Matrix impact on the mechanical, thermal and electrical properties of microfluidized nanofibrillated cellulose composites

2017 ◽  
Vol 37 (9) ◽  
pp. 921-931 ◽  
Author(s):  
Bayram Poyraz ◽  
Ayhan Tozluoğlu ◽  
Zeki Candan ◽  
Ahmet Demir
Keyword(s):  
Thermal Stability ◽  
Relaxation Process ◽  
Testing Machine ◽  
Nanofibrillated Cellulose ◽  
Industrial Applications ◽  
Silica Matrix ◽  
Nanocomposite Films ◽  
Morphological Alterations ◽  
Cellulose Composites ◽  
And Storage

Abstract This study reports on the effect of organic polyvinyl alcohol (PVA) and silica matrix on the properties of cellulose-based nanocomposites. Nanofibrillated cellulose was isolated from kraft pulp and treated with Pulpzyme HC 2500 enzyme prior to high-pressure homogenization in order to lower energy consumption. Three nanocomposite films were fabricated via the casting process: nanofibrillated cellulose, nanocellulose-PVA (NC-PVA) and nanocellulose-silica (NC-Si). Chemical characterization and crystallization were determined with FTIR. Thermal stability was investigated with thermogravimetric analysis. Morphological alterations were monitored with scanning electron microscopy. A universal testing machine and dynamic mechanical thermal analysis were used for determination of Young’s and storage moduli. The real and imaginary parts of permittivity and electric modulus were evaluated using an impedance analyzer. Considerable alterations were seen under FTIR. Thermal stability was lower in NC-Si than in NC-PVA due to lower crystallinity. Higher Young’s modulus and storage moduli were observed in NC-PVA than in NC-Si. NC-PVA exhibited a singular relaxation process, while a double relaxation process was seen in NC-Si. Consequently, the nanocomposite film prepared from the organic matrix (NC-PVA) had a mechanical advantage for industrial applications. However, neat NC composite revealed the highest storage modulus and thermal stability.

scholarly journals Co-exfoliation and fabrication of graphene based microfibrillated cellulose composites – mechanical and thermal stability and functional conductive properties

Nanoscale ◽  
2018 ◽  
Vol 10 (20) ◽  
pp. 9569-9582 ◽  
Author(s):  
Josphat Phiri ◽  
Leena-Sisko Johansson ◽  
Patrick Gane ◽  
Thad C. Maloney
Keyword(s):  
Thermal Stability ◽  
Composite Material ◽  
Functional Properties ◽  
Nanofibrillated Cellulose ◽  
Microfibrillated Cellulose ◽  
Cellulose Composites ◽  
Micro Nanofibrillated Cellulose ◽  
Conductive Properties

The excellent functional properties of graphene and micro-nanofibrillated cellulose (MNFC) offer plenty of possibilities for wide ranging applications in combination as a composite material.

scholarly journals Structural Nanocomposite Fabrication from Self-Assembled Choline Chloride Modified Kaolinite into Poly(Methylmethacrylate)

2019 ◽  
Vol 3 (3) ◽  
pp. 83 ◽  
Author(s):  
Dipti Saha ◽  
Mithun Kumar Majumdar ◽  
Ajoy Kumar Das ◽  
A.M. Sarwaruddin Chowdhury ◽  
Md. Ashaduzzaman
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Materials Science ◽  
Choline Chloride ◽  
Testing Machine ◽  
Attenuated Total Reflection ◽  
Nanocomposite Films ◽  
Pmma Film ◽  
Nanoscale Particles ◽  
Self Assembled

Composite materials produced from indigenous nanoscale particles and synthetic polymers have created demand in the field of nanoscience and technology. Layered silicates are potential candidates for reinforcing the properties of composites. Here, we report the fabrication of nanocomposites using poly(methylmethacrylate) (PMMA) as the matrix and the Bijoypur clay of Bangladesh known as kaolinite (200–250 nm) as the filler via solution casting. Kaolinite was first modified using choline chloride to prepare core-shell particles through a precipitation technique and was used for self-assembled nanocomposite films preparation. A series of nanocomposites films using 0, 1, 3, 5 and 10% (w/w) modified kaolinite was prepared. The neat PMMA and nanocomposite films were characterized by attenuated total reflection infra-red (ATR-IR) spectroscopy and X-ray diffraction (XRD) techniques. The mechanical properties, thermal stability, and morphology of the films were investigated using a universal testing machine (UTM), a thermal gravimetric analyzer (TGA), and a scanning electron microscope (SEM). The nanocomposite films exhibited better mechanical properties and thermal stability than neat PMMA film. Development of such structural nanocomposite materials using naturally occurring nanoscale particles would play a crucial role in the field of materials science for packaging applications and separation technology.

