Synthesis and properties of germanium nanowires

2007 ◽  
Vol 79 (1) ◽  
pp. 55-65 ◽  
Author(s):  
Dunwei Wang

As a promising electronic material, Ge nanowire (GeNW) has attracted much attention for its low band gaps, high mobilities, and unprecedented dimensions. This article reviews recent research and advancement on this topic and summarizes many aspects of GeNWs, including preparation, surface chemistry, physical properties, functional devices, and controlled assembly. It is shown that GeNWs can be readily synthesized by chemical methods and their electronic properties are comparable or superior to that of the bulk counterparts. Studies of surface chemistry have revealed dominant roles of surfaces on nanowires, and this result led to successful passivations toward air-stable, high-performance functional devices. Finally, controlled assembly to organize chemically synthesized nanowires into functional structures is discussed. Doors are opened up to widely utilize this novel material as excellent electronic building blocks.

2013 ◽  
Vol 135 (8) ◽  
Author(s):  
Kyle C. Smith ◽  
Timothy S. Fisher

Control of transport processes in composite microstructures is critical to the development of high-performance functional materials for a variety of energy storage applications. The fundamental process of conduction and its control through the manipulation of granular composite attributes (e.g., grain shape) are the subject of this work. We show that athermally jammed packings of tetrahedra with ultrashort range order exhibit fundamentally different pathways for conduction than those in dense sphere packings. Highly resistive granular constrictions and few face–face contacts between grains result in short-range distortions from the mean temperature field. As a consequence, ‘granular’ or differential effective medium theory predicts the conductivity of this media within 10% at the jamming point; in contrast, strong enhancement of transport near interparticle contacts in packed-sphere composites results in conductivity divergence at the jamming onset. The results are expected to be particularly relevant to the development of nanomaterials, where nanoparticle building blocks can exhibit a variety of faceted shapes.


2019 ◽  
Author(s):  
Torben Sick ◽  
Niklas Keller ◽  
Nicolai Bach ◽  
Andreas Koszalkowski ◽  
Julian Rotter ◽  
...  

Covalent organic frameworks (COFs), consisting of covalently connected organic building units, combine attractive features such as crystallinity, open porosity and widely tunable physical properties. For optoelectronic applications, the incorporation of heteroatoms into a 2D COF has the potential to yield desired photophysical properties such as lower band gaps, but can also cause lateral offsets of adjacent layers. Here, we introduce dibenzo[g,p]chrysene (DBC) as a novel building block for the synthesis of highly crystalline and porous 2D dual-pore COFs showing interesting properties for optoelectronic applications. The newly synthesized terephthalaldehyde (TA), biphenyl (Biph), and thienothiophene (TT) DBC-COFs combine conjugation in the a,b-plane with a tight packing of adjacent layers guided through the molecular DBC node serving a specific docking site for successive layers. The resulting DBC-COFs exhibit a hexagonal dual-pore kagome geometry, which is comparable to COFs containing another molecular docking site, namely 4,4′,4″,4‴-(ethylene-1,1,2,2-tetrayl)-tetraaniline (ETTA). In this context, the respective interlayer distances decrease from about 4.60 Å in ETTA-COFs to about 3.6 Å in DBC-COFs, leading to well-defined hexagonally faceted single crystals sized about 50-100 nm. The TT DBC-COFs feature broad light absorption covering large parts of the visible spectrum, while Biph DBC-COF shows extraordinary excited state lifetimes exceeding 10 ns. In combination with the large number of recently developed linear conjugated building blocks, the new DBC tetra-connected node is expected to enable the synthesis of a large family of strongly p-stacked, highly ordered 2D COFs with promising optoelectronic properties.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Esteban Gonzalez-Valencia ◽  
Ignacio Del Villar ◽  
Pedro Torres

AbstractWith the goal of ultimate control over the light propagation, photonic crystals currently represent the primary building blocks for novel nanophotonic devices. Bloch surface waves (BSWs) in periodic dielectric multilayer structures with a surface defect is a well-known phenomenon, which implies new opportunities for controlling the light propagation and has many applications in the physical and biological science. However, most of the reported structures based on BSWs require depositing a large number of alternating layers or exploiting a large refractive index (RI) contrast between the materials constituting the multilayer structure, thereby increasing the complexity and costs of manufacturing. The combination of fiber–optic-based platforms with nanotechnology is opening the opportunity for the development of high-performance photonic devices that enhance the light-matter interaction in a strong way compared to other optical platforms. Here, we report a BSW-supporting platform that uses geometrically modified commercial optical fibers such as D-shaped optical fibers, where a few-layer structure is deposited on its flat surface using metal oxides with a moderate difference in RI. In this novel fiber optic platform, BSWs are excited through the evanescent field of the core-guided fundamental mode, which indicates that the structure proposed here can be used as a sensing probe, along with other intrinsic properties of fiber optic sensors, as lightness, multiplexing capacity and easiness of integration in an optical network. As a demonstration, fiber optic BSW excitation is shown to be suitable for measuring RI variations. The designed structure is easy to manufacture and could be adapted to a wide range of applications in the fields of telecommunications, environment, health, and material characterization.


Nano Letters ◽  
2014 ◽  
Vol 14 (11) ◽  
pp. 6547-6553 ◽  
Author(s):  
Zhaoyang Lin ◽  
Yu Chen ◽  
Anxiang Yin ◽  
Qiyuan He ◽  
Xiaoqing Huang ◽  
...  

