The Use of Thermal Mechanical Analysis to Characterize Ethylene-Propylene-Diene Terpolymer (EPDM) Roofing Membrane Materials

2009 ◽  
pp. 168-168-8 ◽  
Author(s):  
GD Gaddy ◽  
WJ Rossiter ◽  
RK Eby
Keyword(s):  
Mechanical Analysis ◽  
Ethylene Propylene ◽  
Membrane Materials ◽  
Thermal Mechanical Analysis ◽  
Ethylene Propylene Diene Terpolymer

scholarly journals The effect of polyhedral oligomeric silsesquioxanes (POSSs) incorporation in ethylene-propylene-diene-terpolymer (EPDM): a thermal study

2021 ◽  
Author(s):  
Ignazio Blanco ◽  
Traian Zaharescu
Keyword(s):  
Room Temperature ◽  
Thermal Characterization ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Dsc Analysis ◽  
Γ Irradiation ◽  
Scanning Calorimetry ◽  
Ethylene Propylene ◽  
Oligomeric Silsesquioxane ◽  
Ethylene Propylene Diene Terpolymer ◽  
Dynamic Heating

AbstractA series of ethylene-propylene-diene-terpolymer (EPDM)/polyhedral oligomeric silsesquioxane (POSS) composites at different percentage of POSS were prepared and subjected to γ-irradiation. Both irradiated and non-irradiated EPDM and composites were investigated by the means of thermal analysis to verify if the presence of POSS molecules is able to reduce the oxidation level of free radicals generated during the degradation and to evaluate the effects of the irradiation. EPDM composites at 1, 3 and 5 mass% of POSS were thus degraded in a thermogravimetric (TG) balance in dynamic heating conditions (25–700 °C), in both inert and oxidative atmosphere by flowing nitrogen and air respectively. Thermal characterization was then completed by carrying out Differential Scanning Calorimetry (DSC) analysis from sub-ambient to better highlight the melting of the polymer and polymer composites occurring just above the room temperature. FTIR spectroscopy was also performed for the prepared samples to check the presence of the molecular filler in the composites and for the TG’s residue at 700 °C, in order to evaluate its nature. DSC and TGA parameters were detected and discussed to have information about the effect of the degradation’s environment, the effect of irradiation on polymer stabilization and the effect of POSS content in the polymer matrix.

scholarly journals Numerical aspects for efficient welding computational mechanics

2014 ◽  
Vol 18 (suppl.1) ◽  
pp. 139-148
Author(s):  
Tarek Aburuga ◽  
Aleksandar Sedmak ◽  
Zoran Radakovic
Keyword(s):  
Residual Stresses ◽  
Three Dimensional ◽  
Shell Element ◽  
Element Model ◽  
Mechanical Analysis ◽  
Tensile Test Specimen ◽  
Integrity Assessment ◽  
Mass Scaling ◽  
Three Dimensional Models ◽  
Thermal Mechanical Analysis

The effect of the residual stresses and strains is one of the most important parameter in the structure integrity assessment. A finite element model is constructed in order to simulate the multi passes mismatched submerged arc welding SAW which used in the welded tensile test specimen. Sequentially coupled thermal mechanical analysis is done by using ABAQUS software for calculating the residual stresses and distortion due to welding. In this work, three main issues were studied in order to reduce the time consuming during welding simulation which is the major problem in the computational welding mechanics (CWM). The first issue is dimensionality of the problem. Both two- and three-dimensional models are constructed for the same analysis type, shell element for two dimension simulation shows good performance comparing with brick element. The conventional method to calculate residual stress is by using implicit scheme that because of the welding and cooling time is relatively high. In this work, the author shows that it could use the explicit scheme with the mass scaling technique, and time consuming during the analysis will be reduced very efficiently. By using this new technique, it will be possible to simulate relatively large three dimensional structures.

FOAMING AND MOISTURE CROSSLINKING OF VINYL TRIETHOXY SILANE GRAFTED ETHYLENE–PROPYLENE–DIENE TERPOLYMER

2022 ◽  
Author(s):  
Zhengwei Lin ◽  
Qinghong Zhang ◽  
Gongliang Wang ◽  
Jie Mao ◽  
Martin Hoch ◽  
...  
Keyword(s):  
High Efficiency ◽  
Low Cost ◽  
Side Reaction ◽  
High Energy ◽  
Expansion Ratio ◽  
Ethylene Propylene ◽  
Foaming Process ◽  
The Matrix ◽  
High Energy Absorption ◽  
Ethylene Propylene Diene Terpolymer

ABSTRACT Moisture crosslinking of polyolefins has attracted increasing attention because of its high efficiency, low cost, and easy processing. However, the crucial shortcoming of moisture crosslinking is that the side reaction of peroxide scorch (precrosslinking) simultaneously occurs in silane grafting. It has been recognized that making peroxide precrosslinking useful is an effective way to broaden the application of moisture crosslinking. A novel foaming process combined with moisture crosslinking is proposed. The matrix of ethylene–propylene–diene terpolymer grafted with silane vinyl triethoxysilane (EPDM-g-VTES) was prepared by melt grafting, with dicumyl peroxide as initiator. Foaming was then carried out with azodicarbonamide (AC) as the blowing agent by making use of precrosslinking. Subsequently, the EPDM-g-VTES foams were immersed in a water bath to achieve moisture crosslinking with dibutyl tin dilaurate as the catalyst. The results showed that VTES was grafted onto EPDM and the EPDM-g-VTES foams were successfully crosslinked by moisture. The EPDM-g-VTES compounds with AC obtained great cells by compression molding with the help of precrosslinking. The mechanical property of the EPDM-g-VTES foam was improved by moisture crosslinking. The moisture-cured foam with 4 wt% AC had an expansion ratio of about three times, which could bear large deformation and showed a high energy-absorption effect.

Suppressing Cracking in Resistance Welding AA5754 by Mechanical Means

2000 ◽  
Author(s):  
Hongyan Zhang ◽  
Jacek Senkara ◽  
Xin Wu
Keyword(s):  
Temperature Field ◽  
Crack Initiation ◽  
Spot Welding ◽  
Mechanical Analysis ◽  
Crack Initiation And Propagation ◽  
State Of Stress ◽  
Initiation And Propagation ◽  
Thermal Mechanical Analysis ◽  
The Impact ◽  
Analytical Approaches

Abstract In this paper mechanical aspects of cracking during single- and multi-spot welding of AA5754 was investigated by both experimental and analytical approaches. The impact of mechanical loading on crack initiation and propagation was studied with the consideration of various process parameters including the loading imposed by electrodes, the formation of liquid nugget, and constraining factors during and after welding. Tensile properties of AA5754 and their dependence on the temperature were tested at room and up to solidus temperatures, in order to provide a reference of cracking stress. Thermal-mechanical analysis was conducted based on the temperature field around the nugget and the state of stress encountered during welding. This analysis revealed that tensile stress might build up in the vicinity of the nugget during cooling, thus explained the experimental observation. General guidelines for suppressing cracking were proposed, i.e. to provide sufficient constraint around the weld spot during and after welding.

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