Macro- and micromechanical characterization of wood-adhesive bonds exposed to alternating climate conditions

Holzforschung ◽  
2010 ◽  
Vol 64 (6) ◽  
Author(s):  
Jürgen Follrich ◽  
Frank Stöckel ◽  
Johannes Konnerth
Keyword(s):  
Bond Strength ◽  
Mechanical Performance ◽  
Urea Formaldehyde ◽  
Tensile Tests ◽  
Tangential Direction ◽  
Wood Adhesive ◽  
Bond Line ◽  
Adhesive Bonds ◽  
Climate Conditions ◽  
Micromechanical Characterization

Abstract Three-part specimens were produced from Norway spruce wood (Picea abies Karst.) and bonded with the following adhesives: melamine-urea-formaldehyde (MUF), phenol-resorcinol-formaldehyde (PRF), and a two-component emulsion polymer isocyanate (EPI). The effect of alternating climate conditions on bond strength was studied by tensile tests. The specimens were exposed to a three-step ageing cycle lasting for 7 days [50°C/95% relative humidity (RH), -20°C/65– 70% RH and 75°C/15% RH] which was repeated 24 times. In general, a decrease in internal bond strength of all exposed specimens was observed but it was highest in the case of MUF-bonded joints. Furthermore, a significant decrease of the tensile strength of the wood adherend perpendicular to the grain in the tangential direction was determined after the cyclic climatic changes. The mechanical performance of the different adhesives in the bond line was tested by means of nanoindentation. Reduced values of elastic modulus, hardness, and total indentation were observed after climatic treatment, particularly for the rigid MUF adhesive, whereas the flexible adhesive EPI did not show such changes.

scholarly journals Generic failure mechanisms in adhesive bonds

Holzforschung ◽  
2013 ◽  
Vol 67 (2) ◽  
pp. 207-215 ◽  
Author(s):  
Philipp Hass ◽  
Falk K. Wittel ◽  
Peter Niemz
Keyword(s):  
Crack Propagation ◽  
Urea Formaldehyde ◽  
Failure Mechanisms ◽  
Tensile Tests ◽  
Propagation Path ◽  
Adhesive Properties ◽  
Adhesive Bonds ◽  
Stable Crack Propagation ◽  
Order Of Magnitude

Abstract The failure of adhesive bondlines has been studied at the microscopic level via tensile tests. Stable crack propagation could be generated by means of samples with improved geometry, which made in situ observations possible. The interaction of cracks with adhesive bondlines under various angles to the crack propagation was the focus of this study, as well as the respective loading situations for the adhesives urea formaldehyde (UF), polyurethane (PUR), and polyvinyl acetate (PVAc), which have distinctly different mechanical behaviors. It has been shown how adhesive properties influence the occurrence of certain failure mechanisms and determine their appearance and order of magnitude. With the observed failure mechanisms, it becomes possible to predict the propagation path of a crack through the specimen.

Effect of plasma treatment on cell-wall adhesion of urea-formaldehyde resin revealed by nanoindentation

Holzforschung ◽  
2014 ◽  
Vol 68 (6) ◽  
pp. 707-712 ◽  
Author(s):  
Johannes Konnerth ◽  
Martin Weigl ◽  
Wolfgang Gindl-Altmutter ◽  
Georg Avramidis ◽  
Arndt Wolkenhauer ◽  
...  
Keyword(s):  
Cell Wall ◽  
Bond Strength ◽  
Mechanical Performance ◽  
Urea Formaldehyde ◽  
Primary Source ◽  
Formaldehyde Resin ◽  
Bond Performance ◽  
Spruce Wood ◽  
Wood Surfaces ◽  
Reference Samples

Abstract Spruce wood surfaces were treated with plasma with the aim of increacing either hydrophilicity or hydrophobicity. The treatments resulted in significant changes in wettability compared to aged and reference samples. Wettability was found to be a very good indicator of macroscopic bond strength. Nanoindentation adhesion measurements identified significant changes in adhesion at the immediate wood surface as a primary source of changes of bond performance, whereas mechanical performance of bulk wood cells was not affected.

