scholarly journals Biosorption of Metallic Elements onto Fen Peat

2014 ◽  
Vol 14 (1) ◽  
pp. 12-17
Author(s):  
Janis Krumins ◽  
Artis Robalds

Abstract Industrial development and anthropogenic activity have a huge impact on the environment, forcing society to find new and cost-effective environment treatment technologies. One of the most effective and environmentally friendly methods is the use of biosorbents, for which peat is one of the most cost-effective materials. The adsorption capabilities of peat sediments are well known; however, mainly raised bog peat is used for environmental treatment, and thus the abilities of fen peat are underestimated. The aim of this research was to assess the fen peat suitability as an adsorbent for metallic elements. In this study we have determined the sorption characteristics of Ca, Mg, K, Na, Cu and Pb and results show that fen peat deposits have a huge variability as a biosorbent due to their variable botanical composition and complex properties, for instance, under equal conditions, wood-sedge peat can have higher lead adsorption capacity than wood peat. However, due to its natural content of metallic elements, the sorption capacity overall is lower than it is for raised bog peat, although the high pH reaction encourage a high mobility metals.

2018 ◽  
Vol 69 (1) ◽  
pp. 14-20 ◽  
Author(s):  
Cristina Dinu ◽  
Eleonora Mihaela Ungureanu ◽  
Gabriela Geanina Vasile ◽  
Lidia Kim ◽  
Ioana Ionescu ◽  
...  

The soils situated near the abandoned mines are highly polluted with metals due to the discharge and dispersion of mine waste into nearby air, water (surface and groundwater) and soil. Heavy metals may be transferred to humans through ingestion, inhalation or dermal absorption and can produce serious health problems affect the nervous, endocrine and immune systems, hematopoietic function and cellular metabolism. This paper investigates the presence of metallic elements from fourteen soil samples (seven sampling points) and thirty-six vegetation samples (different types of leaves, plants, roots and tree barks). The samples were collected from six different sites located in an abandoned mining area and from a point (blank sample) located 5 km in the SV direction of the quarry. The results obtained for soil samples show an overrun of the alert and / or intervention threshold for the following metals: arsenic, cadmium, cobalt, copper, manganese, nickel, lead and zinc. The analytical investigation for vegetation samples indicated that concentration for calcium, magnesium, cadmium, chromium, manganese, nickel, lead, zinc were situated over the normal range in some samples. The analytical investigations were performed by optical emission spectrometry (ICP-OES). The study�s conclusion indicates that, as result of soil acidic pH and high mobility of some metals, metallic elements migrate from soil to vegetation.


2015 ◽  
Vol 2015 (1) ◽  
pp. 1-16
Author(s):  
J Fitzpatrick ◽  
S Eisner ◽  
S Goris ◽  
J Hutchins ◽  
C O’Bryan ◽  
...  

2020 ◽  
Vol 10 (19) ◽  
pp. 6656
Author(s):  
Stefano Lai ◽  
Giulia Casula ◽  
Pier Carlo Ricci ◽  
Piero Cosseddu ◽  
Annalisa Bonfiglio

The development of electronic devices with enhanced properties of transparency and conformability is of high interest for the development of novel applications in the field of bioelectronics and biomedical sensing. Here, a fabrication process for all organic Organic Field-Effect Transistors (OFETs) by means of large-area, cost-effective techniques such as inkjet printing and chemical vapor deposition is reported. The fabricated device can operate at low voltages (as high as 4 V) with ideal electronic characteristics, including low threshold voltage, relatively high mobility and low subthreshold voltages. The employment of organic materials such as Parylene C, PEDOT:PSS and 6,13-Bis(triisopropylsilylethynyl)pentacene (TIPS pentacene) helps to obtain highly transparent transistors, with a relative transmittance exceeding 80%. Interestingly enough, the proposed process can be reliably employed for OFET fabrication over different kind of substrates, ranging from transparent, flexible but relatively thick polyethylene terephthalate (PET) substrates to transparent, 700-nm-thick, compliant Parylene C films. OFETs fabricated on such sub-micrometrical substrates maintain their functionality after being transferred onto complex surfaces, such as human skin and wearable items. To this aim, the electrical and electromechanical stability of proposed devices will be discussed.


2015 ◽  
Vol 12 (2) ◽  
pp. 189 ◽  
Author(s):  
Jun Wang ◽  
Huijie Li ◽  
Yong Chen ◽  
Yuan Fang ◽  
Zongping Wang ◽  
...  

Environmental context Fulvic acids account for a large proportion of dissolved organic matter in aquatic environments and affect the transportation and bioavailability of organic and inorganic pollutants. The structural and spectroscopic characteristics of fulvic acids mainly depend on the sources, seasons and anthropogenic activity. We present an advanced approach using fluorescence spectroscopy as a rapid and cost-effective method to investigate the composition, properties and origins of fulvic acids. Abstract Fulvic acids (FAs) isolated seasonally from the sediments of East Lake and Liangzi Lake in central China were comparatively investigated. The structural features of the FAs were characterised using chemical and spectroscopic methods, including elemental analysis, UV-Vis spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy, and three-dimensional excitation emission matrix (EEM) fluorescence spectroscopy coupled with parallel factor analysis (PARAFAC). The O/C, (O+N)/C and C/N ratios of FA extracted from Liangzi Lake (FAL) were higher than those of FA extracted from East Lake (FAE), indicating higher oxygen-containing functionality and polarity and less nutrient in FAL compared with FAE. The two FAs had similar UV-Vis spectra with different absorbance intensities. The FT-IR spectra showed that the two FAs had similar functional groups. The total fluorescence intensity and aromaticity of samples from Liangzi Lake were higher than those of East Lake except for those taken in the summer. The two FAs were largely terrestrially derived organic materials. Five fluorescent components, including four humic-like and two fulvic-like components, were identified by PARAFAC modelling of the EEM spectral data. The fluorescence was dominated by two components. The findings suggest that EEM fluorescence spectroscopy together with PARAFAC is a rapid and cost-effective method for understanding the characteristics and origins of FAs in natural water systems.