2020 ◽  
Vol 11 (SPL4) ◽  
pp. 2756-2767
Author(s):  
Vijaya Vemani ◽  
Mounika P ◽  
Poulami Das ◽  
Anand Kumar Tengli

In the preservation of normal physiological functions, the building blocks of the body called amino acids play a crucial role. A number of valuable and nutritional phytoconstituents are contained in fruit juices, such as vitamins, minerals, microelements, organic acids, antioxidants, flavonoids, amino acids and other components. Due to the growing population and demand, the quality of fruit juices is decreasing. One of the unethical and harmful practices called adulteration or food fraudulence has been adopted by most food and beverage industries. The amino acids which is one of the most important phytochemicals of fruit and fruit juices which affects the organoleptic properties like color, odor, and taste of juices and also helps in authenticity process from governing bodies by providing total amino acid content. Consequently, the main aim of the present review work is to provide information regarding the importance of amino acids, how they are adulterated, the potential analytical approach to detected amino acids and which methods are generally accepted method by the food industries. According to the literature review, we presume that reverse phased high-performance liquid chromatography with pre-column derivatization was the most adopted method for quality checking due to its advantages over other old and recent analytical approaches like simple, rapid, cost-effective nature, less / no sample matrix effect with high sensitivity, accuracy, and precision.


2013 ◽  
Vol 23 (04) ◽  
pp. 1340011 ◽  
Author(s):  
FAISAL SHAHZAD ◽  
MARKUS WITTMANN ◽  
MORITZ KREUTZER ◽  
THOMAS ZEISER ◽  
GEORG HAGER ◽  
...  

The road to exascale computing poses many challenges for the High Performance Computing (HPC) community. Each step on the exascale path is mainly the result of a higher level of parallelism of the basic building blocks (i.e., CPUs, memory units, networking components, etc.). The reliability of each of these basic components does not increase at the same rate as the rate of hardware parallelism. This results in a reduction of the mean time to failure (MTTF) of the whole system. A fault tolerance environment is thus indispensable to run large applications on such clusters. Checkpoint/Restart (C/R) is the classic and most popular method to minimize failure damage. Its ease of implementation makes it useful, but typically it introduces significant overhead to the application. Several efforts have been made to reduce the C/R overhead. In this paper we compare various C/R techniques for their overheads by implementing them on two different categories of applications. These approaches are based on parallel-file-system (PFS)-level checkpoints (synchronous/asynchronous) and node-level checkpoints. We utilize the Scalable Checkpoint/Restart (SCR) library for the comparison of node-level checkpoints. For asynchronous PFS-level checkpoints, we use the Damaris library, the SCR asynchronous feature, and application-based checkpointing via dedicated threads. Our baseline for overhead comparison is the naïve application-based synchronous PFS-level checkpointing method. A 3D lattice-Boltzmann (LBM) flow solver and a Lanczos eigenvalue solver are used as prototypical applications in which all the techniques considered here may be applied.


Research ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-14 ◽  
Author(s):  
Jie Jiang ◽  
Tao Xu ◽  
Junpeng Lu ◽  
Litao Sun ◽  
Zhenhua Ni

Two-dimensional (2D) materials have attracted increasing interests in the last decade. The ultrathin feature of 2D materials makes them promising building blocks for next-generation electronic and optoelectronic devices. With reducing dimensionality from 3D to 2D, the inevitable defects will play more important roles in determining the properties of materials. In order to maximize the functionality of 2D materials, deep understanding and precise manipulation of the defects are indispensable. In the recent years, increasing research efforts have been made on the observation, understanding, manipulation, and control of defects in 2D materials. Here, we summarize the recent research progress of defect engineering on 2D materials. The defect engineering triggered by electron beam (e-beam), plasma, chemical treatment, and so forth is comprehensively reviewed. Firstly, e-beam irradiation-induced defect evolution, structural transformation, and novel structure fabrication are introduced. With the assistance of a high-resolution electron microscope, the dynamics of defect engineering can be visualized in situ. Subsequently, defect engineering employed to improve the performance of 2D devices by means of other methods of plasma, chemical, and ozone treatments is reviewed. At last, the challenges and opportunities of defect engineering on promoting the development of 2D materials are discussed. Through this review, we aim to build a correlation between defects and properties of 2D materials to support the design and optimization of high-performance electronic and optoelectronic devices.


High-performance VLSI systems are essential in real-time applications, in order to increase the performance of the VLSI systems, an approximate computing technique is followed where the performance of the circuit is enhanced by trading off it with a slight loss in the accuracy. These approximate circuits are used in error-tolerant applications, where output need not be accurate. This paper concentrates mainly on approximate adders, as they are major building blocks of DSP systems. The analysis of the Lower-part OR Adder for 4-bit addition and comparison of it with the precise adder i.e., Ripple Carry Adder using the mentor graphics tool in 90 nm CMOS technology are presented in this paper. Our experimental results show that there is 17%-70% savings in power dissipation, 4%-32% saving in the area, and 19%-84% savings in time due to approximate adder. As the LOA-2 and LOA-3 are performing optimally these two adders can be used for error-tolerant applications and based on the requirement LOA-2 or LOA-3 can be selected.


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