Mechanical characterisation of wood-adhesive interphase cell walls by nanoindentation

Holzforschung ◽  
2006 ◽  
Vol 60 (4) ◽  
pp. 429-433 ◽  
Author(s):  
Johannes Konnerth ◽  
Wolfgang Gindl
Keyword(s):  
Elastic Modulus ◽  
Cell Walls ◽  
Urea Formaldehyde ◽  
Wood Adhesive ◽  
Interphase Cell ◽  
Adhesive Bonds ◽  
Resorcinol Formaldehyde ◽  
Interphase Region ◽  
Mechanical Characterisation ◽  
Penetration Behaviour

Abstract The elastic modulus, hardness, and creep factor of wood cell walls in the interphase region of four different adhesive bonds were determined by nanoindentation. In comparison with reference cell walls unaffected by adhesive, interphase cell walls from melamine-urea-formaldehyde (MUF) and phenol-resorcinol-formaldehyde (PRF) adhesive bonds showed improved hardness and reduced creep, as well as improved elastic modulus in the case of MUF. In contrast, cell walls from the interphase region in polyvinylacetate (PVAc) and one-component polyurethane (PUR) bonds showed more creep, but lower elastic modulus and hardness than the reference. Considering the different cell-wall penetration behaviour of the adhesive polymers studied here, it is concluded that damage and loss of elastic modulus to surface cells occurring during the machining of wood is recovered in MUF and PRF bond lines, whereas damage of cell walls persists in PVAc and PUR bond lines.

scholarly journals Measurement of moisture-related strain in bonded ash depending on adhesive type and glueline thickness

Holzforschung ◽  
2016 ◽  
Vol 70 (2) ◽  
pp. 145-155 ◽  
Author(s):  
Markus Knorz ◽  
Peter Niemz ◽  
Jan-Willem van de Kuilen
Keyword(s):  
High Strain ◽  
Urea Formaldehyde ◽  
Wood Adhesive ◽  
Image Correlation ◽  
Adhesive Bonds ◽  
Mechanical Loads ◽  
Resorcinol Formaldehyde ◽  
Emulsion Polymer ◽  
Distinct Strain ◽  
Adhesive Type

Abstract Structural wood-adhesive bonds (WAB) have to be durable while subjected to considerable stresses caused by mechanical loads and moisture content changes. To better understand the moisture-related durability of WABs, knowledge is important of how moisture changes generate strain in the bond. In this paper, strain on end-grain surfaces of bonded ash specimens was analyzed by means of digital image correlation. Strains were generated by wood shrinkage, and the evaluation was focused on shear strain (SStr). The bond lines were studied depending on the adhesive type – phenol resorcinol formaldehyde (PRF), melamine urea formaldehyde (MUF), polyurethane (PUR), and emulsion polymer isocyanates (EPI). Moreover, three different glueline (GL) thicknesses of MUF were taken into consideration. Comparing the adhesive types, SStr distributions (SStrD) were strongly influenced by adhesive elasticity. MUF and PRF bonds were quite rigid and were associated with pronounced strain amplitudes in and close to the GL together with strain dissipation reaching deep in the wood. PUR and EPI adhesives were more elastic and therefore allowed for smoother strain transition showing less distinct strain peaks. GL thickness had significant impact on SStrD. A high strain level and direct strain transition between adherends was found for the 0.01 mm GL, whereas a pronounced strain decrease was observed in the 0.1 and 0.2 mm GLs. This indicates different stress levels in the wood-adhesive interface dependent on GL thickness.

scholarly journals A Study on the Bond Strength of Plastic–Metal Direct Bonds Using Friction Press Joining

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 660
Author(s):  
Stefan P. Meyer ◽  
Maren T. Herold ◽  
Jan B. Habedank ◽  
Michael F. Zaeh
Keyword(s):  
Bond Strength ◽  
Tensile Tests ◽  
Friction Press ◽  
Adhesive Bonds ◽  
Technical Potential ◽  
Plastic Metal ◽  
Metal Sheets ◽  
Plastic Components ◽  
Joining Process

Friction press joining (FPJ) is an innovative joining process for bonding plastic components and metal sheets without additives in an overlap configuration. This paper focuses on the resulting bond strength. Tensile tests showed that the direct bonds produced by FPJ have either an equivalent or a higher bond strength compared to adhesive bonds. For the material combination of HD-PE and EN AW-6082-T6, an equivalent bond strength was achieved. In contrast, for the material combinations PA6-GF30 with EN AW-6082-T6 and PPS-CF with EN AW-2024-T3, higher tensile shear strengths were achieved via the FPJ technology. In addition to the technical considerations, this paper presents an evaluation of the technological maturity of FPJ. It was found that the basics of the technology are already well developed, and prototypes for showing the applicability have already been manufactured. The last part of this paper deals with the classification of FPJ into the standard for manufacturing processes, according to DIN 8593. The authors suggest a categorization into Activation bonding (item 4.8.1.3). These investigations show the high technical potential of FPJ for joining plastic components with metals.