2021 ◽  
Vol 3 ◽  
Author(s):  
Subhrangshu Mandal ◽  
Kunal Kumar Saha ◽  
Narayan Chandra Mandal

Over the past few decades, the massive increase in anthropogenic activity and industrialization processes has increased new pollutants in the environment. The effects of such toxic components (heavy metals, pesticides, etc.) in our ecosystem vary significantly and are of significant public health and economic concern. Because of this, environmental consciousness is increasing amongst consumers and industrialists, and legal constraints on emissions are becoming progressively stricter; for the ultimate aim is to achieve cost-effective emission control. Fortunately, certain taxonomically and phylogenetically diverse microorganisms (e.g., sulfur oxidizing/reducing bacteria) are endowed with the capability to remediate such undesired components from diverse habitats and have diverse plant-growth-promoting abilities (auxin and siderophore production, phosphate solubilization, etc.). However, the quirk of fate for pollutant and plant-growth-promoting microbiome research is that, even with an early start, genetic knowledge on these systems is still considered to be in its infancy due to the unavailability of in-depth functional genomics and population dynamics data from various ecosystems. This knowledge gap can be breached if we have adequate information concerning their genetic make-up, so that we can use them in a targeted manner or with considerable operational flexibility in the agricultural sector. Amended understanding regarding the genetic basis of potential microbes involved in such processes has led to the establishment of novel or advanced bioremediation technologies (such as the detoxification efficiency of heavy metals), which will further our understanding of the genomic/genetic landscape in these potential organisms. Our review aimed to unravel the hidden genomic basis and eco-physiological properties of such potent bacteria and their interaction with plants from various ecosystems.


2009 ◽  
Vol 10 (04) ◽  
pp. 435-457
Author(s):  
ATHANASIOS KINALIS ◽  
SOTIRIS NIKOLETSEAS

Motivated by emerging applications, we consider sensor networks where the sensors themselves (not just the sinks) are mobile. Furthermore, we focus on mobility scenarios characterized by heterogeneous, highly changing mobility roles in the network. To capture these high dynamics of diverse sensory motion we propose a novel network parameter, the mobility level, which, although simple and local, quite accurately takes into account both the spatial and speed characteristics of motion. We then propose adaptive data dissemination protocols that use the mobility level estimation to optimize performance, by basically exploiting high mobility (redundant message ferrying) as a cost-effective replacement of flooding, e.g. the sensors tend to dynamically propagate less data in the presence of high mobility, while nodes of high mobility are favored for moving data around. These dissemination schemes are enhanced by a distance-sensitive probabilistic message flooding inhibition mechanism that further reduces communication cost, especially for fast nodes of high mobility level, and as distance to data destination decreases. Our simulation findings demonstrate significant performance gains of our protocols compared to non-adaptive protocols, i.e. adaptation increases the success rate and reduces latency (even by 15%) while at the same time significantly reducing energy dissipation (in most cases by even 40%). Also, our adaptive schemes achieve significantly higher message delivery ratio and satisfactory energy-latency trade-offs when compared to flooding when sensor nodes have limited message queues.


Author(s):  
Anil Kumar ◽  
Monika Chandrabhan Dhote

Environmental contamination due to petroleum compounds is a serious global issue. Oil /petroleum refineries produce huge amount of oil sludge during drilling, storage, transport, refining which spoil soil and ground water resources. Such activities release different compounds viz. alkane, mono- polyaromatic hydrocarbons (PAH), asphaltene, resins and heavy metals. Due to physico-chemical properties, PAHs are one of most targeted compounds as they are highly persistent, carcinogenic, and have mutagenic effects on ecosystem. Such problems of PAHs drag researcher's attention to find some reliable and cost effective solution for oil sludge disposal management. Since last few decades, extensive research work has been carried out on various methods for treatment of oil sludge. In recent years, microbial assisted phytoremediation treatment technologies are being studied since these are reliable and cost effective for field applications. Here, we have discussed about combined eco-friendly technology of plant and microbe(s) to treat oil sludge for its better management.


Author(s):  
Vidushi Abrol ◽  
Sharada Mallubhotla ◽  
Sundeep Jaglan

Rising cases of environmental mercury hazards has led to a need for cost-effective mercury treatment techniques. Extensive use of mercury from ancient times has resulted in water contamination that may require remediation. Mercury contamination is tedious to treat and may pose a risk to human health and the environment. To deal with this threat of mercury contamination, industrial wastes and wastewaters containing mercury requires treatment for its removal and immobilization. This chapter provides a synopsis of the availability, performance, and technologies for management of mercury in water. It covers the innovative methods to treat the mercury contamination like biosorption. In this chapter, the technological aspects available for the mercury treatment technologies are reviewed. It describes the theory, design, and operation of the technologies; provides information on commercial availability and use; and includes data on performance, where available.


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