A Review of the Relationship Between the Characteristics of Spilled Oil and Dispersant Effectiveness

Author(s):  
GP Canevari
Author(s):  
Robert Grosser ◽  
Robyn Conmy ◽  
Devi Sundaravadivelu ◽  
Andrea Burkes ◽  
Edith Holder ◽  
...  

Surface washing agents (SWAs) can be used to enhance removal of spilled oil from shoreline surfaces and structures. There are two classes of SWA products, “lift and float” products which remove the oil from the surfaces to create an oil slick which can be recovered mechanically and “lift and disperse” products which emulsify and disperse the oil into the water column, which are more difficult to remove mechanically. Therefore, information regarding the ability of a product to lift oil from a surface and its mechanism of action once the oil has been removed is important for oil spill responders. The SWA effectiveness (SWAE) of 15 products (conducted and reported blind) listed on the NCP Product Schedule was evaluated by applying oil to a sand substrate, allowing time for the oil to adhere to the substrate, treating with SWA, and washing with artificial seawater to release any oil that has been lifted from the substrate surface. The efficiency of SWAs is calculated based on the mass of oil remaining on the substrate relative to the total mass of oil applied. The Dispersant Effectiveness (DE) of SWA products was determined using the Baffled Flask Test and was used to sort products based on their mechanism of action (“lift and disperse” rather than “lift and float”). Using a sand basket approach, the amount of oil remaining in sand varied from 10 to 95% for the various products tested, where a lower percent signifies a better SWA. The DE varied between 8 and 81%. Though previous studies have concluded that good SWAs are poor dispersants and vice versa, the results from this study demonstrate that this is not a general rule. A stoplight decision framework was developed that considers the relationship between DE and SWAE, and serves to identify products whose primary mechanism is “lift and disperse” rather than “lift and float.” Results suggest that regardless of which test is used to evaluate SWAs, coupling findings with DE can provide useful information for decisions during response operations.


2020 ◽  
Vol 8 (5) ◽  
pp. 362
Author(s):  
Yunseon Choe ◽  
Hyeonuk Kim ◽  
Cheol Huh ◽  
Choong-Ki Kim ◽  
Meang-Ik Cho ◽  
...  

Recovery modeling and countermeasures for oil spilled at sea have been extensively researched, but research remains insufficient on recovery potential estimation methods. It is required to access the mechanical recovery potential by considering the relationship between oil behavior, environmental conditions, and the performance of clean-up activities. Two response-planning models were developed in this study. One is a spatially uniform recovery model for estimating recovery potential that reflects weathering, oil properties, and equipment efficiency. The other is a spatially nonuniform recovery model that considers not only the above characteristics but also local thickness reduction by skimming. A comparison between the two models and an analysis of their effects on response was carried out through the calculation using an accident scenario. It is possible to analyze the effect of the thin slicks, natural dissipation, and the quantification of deployable skimming systems with the spatially nonuniform recovery model. Finally, we analyzed interrelationships among residual oil volume on the sea, response time, and the number of skimming systems.


2021 ◽  
Author(s):  
xin LIU ◽  
chunchang zhang ◽  
ruiying geng ◽  
xin lv

Abstract Between 1973–2017, evidences of red-tide outbreaks and oil spill accidents in the Chinese coastal waters were collected. Statistical analysis and multiple regression models were used to determine the relationship between the red tide and the oil spill. Major findings reveal that, (1) the frequency of red tides positively correlates to the number of oil spills and the volume of oil spilled as well; (2) The higher percentage of small spills (< 7 tonnes) are more likely to enhance the outbreaks of red tides; (3) More severe oil spill with penalty recorded implies a higher possibility to trigger the red tide afterwards. Therefore, oil spill contingency management aiming at preventing oil spills and mitigating spill effect could be of benefit to decrease the frequency of red tides as well. For example, it is suggested to carry out physical combat instead of chemical dispersants to remove the spilled oil in the shallow coastal areas for reducing the outbreak risk of red tides after the oil spill. The findings from this study shed light on the preventative management of red tides occurrence in the Chinese coastal waters and the similar coastal region elsewhere.


1993 ◽  
Vol 1993 (1) ◽  
pp. 567-574 ◽  
Author(s):  
M. F. Fingas ◽  
D. A. Kyle ◽  
J. B. Holmes ◽  
E. J. Tennyson

ABSTRACT A study of the relationship of dispersant effectiveness and mixing energy was performed. Energy was varied by changing the rotational speed of a specially designed apparatus. The effects of dispersant type and oil type were also measured. The stability of the resulting emulsions was gauged by measuring the amount of oil that remained in the water column over time. The findings are that each oil-dispersant combination shows a unique threshold or onset of dispersion. The effectiveness goes up linearly with energy, expressed as flask rotational speed. Natural dispersion was also measured and shows behavior similar to that of chemical dispersion, except that the thresholds occur at a higher energy and effectiveness rises more slowly with increasing energy. Effectiveness (defined as the percentage of oil in the water column) rises rapidly to 80 to 90 percent with increasing energy for light oils treated with chemical dispersants. Heavier oils will disperse, but to lesser effectiveness values.