Effect of gamma radiation on the structural, thermal and optical properties of PMMA/Sn0.75Fe0.25S2 nanocomposite

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Ali A. Alhazime ◽  
Nesreen T. El-Shamy ◽  
Kaoutar Benthami ◽  
Mai ME. Barakat ◽  
Samir A. Nouh
Keyword(s):  
Thermal Stability ◽  
Optical Properties ◽  
Gamma Irradiation ◽  
Optical Band Gap ◽  
Color Variation ◽  
Nanocomposite Films ◽  
Color Changes ◽  
Gamma Irradiated ◽  
Intermolecular Crosslinking ◽  
Amorphous Part

AbstractNanocomposite films of polymethylmethacrylate PMMA with Sn0.75Fe0.25S2 nanoparticles (NPs) were fabricated by both thermolysis and casting techniques. Changes in PMMA/Sn0.75Fe0.25S2 nanocomposite (NCP) due to gamma irradiation have been measured. XRD results indicate that the gamma doses of 10–80 kGy cause intermolecular crosslinking that reduces the ordered portion in the NPs. Bonding between the NPs and the host PMMA was confirmed by FTIR. TGA results indicate an enhancement in thermal stability in the NCP films irradiated with doses 20–80 kGy. The optical band gap was reduced from 3.23 to 2.47 eV upon gamma irradiation up to 80 kGy due bonding between the NPs and PMMA which enhanced the amorphous part of the NPs. Finally, the color variation between the blank and irradiated films (ΔE) was determined. Color changes immensely when the PMMA/Sn0.75Fe0.25S2 NCP films are gamma irradiated. Values of ΔE were as much as 31.6 which is an acceptable match in commercial reproduction on printing presses.

scholarly journals Cellulose Nanofiber-Based Nanocomposite Films Reinforced with Zinc Oxide Nanorods and Grapefruit Seed Extract

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 877 ◽  
Author(s):  
Swarup Roy ◽  
Hyun Chan Kim ◽  
Pooja S. Panicker ◽  
Jong-Whan Rhim ◽  
Jaehwan Kim
Keyword(s):  
Thermal Stability ◽  
Zinc Oxide ◽  
Seed Extract ◽  
Cellulose Nanofiber ◽  
Nanocomposite Films ◽  
Zinc Oxide Nanorods ◽  
Precipitation Method ◽  
Active Food Packaging ◽  
Oxide Nanorods ◽  
Grapefruit Seed Extract

Here, we report the fabrication and characterization of cellulose nanofiber (CNF)-based nanocomposite films reinforced with zinc oxide nanorods (ZnOs) and grapefruit seed extract (GSE). The CNF is isolated via a combination of chemical and physical methods, and the ZnO is prepared using a simple precipitation method. The ZnO and GSE are used as functional nanofillers to produce a CNF/ZnO/GSE film. Physical (morphology, chemical interactions, optical, mechanical, thermal stability, etc.) and functional (antimicrobial and antioxidant activities) film properties are tested. The incorporation of ZnO and GSE does not impact the crystalline structure, mechanical properties, or thermal stability of the CNF film. Nanocomposite films are highly transparent with improved ultraviolet blocking and vapor barrier properties. Moreover, the films exhibit effective antimicrobial and antioxidant actions. CNF/ZnO/GSE nanocomposite films with better quality and superior functional properties have many possibilities for active food packaging use.

Microstructures and Properties of Ti-Nb Alloys Produced by Powder Metallurgy

2011 ◽  
Vol 80-81 ◽  
pp. 431-435 ◽  
Author(s):  
Zheng Cun Zhou ◽  
J. Du ◽  
H. Yang ◽  
S.Y. Gu ◽  
Y.J. Yan
Keyword(s):  
Powder Metallurgy ◽  
Testing Machine ◽  
Optical Microscope ◽  
Mechanical Analysis ◽  
Sintered Alloy ◽  
Xrd Diffraction ◽  
Β Phase ◽  
Ω Phase ◽  
Nb Content ◽  
And Storage

Ti-Nb alloys were prepared by powder metallurgy. Their microstructures are detected by the XRD diffraction and are observed using an optical microscope. The mechanical properties are tested using a dynamic mechanical analysis (DMA) Q800 from TA Instruments in single cantilever mode and using a 100 KN MTS testing machine with control software. It has been found that the sintered Ti-Nb alloys possess the stable α and β phases and the amount in β phase increases with increasing Nb content. The water quenched Ti-35.4Nb alloy contains α,,and βM. The as-sintered alloy has higher yield stress and storage modulus than the water quenched Ti-35.4Nb alloy, which is resulted from the α phase with high modulus in the as-sintered alloy. The ω phase can be precipitated from βMwhen the water quenched Ti-35.4Nb alloy is aged at 300 °C, causing the modulus to increase since ω phase has large modulus.

