the cement that would otherwise be available for chloride binding, though further work is required to confirm that this is the case. Post-experimental digital autoradiographs of the cement cylinders, and elemental mapping showed evidence of increased 36Cl activity associated with black ash-like particles in the matrix, believed to correspond to partially hydrated glassy calcium-silicate-sulfate-rich clinker.

Diffusion Analysis of Chloride in Concrete Following Electrokinetic Nanoparticle Treatment

2010 ◽  
Author(s):  
K. Kupwade-Patil ◽  
T. J. John ◽  
B. Mathew ◽  
H. Cardenas ◽  
H. Hegab
Keyword(s):  
Diffusion Coefficient ◽  
Reinforced Concrete ◽  
Diffusion Coefficients ◽  
Sea Water ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Chloride Concentration ◽  
Passive Layer ◽  
Chloride Diffusion ◽  
Equivalent Circuit Analysis

Concrete is a highly porous material which is susceptible to the migration of highly deleterious species such as chlorides and sulfates. Various external sources including sea salt spray, direct sea water wetting, deicing salts and brine tanks harbor chlorides that can enter reinforced concrete. Chlorides diffuse into the capillary pores of concrete and come into contact with the rebar. When chloride concentration at the rebar exceeds a threshold level it breaks down the passive layer of oxide, leading to chloride induced corrosion. Application of electrokinetics using positively charged nanoparticles for corrosion protection in reinforced concrete structures is an emerging technology. This technique involves the principle of electrophoretic migration of nanoparticles to hinder chloride diffusion in the concrete. The re-entry of the chlorides is inhibited by the electrodeposited assembly of the nanoparticles at the rebar interface. In this work electrochemical impedance spectroscopy (EIS) combined with equivalent circuit analysis was used to predict chloride diffusion coefficients as influenced by nanoparticle treatments. Untreated controls exhibited a diffusion coefficient of 3.59 × 10−12 m2/s which is slightly higher than the corrosion initiation benchmark value of 1.63 × 10−12 m2/s that is noted in the literature for mature concrete with a 0.5 water/cement mass ratio. The electrokinetic nanoparticle (EN) treated specimens exhibited a diffusion coefficient of 1.41 × 10−13m2/s which was 25 times lower than the untreated controls. Following an exposure period of three years the mature EN treated specimens exhibited lower chloride content by a factor of 27. These findings indicate that the EN treatment can significantly lower diffusion coefficients thereby delaying the initiation of corrosion.

Through diffusion study on Olkiluoto veined gneiss and pegmatitic granite from a structural perspective

MRS Advances ◽  
2016 ◽  
Vol 1 (61) ◽  
pp. 4041-4046 ◽  
Author(s):  
Mikko Voutilainen ◽  
Jussi Ikonen ◽  
Juuso Sammaljärvi ◽  
Jukka Kuva ◽  
Antero Lindberg ◽  
...  
Keyword(s):  
Pore Structure ◽  
Power Plants ◽  
Spent Nuclear Fuel ◽  
Knudsen Diffusion ◽  
Effective Diffusion ◽  
Crystalline Bedrock ◽  
Through Diffusion ◽  
The Difference ◽  
Micrometer Scale ◽  
Pegmatitic Granite

ABSTRACTSpent nuclear fuel from Finnish power plants is planned to be deposited deep in the crystalline bedrock in Olkiluoto, Finland. The bedrock needs to be well characterized to assess the risks inherent to the long term safety of the site. In the bedrock the possibly released radionuclides are mainly transported by water conducting fractures and their transport is retarded by diffusion and sorption. In porous materials these properties are typically linked to microscopic pore structure (pore size distribution, tortuosity and constrictivity) and chemical nature of the minerals and groundwater.In this work transport properties of veined gneiss (VGN) and pegmatitic granite (PGR) samples from Olkiluoto were studied using various through diffusion experiments and the C-14-PMMA autoradiography. Through diffusion experiments were performed on rock cores using HTO and 36Cl in water phase and He in gas phase as tracers. The effective diffusion coefficients (De) determined for the VGN were found to be dependent on the tracer molecule (De(HTO) < De(He) < De(Cl)) whereas for the PGR such a dependence was not found. The porosity distributions determined by the C-14-PMMA autoradiography revealed the difference in the pore structure between the samples. The porosity of VGN consists mostly of grain boundary pores and pores between biotite lamellae. Due to a high content of nanometer scale pores anion exclusion affected the results of 36Cl and Knudsen diffusion the ones of He for VGN. Furthermore, in the PGR micrometer scale intra- and intergranular fissures form a connected network for diffusive transport and thus all tracers diffuse at the same rate.

Effect of W/B to the Time Dependent Chloride Diffusion in Concrete with GGBS

2012 ◽  
Vol 174-177 ◽  
pp. 144-147
Author(s):  
Lu Guang Song ◽  
Wei Sun ◽  
Jian Ming Gao
Keyword(s):  
Diffusion Coefficients ◽  
Chloride Concentration ◽  
Time Dependent ◽  
Chloride Diffusion ◽  
Concentration Increase ◽  
Apparent Diffusion Coefficients ◽  
Apparent Diffusion ◽  
Influence Of Water ◽  
Binder Ratio ◽  
Water To Binder Ratio

This paper studied the influence of water to binder ratio to time dependent diffusion coefficients in concrete exposed to marine environments. And a refined diffusion model which considered the time dependent apparent diffusion coefficients and time dependent surface chloride concentration was established. It was found that both apparent diffusion coefficients and surface chloride concentration are time dependent and both are significantly influenced by water to binder ratio. Apparent diffusion decrease with time while surface chloride concentration increase with time. but water to binder ratio has similar influence to the constant of time dependent diffusion coefficients and the parameter of time dependent surface chloride concentration.