1983 ◽  
Vol 1983 (1) ◽  
pp. 95-103
Author(s):  
Atsuo Yazaki

ABSTRACT This paper presents a summary of research and development projects at the Institute of Ocean Environmental Technology. First, projects in the field of oil boom and skimmer development are described. Oil containment performance for each of four new oil booms, and the oil recovery rate for each of seven new oil recovery devices and a new oil recovery ship are explained. Next, as typical examples of research projects concerning ocean and marine environmental problems, summaries of the following themes are presented: (a) oil spreading on the water surface, (b) the mechanism of oil leakage from a flat plate barrier, (c) oil slick behavior around a moving catamaran skimmer, (d) a law of similarity for the performance of oil recovery equipment, (e) evaporation of gasoline under various conditions, (f) the relationship of spilled oil and dissolved oxygen in sea water, (g) the effectiveness of chemical dispersants for spilled gasoline, (h) the generation of transient waves in a circulating water channel, and (i) experiments with a wave energy absorber.


1967 ◽  
Vol 31 ◽  
pp. 239-251 ◽  
Author(s):  
F. J. Kerr

A review is given of information on the galactic-centre region obtained from recent observations of the 21-cm line from neutral hydrogen, the 18-cm group of OH lines, a hydrogen recombination line at 6 cm wavelength, and the continuum emission from ionized hydrogen.Both inward and outward motions are important in this region, in addition to rotation. Several types of observation indicate the presence of material in features inclined to the galactic plane. The relationship between the H and OH concentrations is not yet clear, but a rough picture of the central region can be proposed.


Paleobiology ◽  
1980 ◽  
Vol 6 (02) ◽  
pp. 146-160 ◽  
Author(s):  
William A. Oliver

The Mesozoic-Cenozoic coral Order Scleractinia has been suggested to have originated or evolved (1) by direct descent from the Paleozoic Order Rugosa or (2) by the development of a skeleton in members of one of the anemone groups that probably have existed throughout Phanerozoic time. In spite of much work on the subject, advocates of the direct descent hypothesis have failed to find convincing evidence of this relationship. Critical points are:(1) Rugosan septal insertion is serial; Scleractinian insertion is cyclic; no intermediate stages have been demonstrated. Apparent intermediates are Scleractinia having bilateral cyclic insertion or teratological Rugosa.(2) There is convincing evidence that the skeletons of many Rugosa were calcitic and none are known to be or to have been aragonitic. In contrast, the skeletons of all living Scleractinia are aragonitic and there is evidence that fossil Scleractinia were aragonitic also. The mineralogic difference is almost certainly due to intrinsic biologic factors.(3) No early Triassic corals of either group are known. This fact is not compelling (by itself) but is important in connection with points 1 and 2, because, given direct descent, both changes took place during this only stage in the history of the two groups in which there are no known corals.


2020 ◽  
Vol 43 ◽  
Author(s):  
Thomas Parr

Abstract This commentary focuses upon the relationship between two themes in the target article: the ways in which a Markov blanket may be defined and the role of precision and salience in mediating the interactions between what is internal and external to a system. These each rest upon the different perspectives we might take while “choosing” a Markov blanket.


2019 ◽  
Vol 42 ◽  
Author(s):  
Paul Benjamin Badcock ◽  
Axel Constant ◽  
Maxwell James Désormeau Ramstead

Abstract Cognitive Gadgets offers a new, convincing perspective on the origins of our distinctive cognitive faculties, coupled with a clear, innovative research program. Although we broadly endorse Heyes’ ideas, we raise some concerns about her characterisation of evolutionary psychology and the relationship between biology and culture, before discussing the potential fruits of examining cognitive gadgets through the lens of active inference.


Author(s):  
Robert M. Glaeser

It is well known that a large flux of electrons must pass through a specimen in order to obtain a high resolution image while a smaller particle flux is satisfactory for a low resolution image. The minimum particle flux that is required depends upon the contrast in the image and the signal-to-noise (S/N) ratio at which the data are considered acceptable. For a given S/N associated with statistical fluxtuations, the relationship between contrast and “counting statistics” is s131_eqn1, where C = contrast; r2 is the area of a picture element corresponding to the resolution, r; N is the number of electrons incident per unit area of the specimen; f is the fraction of electrons that contribute to formation of the image, relative to the total number of electrons incident upon the object.


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