A study of the solvation and association of lithium nitrate and lithium perchlorate in methanol and N,N-Dimethylformamide

1989 ◽  
Author(s):  
Ian McLeod Jamie
Keyword(s):  
Lithium Perchlorate ◽  
Lithium Nitrate

On the Properties of an Ion Conductive System Incorporated in Hybrid Films

2000 ◽  
Vol 628 ◽  
Author(s):  
G. González ◽  
P. J. Retuert ◽  
S. Fuentes
Keyword(s):  
Electrochemical Impedance ◽  
Ternary Phase Diagram ◽  
Lithium Perchlorate ◽  
Molar Ratio ◽  
Ionic Conductors ◽  
X Ray Diffraction ◽  
Poly Ethylene Oxide ◽  
Ion Conducting ◽  
Poly Ethylene ◽  
High Degree

ABSTRACTBlending the biopolymer chitosan (CHI) with poly (aminopropilsiloxane) oligomers (pAPS), and poly (ethylene oxide) (PEO) in the presence of lithium perchlorate lead to ion conducting products whose conductivity depends on the composition of the mixture. A ternary phase diagram for mixtures containing 0.2 M LiClO4 shows a zone in which the physical properties of the products - transparent, flexible, mechanically robust films - indicate a high degree of molecular compatibilization of the components. Comparison of these films with binary CHI-pAPS nanocomposites as well as the microscopic aspect, thermal behavior, and X-ray diffraction pattern of the product with the composition PEO/CHI/pAPS/LiClO4 1:0.5:0.6:0.2 molar ratio indicates that these films may be described as a layered nanocomposite. In this composite, lithium species coordinated by PEO and pAPS should be inserted into chitosan layers. Electrochemical impedance spectroscopy measurements indicate the films are pure ionic conductors with a maximal bulk conductivity of 1.7*10-5 Scm-1 at 40 °C and a sample-electrode interface capacitance of about 1.2*10-9 F.

scholarly journals Monitoring of the Impact of Lithium Nitrate on the Alkali–aggregate Reaction Using Acoustic Emission Methods

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 20
Author(s):  
Justyna Zapała-Sławeta ◽  
Grzegorz Świt
Keyword(s):  
Acoustic Emission ◽  
Initial Reaction ◽  
Lithium Nitrate ◽  
Acoustic Emission Method ◽  
Emission Method ◽  
Acoustic Activity ◽  
Initial Stage ◽  
Chemical Admixture ◽  
Different Characteristics ◽  
The Impact

The study analyzed the possibility of using the acoustic emission method to analyse the reaction of alkali with aggregate in the presence of lithium nitrate. Lithium nitrate is a chemical admixture used to reduce adverse effects of corrosion. The tests were carried out using mortars with reactive opal aggregate, stored under the conditions defined by ASTM C227. The acoustic activity of mortars with a corrosion inhibitor was referred to linear changes and microstructure of specimens in the initial reaction stages. The study found a low acoustic activity of mortars with lithium nitrate. Analysis of characteristic parameters of acoustic emission signals, combined with the observation of changes in the microstructure, made it possible to describe the corrosion processes. As the reaction progressed, signals with different characteristics were recorded, indicating aggregate cracking at the initial stage of the reaction, followed by cracking of the cement paste. The results, which were referred to the acoustic activity of reference mortars, confirmed that the reaction of opal aggregate with alkali was mitigated in mortars with lithium nitrate, and the applied acoustic emission method enabled the detection and monitoring of ASR progress.

scholarly journals In Situ Dielectric Characterization of Poly(ethylene oxide) Melts Containing Lithium Perchlorate under Steady Shear Flow

2004 ◽  
Vol 37 (18) ◽  
pp. 7064-7064
Author(s):  
Yumi Matsumiya ◽  
Nitash P. Balsara ◽  
John B. Kerr ◽  
Tadashi Inoue ◽  
Hiroshi Watanabe
Keyword(s):  
Shear Flow ◽  
Ethylene Oxide ◽  
Lithium Perchlorate ◽  
Dielectric Characterization ◽  
Steady Shear Flow ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Oxide Melts
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