scholarly journals Probabilistic Analysis of the Durability of Piles with Microcracks Under Chloride Attack

2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Wei Shao ◽  
Danda Shi
Keyword(s):  
Diffusion Coefficient ◽  
Probabilistic Analysis ◽  
Probabilistic Method ◽  
Crack Density ◽  
Chloride Concentration ◽  
Experimental Results ◽  
Chloride Diffusion ◽  
Chloride Ingress ◽  
Chloride Attack ◽  
Equivalent Diffusion

AbstractA probabilistic analysis approach for estimating the durability of piles with microcracks under chloride attack is presented. The chloride ingress model is obtained by considering the time-dependent diffusion process. The equivalent diffusion coefficient is derived to investigate the crack effect by introducing the crack effect factor. The fitting formula between the chloride diffusion coefficients and crack widths is established through experimental results, and the proposed equivalent diffusion coefficient is verified by comparison with the experimental results. The probabilistic evaluation of durability of piles with microcracks is performed, and then the parametric analysis is performed to study the effect of main parameters on the failure probability and durability life. The results indicate that the chloride concentration increases rapidly as the crack width increases at the same number of cracks. The durability life greatly reduces with increasing crack density of pile. The durability life predicted by probabilistic method is always less than those by deterministic method at the same condition. The deterministic approach may underestimate the threat of reinforcement corrosion induced by chloride attack, owing to the omission of probabilistic nature of main influencing parameters.

scholarly journals Experimental Study on Effective Chloride Diffusion Coefficient of Cement Mortar by Different Electrical Accelerated Measurements

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 240
Author(s):  
Jianlan Chen ◽  
Jiandong Wang ◽  
Rui He ◽  
Huaizhu Shu ◽  
Chuanqing Fu
Keyword(s):  
Diffusion Coefficient ◽  
Cement Mortar ◽  
Early Stage ◽  
Chloride Concentration ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Good Consistency ◽  
Determination Methods

This study investigated the effective chloride diffusion coefficient of cement mortar with different water-to-cement ratio (w/c) under electrical accelerated migration measurement. The cumulative chloride concentration in anode cell solution and the cumulative chloride concentration drop in the cathode cell solution was measured by RCT measurement and the results were further used to calculate the chloride diffusion coefficient by Nordtest Build 355 method and Truc method. The influence of w/c on cement mortar’s chloride coefficient was investigated and the chloride diffusion coefficient under different determination methods were compared with other researchers’ work, a good consistency between this work’s results and literatures’ results was obtained. The results indicated that the increased w/c of cement mortar samples will have a higher chloride diffusion coefficient. The cumulative chloride concentration drop in the cathode cell solution will have deviation in early stage measurement (before 60 h) which will result in overestimation of the effective chloride diffusion coefficient.

scholarly journals Numerical Simulation of Non-Uniformly Distributed Corrosion in Reinforced Concrete Cross-Section

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3975
Author(s):  
Magdalena German ◽  
Jerzy Pamin
Keyword(s):  
Reinforced Concrete ◽  
Cross Section ◽  
Chloride Transport ◽  
Chloride Concentration ◽  
Corrosion Current ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Initiation Phase ◽  
Chloride Corrosion ◽  
Cover Thickness

Reinforced concrete structures can be strongly damaged by chloride corrosion of reinforcement. Rust accumulated around rebars involves a volumetric expansion, causing cracking of the surrounding concrete. To simulate the corrosion progress, the initiation phase of the corrosion process is first examined, taking into account the phenomena of oxygen and chloride transport as well as the corrosion current flow. This makes it possible to estimate the mass of produced rust, whereby a corrosion level is defined. A combination of three numerical methods is used to solve the coupled problem. The example object of the research is a beam cross-section with four reinforcement bars. The proposed methodology allows one to predict evolving chloride concentration and time to reinforcement depassivation, depending on the reinforcement position and on the location of a point on the bar surface. Moreover, the dependence of the corrosion initiation time on the chloride diffusion coefficient, chloride threshold, and reinforcement cover thickness is examined.

scholarly journals Characterization of percolation behavior in conductor–dielectric 0-3 composites

2014 ◽  
Vol 04 (04) ◽  
pp. 1450035 ◽  
Author(s):  
Lin Zhang ◽  
Patrick Bass ◽  
Zhi-Min Dang ◽  
Z.-Y. Cheng
Keyword(s):  
Dielectric Constant ◽  
Percolation Threshold ◽  
Frequency Dependence ◽  
Experimental Results ◽  
Effective Dielectric Constant ◽  
Filler Concentration ◽  
Percolation Behavior ◽  
The Matrix ◽  
The Relationship

The equation ε eff ∝ (ϕc - ϕ)-s which shows the relationship between effective dielectric constant (εeff) and the filler concentration (φ), is widely used to determine the percolation behavior and obtain parameters, such as percolation threshold φc and the power constant s in conductor–dielectric composites (CDCs). Six different systems of CDCs were used to check the expression by fitting experimental results. It is found that the equation can fit the experimental results at any frequency. However, it is found that the fitting constants do not reflect the real percolation behavior of the composites. It is found that the dielectric constant is strongly dependent on the frequency, which is mainly due to the fact that the frequency dependence of the dielectric constant for the composites close to φc is almost independent of the matrix.

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