scholarly journals Wastes from Agricultural Silage Film Recycling Line as a Potential Polymer Materials

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1383
Author(s):  
Jerzy Korol ◽  
Aleksander Hejna ◽  
Klaudiusz Wypiór ◽  
Krzysztof Mijalski ◽  
Ewelina Chmielnicka
Keyword(s):  
Vinyl Acetate ◽  
Thermal Performance ◽  
Mechanical Performance ◽  
Ethylene Vinyl Acetate ◽  
Tensile Tests ◽  
Solid Particles ◽  
Polymer Materials ◽  
Slight Reduction ◽  
Scanning Calorimetry ◽  
Crystallinity Degree

The recycling of plastics is currently one of the most significant industrial challenges. Due to the enormous amounts of plastic wastes generated by various industry branches, it is essential to look for potential methods for their utilization. In the presented work, we investigated the recycling potential of wastes originated from the agricultural films recycling line. Their structure and properties were analyzed, and they were modified with 2.5 wt % of commercially available compatibilizers. The mechanical and thermal performance of modified wastes were evaluated by tensile tests, thermogravimetric analysis, and differential scanning calorimetry. It was found that incorporation of such a small amount of modifiers may overcome the drawbacks caused by the presence of impurities. The incorporation of maleic anhydride-grafted compounds enhanced the tensile strength of wastes by 13–25%. The use of more ductile compatibilizers—ethylene-vinyl acetate and paraffin increased the elongation at break by 55–64%. The presence of compatibilizers also reduced the stiffness of materials resulting from the presence of solid particles. It was particularly emphasized for styrene-ethylene-butadiene-styrene and ethylene-vinyl acetate copolymers, which caused up to a 20% drop of Young’s modulus. Such effects may facilitate the further applications of analyzed wastes, e.g., in polymer film production. Thermal performance was only slightly affected by compatibilization. It caused a slight reduction in polyethylene melting temperatures (up to 2.8 °C) and crystallinity degree (up to 16%). For more contaminated materials, the addition of compatibilizers caused a minor reduction in the decomposition onset (up to 6 °C). At the same time, for the waste after three washing cycles, thermal stability was improved. Moreover, depending on the desired properties and application, materials do not have to go through the whole recycling line, simplifying the process, reducing energy and water consumption. The presented results indicate that it is possible to efficiently use the materials, which do not have to undergo the whole recycling process. Despite the presence of impurities, they could be applied in the manufacturing of products which do not require exceptional mechanical performance.

scholarly journals Chemical and physical interactions of regenerated cellulose yarns and isocyanate-based matrix systems

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Bernhard Ungerer ◽  
Ulrich Müller ◽  
Antje Potthast ◽  
Enrique Herrero Acero ◽  
Stefan Veigel
Keyword(s):  
Mechanical Performance ◽  
Tensile Force ◽  
Tensile Modulus ◽  
Tensile Tests ◽  
Size Exclusion ◽  
Regenerated Cellulose ◽  
Hydrolytic Cleavage ◽  
Yarn Twist ◽  
Exclusion Chromatography ◽  
Physical And Chemical

AbstractIn the development of structural composites based on regenerated cellulose filaments, the physical and chemical interactions at the fibre-matrix interphase need to be fully understood. In the present study, continuous yarns and filaments of viscose (rayon) were treated with either polymeric diphenylmethane diisocyanate (pMDI) or a pMDI-based hardener for polyurethane resins. The effect of isocyanate treatment on mechanical yarn properties was evaluated in tensile tests. A significant decrease in tensile modulus, tensile force and elongation at break was found for treated samples. As revealed by size exclusion chromatography, isocyanate treatment resulted in a significantly reduced molecular weight of cellulose, presumably owing to hydrolytic cleavage caused by hydrochloric acid occurring as an impurity in pMDI. Yarn twist, fibre moisture content and, most significantly, the chemical composition of the isocyanate matrix were identified as critical process parameters strongly affecting the extent of reduction in mechanical performance. To cope with the problem of degradative reactions an additional step using calcium carbonate to trap hydrogen ions is proposed.

scholarly journals Potential of Brewer’s Spent Grain as a Potential Replacement of Wood in pMDI, UF or MUF Bonded Particleboard

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 319
Author(s):  
Marius Cătălin Barbu ◽  
Zeno Montecuccoli ◽  
Jakob Förg ◽  
Ulrike Barbeck ◽  
Petr Klímek ◽  
...  
Keyword(s):  
Internal Bond ◽  
Mechanical Performance ◽  
Animal Feed ◽  
Urea Formaldehyde ◽  
Modulus Of Rupture ◽  
Brewer’S Spent Grain ◽  
Beer Brewing ◽  
Removal Of Heavy Metals ◽  
Dry Conditions ◽  
Spent Grain