Electro-conductively deposited carbon fibers for power controllable heating elements

RSC Advances ◽  
2015 ◽  
Vol 5 (34) ◽  
pp. 26998-27002 ◽  
Author(s):  
Chang Hyo Kim ◽  
Moo Sung Kim ◽  
Yoong Ahm Kim ◽  
Kap Seung Yang ◽  
Seung Jo Baek ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Electrical Conductivity ◽  
Carbon Fibers ◽  
Industrial Applications ◽  
Excellent Thermal Stability

Carbon fibers are considered as one of the promising heating elements in various industrial applications because of their excellent thermal stability and electrical conductivity.

scholarly journals Immobilization of Mutant Phosphotriesterase on Fuller’s Earth Enhanced the Stability of the Enzyme

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 983
Author(s):  
Wahhida Latip ◽  
Victor Feizal Knight ◽  
Ong Keat Khim ◽  
Noor Azilah Mohd Kasim ◽  
Wan Md Zin Wan Yunus ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Ions ◽  
Half Life ◽  
Industrial Applications ◽  
Free Enzyme ◽  
High Tolerance ◽  
Tween 40 ◽  
Fuller’S Earth ◽  
The Stability ◽  
Biochemical Features

Immobilization is a method for making an enzyme more robust in the environment, especially in terms of its stability and reusability. A mutant phosphotriesterase (YT PTE) isolated from Pseudomonas dimunita has been reported to have high proficiency in hydrolyzing the Sp and Rp-enantiomers of organophosphate chromophoric analogs and therefore has great potential as a decontamination agent and biosensor. This work aims to investigate the feasibility of using Fuller’s earth (FE) as a YT PTE immobilization support and characterize its biochemical features after immobilization. The immobilized YT PTE was found to show improvement in thermal stability with a half-life of 24 h compared to that of the free enzyme, which was only 8 h. The stability of the immobilized YT PTE allowed storage for up to 4 months and reuse for up to 6 times. The immobilized YT PTE showed high tolerance against all tested metal ions, Tween 40 and 80 surfactants and inorganic solvents. These findings showed that the immobilized YT PTE became more robust for use especially with regards to its stability and reusability. These features would enhance the future applicability of this enzyme as a decontamination agent and its use in other suitable industrial applications.

scholarly journals Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties

Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3193
Author(s):  
Sylva Holešová ◽  
Karla Čech Čech Barabaszová ◽  
Marianna Hundáková ◽  
Michaela Ščuková ◽  
Kamila Hrabovská ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Surface Properties ◽  
Food Packaging ◽  
Synergistic Effects ◽  
Nanocomposite Films ◽  
Mechanical Resistance ◽  
X Ray Diffraction ◽  
Microbial Strains ◽  
And Storage ◽  
Structure Properties

Infection with pathogenic microorganisms is of great concern in many areas, especially in healthcare, but also in food packaging and storage, or in water purification systems. Antimicrobial polymer nanocomposites have gained great popularity in these areas. Therefore, this study focused on new approaches to develop thin antimicrobial films based on biodegradable polycaprolactone (PCL) with clay mineral natural vermiculite as a carrier for antimicrobial compounds, where the active organic antimicrobial component is antifungal ciclopirox olamine (CPX). For possible synergistic effects, a sample in combination with the inorganic antimicrobial active ingredient zinc oxide was also prepared. The structures of all the prepared samples were studied by X-ray diffraction, FTIR analysis and, predominantly, by SEM. The very different structure properties of the prepared nanofillers had a fundamental influence on the final structural arrangement of thin PCL nanocomposite films as well as on their mechanical, thermal, and surface properties. As sample PCL/ZnOVER_CPX possessed the best results for antimicrobial activity against examined microbial strains, the synergic effect of CPX and ZnO combination on antimicrobial activity was proved, but on the other hand, its mechanical resistance was the lowest.

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