Total Reflection X-ray Spectrometry (TXRF) for Trace Elements Assessment in Edible Clams

2014 ◽  
Vol 68 (11) ◽  
pp. 1241-1246 ◽  
Author(s):  
Eva Marguí ◽  
Alexandra de Fátima Marques ◽  
Maria de Lurdes Prisal ◽  
Manuela Hidalgo ◽  
Ignasi Queralt ◽  
...  

The present contribution presents a preliminary investigation of the chemical composition with respect to major, minor, trace, and ultratrace elements in several clam species that are frequently used for human consumption in Portuguese markets and worldwide. In order to use a simple and rapid analytical methodology for clam analysis, energy dispersive X-ray fluorescence (EDXRF) spectrometry and total reflection X-ray fluorescence (TXRF) spectrometry were selected as analytical techniques. The analytical capabilities of TXRF spectrometry were evaluated for the determination of minor and trace elements in commercial edible clams. We compared the direct analysis of powdered suspensions (using different sample amounts and dispersant agents) with the analysis of the digested samples for trace element determination. Inductively coupled plasma mass spectrometry analysis of clam digests was also performed to evaluate the analytical possibilities of TXRF spectrometry for trace and ultratrace analysis.

1999 ◽  
Vol 131 (3-4) ◽  
pp. 219-223 ◽  
Author(s):  
Juha K. Vilhunen ◽  
Alex von Bohlen ◽  
Martina Schmeling ◽  
Leena Rantanen ◽  
Seppo Mikkonen ◽  
...  

1985 ◽  
Vol 57 (14) ◽  
pp. 2880-2885 ◽  
Author(s):  
Rolf Peter. Stoessel ◽  
Andreas. Prange

2019 ◽  
Vol 193 (1) ◽  
pp. 73-80
Author(s):  
Susana Padoin ◽  
Victor Hugo de Freitas ◽  
Daniele Aparecida Maia Cleto ◽  
Aline Campos Zeffa ◽  
Fábio Yuzo Nakamura ◽  
...  

1999 ◽  
Vol 34 (2) ◽  
pp. 305-316 ◽  
Author(s):  
E.H. Bakraji ◽  
J. Karajo

Abstract Total reflection X-ray fluorescence spectrometry and chemical preconcentration have been applied for multi-elemental analysis of Damascus drinking water. Water was taken directly from taps of several city sectors and analyzed for the following trace elements: Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Se and Pb. The detection limits were found to be in the range of 0.1 to 0.4 µg/L. The mean levels of trace elements in the Damascus drinking water were below the World Health Organization drinking water quality guidelines.


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