Brewer’s spent grain (BSG) is the richest by-product (85%) of the beer-brewing industry, that can be upcycled in a plentiful of applications, from animal feed, bioethanol production or for removal of heavy metals from wastewater. The aim of this research is to investigate the mechanical, physical and structural properties of particleboard manufactured with a mixture of wood particles and BSG gradually added/replacement in 10%, 30% and 50%, glued with polymeric diisocyanate (pMDI), urea-formaldehyde (UF) and melamine urea-formaldehyde (MUF) adhesives. The density, internal bond, modulus of rupture, modulus of elasticity, screw withdrawal resistance, thickness swelling and water absorption were tested. Furthermore, scanning electron microscopy anaylsis was carried out to analyze the structure of the panels after the internal bond test. Overall, it was shown that the adding of BSG decreases the mechanical performance of particleboard, due to reduction of the bonding between wood and BSG particles. This decrease has been associated with the structural differences proven by SEM inspection. Interaction of particles with the adhesive is different for boards containing BSG compared to those made from wood. Nevertheless, decrease in the mechanical properties was not critical for particleboards produced with 10% BSG which could be potentially classified as a P2 type, this means application in non-load-bearing panel for interior use in dry conditions, with high dimensional stability and stiffness.

scholarly journals Mechanical Optimization of Concrete with Recycled PET Fibres Based on a Statistical-Experimental Study

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 240
Author(s):  
Alejandro Meza ◽  
Pablo Pujadas ◽  
Laura Montserrat Meza ◽  
Francesc Pardo-Bosch ◽  
Rubén D. López-Carreño
Keyword(s):  
Reinforced Concrete ◽  
Aspect Ratio ◽  
Mechanical Performance ◽  
Tensile Tests ◽  
Superior Performance ◽  
Fibre Reinforced Concrete ◽  
Marine Fauna ◽  
Recycled Pet ◽  
Pet Bottles ◽  
Fibre Aspect Ratio

Discarded polyethylene terephthalate (PET) bottles have damaged our ecosystem. Problems of marine fauna conservation and land fertility have been related to the disposal of these materials. Recycled fibre is an opportunity to reduce the levels of waste in the world and increase the mechanical performance of the concrete. PET as concrete reinforcement has demonstrated ductility and post-cracking strength. However, its performance could be optimized. This study considers a statistical-experimental analysis to evaluate recycled PET fibre reinforced concrete with various fibre dose and aspect ratio. 120 samples were experimented under workability, compressive, flexural, and splitting tensile tests. The results pointed out that the fibre dose has more influence on the responses than its fibre aspect ratio, with statistical relation on the tensional toughness, equivalent flexural strength ratio, volumetric weight, and the number of fibres. Moreover, the fibre aspect ratio has a statistical impact on the tensional toughness. In general, the data indicates that the optimal recycled PET fibre reinforced concrete generates a superior performance than control samples, with an improvement similar to those reinforced with virgin fibres.

scholarly journals Mechanical and thermal stability of retained austenite in plastically deformed bainite-based TRIP-aided medium-Mn steels

2021 ◽  
Vol 21 (3) ◽  
Author(s):  
Aleksandra Kozłowska ◽  
Adam Grajcar ◽  
Aleksandra Janik ◽  
Krzysztof Radwański ◽  
Ulrich Krupp ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Thermal Stability ◽  
Retained Austenite ◽  
Elevated Temperatures ◽  
Mechanical Performance ◽  
Mechanical Stability ◽  
Electron Backscatter Diffraction ◽  
Cost Effective ◽  
Tensile Tests ◽  
Thermal Stability Of

AbstractAdvanced medium-Mn sheet steels show an opportunity for the development of cost-effective and light-weight automotive parts with improved safety and optimized environmental performance. These steels utilize the strain-induced martensitic transformation of metastable retained austenite to improve the strength–ductility balance. The improvement of mechanical performance is related to the tailored thermal and mechanical stabilities of retained austenite. The mechanical stability of retained austenite was estimated in static tensile tests over a wide temperature range from 20 °C to 200 °C. The thermal stability of retained austenite during heating at elevated temperatures was assessed by means of dilatometry. The phase composition and microstructure evolution were investigated by means of scanning electron microscopy, electron backscatter diffraction, X-ray diffraction and transmission electron microscopy techniques. It was shown that the retained austenite stability shows a pronounced temperature dependence and is also stimulated by the manganese addition in a 3–5% range.

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