Thin-Film Absorbers based on Gold Nanoparticles decorated Silicon Nanowires on thin Gold film

Author(s):  
Fugen Chen ◽  
Liu Yang ◽  
Sailing He
2012 ◽  
Vol 3 ◽  
pp. 535-545 ◽  
Author(s):  
Britta Kämpken ◽  
Verena Wulf ◽  
Norbert Auner ◽  
Marcel Winhold ◽  
Michael Huth ◽  
...  

In this work the applicability of neopentasilane (Si(SiH3)4) as a precursor for the formation of silicon nanowires by using gold nanoparticles as a catalyst has been explored. The growth proceeds via the formation of liquid gold/silicon alloy droplets, which excrete the silicon nanowires upon continued decomposition of the precursor. This mechanism determines the diameter of the Si nanowires. Different sources for the gold nanoparticles have been tested: the spontaneous dewetting of gold films, thermally annealed gold films, deposition of preformed gold nanoparticles, and the use of “liquid bright gold”, a material historically used for the gilding of porcelain and glass. The latter does not only form gold nanoparticles when deposited as a thin film and thermally annealed, but can also be patterned by using UV irradiation, providing access to laterally structured layers of silicon nanowires.


2019 ◽  
Author(s):  
Kam Sang Kwok ◽  
Yuxuan Wang ◽  
Michael Cao ◽  
Hao Shen ◽  
Weinan Xu ◽  
...  

<p>The local structure and geometry of catalytic interfaces can influence the selectivity of chemical reactions. Here, using a pre-strained polymer, we uniaxially compress a thin gold film to form a nano-folded catalyst. We observe two kinds of folds and can tune the ratio of loose to tight folds by varying the extent of pre-strain in the polymer. We characterize the nano-folded catalysts using x-ray diffraction, scanning, and transmission electron microscopy. We observe grain reorientation and coarsening in the nano-folded gold catalysts. Electroreduction of carbon dioxide with these nano-folded catalysts reveals an enhancement of Faradaic efficiency for carbon monoxide formation by a factor of about four. This result suggests that electrolyte mass transport limitations and an increase of the local pH in the tight folds of the catalyst outweigh the effects of alterations in grain characteristics. Together, our studies demonstrate that nano-folded geometries can significantly alter grain characteristics, mass transport, and catalytic selectivity. </p>


2002 ◽  
Vol 80 (20) ◽  
pp. 3715-3717 ◽  
Author(s):  
Ulrich C. Fischer ◽  
Eugene Bortchagovsky ◽  
Jörg Heimel ◽  
René T. Hanke

2002 ◽  
Vol 34 (3) ◽  
pp. 199-202 ◽  
Author(s):  
K. Venkatakrishnan ◽  
B. Tan ◽  
B.K.A. Ngoi

Vacuum ◽  
1994 ◽  
Vol 45 (2-3) ◽  
pp. 299-301 ◽  
Author(s):  
L. Stobiński ◽  
R. Duś

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