Practice for Sampling and Determination of Hydrogen Cyanide (HCN) in Combustion Effluents and Other Stationary Sources

2006 ◽  
Author(s):  
The Analyst ◽  
1999 ◽  
Vol 124 (4) ◽  
pp. 615-620 ◽  
Author(s):  
D. Sicilia ◽  
S. Rubio ◽  
D. Pérez-Bendito ◽  
N. Maniasso ◽  
E. A. G. Zagatto

1985 ◽  
Vol 57 (6) ◽  
pp. 1168-1168
Author(s):  
T W. Dolzine ◽  
G G. Esposito ◽  
D S. Rinehart

2010 ◽  
Vol 10 (2) ◽  
pp. 167-171 ◽  
Author(s):  
Hermin Sulistyarti ◽  
Spas D. Kolev ◽  
Stephanie Lim

The importance of developing method for thiocyanate becomes obvious, because thiocyanate can inhibit iodine uptake of thyroid gland leading to mumps disease. In this work, thiocyanate is oxidized by permanganate in the acid donor stream to cyanide, which is directly converted to hydrogen cyanide. Then, hydrogen cyanide diffuses through a Teflon membrane into acceptor stream containing nickel(II) in ammoniacal buffer to form tetracyanonickelate(II) which is detected spectrophotometrically at 267 nm. Analytical figures of merit were linear up to 50 mg L-1 for thiocyanate, with RSD of 1.34%, and detection limit of 0.07 mg L-1, respectively. Interfering anions were eliminated under stoichiometric amount of permanganate and sample throughput was 20 h-1. The method was validated for determining thiocyanate samples from synthetic and gold process waters with satisfactory results.   Keywords: Thiocyanate, flow injection, permanganate, spectrophotometry


1952 ◽  
Vol 39 (2) ◽  
pp. 287-291 ◽  
Author(s):  
G.E. Boxer ◽  
J.C. Rickards
Keyword(s):  

2018 ◽  
Vol 30 (4-5) ◽  
pp. 195-202 ◽  
Author(s):  
Jillian M. Staugler ◽  
Michael C. Babin ◽  
M. Claire Matthews ◽  
Matthew K. Brittain ◽  
Mark R. Perry

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