Vibrational spectroscopy of nonlinear excitations via excited-state resonant impulsive Raman spectroscopy

2006 ◽  
Author(s):  
F.X. Morrissey ◽  
S.L. Dexheimer
Keyword(s):  
Raman Spectroscopy ◽  
Excited State ◽  
Vibrational Spectroscopy ◽  
Nonlinear Excitations

scholarly journals Exploring the Franck-Condon region of a photoexcited charge transfer complex in solution to interpret femtosecond stimulated Raman spectroscopy: excited state electronic structure methods to unveil non-radiative pathways

2021 ◽  
Author(s):  
Federico Coppola ◽  
Paola Cimino ◽  
Umberto Raucci ◽  
Maria Gabriella Chiariello ◽  
Alessio Petrone ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Electronic Structure ◽  
Excited State ◽  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Main Role ◽  
Photoinduced Charge Transfer ◽  
Electronic Structure Methods ◽  
Franck Condon ◽  
Photoinduced Charge

We present electronic structure methods to unveil non-radiative pathways of photoinduced charge transfer (CT) reactions that play a main role in photophysics and light harvesting technologies. A prototypical π-stacked molecular...

scholarly journals Applications of Vibrational Spectroscopy for Analysis of Connective Tissues

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 922
Author(s):  
William Querido ◽  
Shital Kandel ◽  
Nancy Pleshko
Keyword(s):  
Raman Spectroscopy ◽  
Vibrational Spectroscopy ◽  
Near Infrared ◽  
Ex Vivo ◽  
Biological Tissues ◽  
Label Free ◽  
Connective Tissues ◽  
Bone Properties ◽  
Composition And Structure

Advances in vibrational spectroscopy have propelled new insights into the molecular composition and structure of biological tissues. In this review, we discuss common modalities and techniques of vibrational spectroscopy, and present key examples to illustrate how they have been applied to enrich the assessment of connective tissues. In particular, we focus on applications of Fourier transform infrared (FTIR), near infrared (NIR) and Raman spectroscopy to assess cartilage and bone properties. We present strengths and limitations of each approach and discuss how the combination of spectrometers with microscopes (hyperspectral imaging) and fiber optic probes have greatly advanced their biomedical applications. We show how these modalities may be used to evaluate virtually any type of sample (ex vivo, in situ or in vivo) and how “spectral fingerprints” can be interpreted to quantify outcomes related to tissue composition and quality. We highlight the unparalleled advantage of vibrational spectroscopy as a label-free and often nondestructive approach to assess properties of the extracellular matrix (ECM) associated with normal, developing, aging, pathological and treated tissues. We believe this review will assist readers not only in better understanding applications of FTIR, NIR and Raman spectroscopy, but also in implementing these approaches for their own research projects.

scholarly journals Quantification of protein glycation using vibrational spectroscopy

The Analyst ◽  
2020 ◽  
Vol 145 (10) ◽  
pp. 3686-3696
Author(s):  
Bethan S. McAvan ◽  
Aidan P. France ◽  
Bruno Bellina ◽  
Perdita E. Barran ◽  
Royston Goodacre ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Vibrational Spectroscopy ◽  
Protein Glycation ◽  
Glycated Proteins

FTIR-ATR and Raman spectroscopy can distinguish between glycated and non-glycated proteins.

scholarly journals Identification of LDPE Grades Focusing on Specific CH2 Raman Vibration Modes

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Richard Jumeau ◽  
Patrice Bourson ◽  
Michel Ferriol ◽  
François Lahure ◽  
Marc Ponçot ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Raman Spectroscopy ◽  
Vibrational Spectroscopy ◽  
Phenomenological Model ◽  
Low Density ◽  
Vibration Modes ◽  
Scanning Calorimetry ◽  
Lamella Thickness ◽  
Poly Ethylene

The possibilities of applications of vibrational spectroscopy techniques (Raman spectroscopy) in the analysis and characterization of polymers are more and more used and accurate. In this paper, our purpose is to characterize Low Density Poly(Ethylene) (LDPE) grades by Raman spectroscopy and in particular with CH2 Raman vibration modes. With temperature measurements, we determine different amorphous and crystalline Raman assignments. From these results and on the basis of the evolution of CH2 bending Raman vibration modes, we develop a phenomenological model in correlation with Differential Scanning Calorimetry and in particular with crystalline lamella thickness determination.

Identification of the Excited-State C═C and C═O Modes of trans-β-Apo-8′-carotenal with Transient 2D-IR-EXSY and Femtosecond Stimulated Raman Spectroscopy

2015 ◽  
Vol 6 (9) ◽  
pp. 1592-1598 ◽  
Author(s):  
Mariangela Di Donato ◽  
Elena Ragnoni ◽  
Andrea Lapini ◽  
Tomasz M. Kardaś ◽  
Boźena Ratajska-Gadomska ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Excited State ◽  
2D Ir ◽  
Stimulated Raman
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